CBSE Class 12 Chemistry Haloalkanes And Haloarenes Notes Set 04

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(ix) (CCl3)3 CCl

2. Write the structure of following halogen compounds

(i) 2-chloro-3-methylpentane

(ii) 2-(2-chlorophenyl)-1-iodooctane

(iii) 1-bromo-4-sec-butyl-2–methylebenzene.

(iv) p-bromotoluene.

(v) chlorophenylmethane

3. Arrange the following in the increasing order of properly indicated :

(i) bromomethane, chloromethane, dichloromethane. (Increasing order of boiling points).

(ii) 1-chloropropane, isopropyl chloride, 1-chlorobutane (Increasing order of boiling point)

(iii) dichloromethane, chloroform, carbon terachloride. (Increasing order of dipole moment.

(iv) CH3F, CH3Cl, CH3Br, CH3l (Increasing reactivity towards nucleophilic substitution and increasing order of dipole moment)

(v) o,m.p-dichlorobenzenes (Increasing order of melting points). 

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CBSE Class 12 Chemistry notes and questions for Haloalkanes and Haloarenes Part B 1

CBSE Class 12 Chemistry notes and questions for Haloalkanes and Haloarenes Part B 2

 

5. How will you bring about the following conversions?
 
(i) benzene to 3-bromonitrobenzene
(ii) ethanol to but-1-yne
(iii) 1-bromopropane to 2-bromopropane
(iv) benzene to 4-bromo-1-nitrobenzene
(v) aniline to chlorobenzene
(vi) 2-methyl-1-propene to 2-chloro-2-methylpropane
(vii) ethyl chloride to propanoic acid
(viii) but-1-ene to n-butyl iodide
(ix) benzene to phenylchloromethane.
(x) tert-butyl bromide to isobutyl bromide.
 
6. Identify the products formed in the following sequence :

CBSE Class 12 Chemistry notes and questions for Haloalkanes and Haloarenes Part B 3

CBSE Class 12 Chemistry notes and questions for Haloalkanes and Haloarenes Part B 4

 

7. Explain the following reactions with suitable example :
 
(i) Finkelstein reaction.
(ii) Swarts reaction.
(iii) Wurtz reaction.
(iv) Wurtz-Fitting reaction
(v) Friedel-Craft’s alkylation reaction.
(vi) Friedel-Craft’s acylation reaction
(vii) Sandmeyer reaction.
 

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Revision Notes and Key Concepts for Class 12 Chemistry Unit 6 Haloalkanes and Haloarenes

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