CBSE Class 12 Chemistry Amines Notes Set E

2. Giving an example of each, describe the following reactions :

(i) Hoffman bromamide reaction

(ii) Gabriel phthanlimide synthesis

(iii) Gatterman reaction

(iv) Coupling reaction

(vi) Carbylamine reaction

(vii) Acetylation of aniline

3. Describe the Hinsberg’s test for identification of primary, secondary and tertiary amines. Also write the chemical equations of the reactions involved.

4. Arrange the following in the increasing order of given property indicated.

(i) C₂H₅NH₂, (C₂H₅)₂NH, (C₂H₅)₃N and NH₃, (Basic strength in aqueous solution).

(ii) C₂H₅NH₂, (C₂H₅)₂NH, (C₂H₅)₃N and CH₃NH₂. (Basic strength in aseous phase).

(iii) Aniline, p-toluidine, p-nitroaniline. (Basic strength).

(iv) C₂H₅OH, (CH₃)₂ HN, C₂H₅NH₂ (Boiling point)

6. How will you bring about the following conversions?

(i) benzene to Aniline

(ii) aniline to benzene

(iii) ethanoic acid to ethanamine

(iv) p-toluidine to 2-bromo-4-methylaniline.

(v) methylbromide to ethanamine

(vi) benzenediazonium chloride to nitrobenzene

(vii) ethylamine to methylamine

(ix) benzene to sulphanilic acid

(x) hexanenitrile to 1-aminopentane.

7. Write the products formed in the following sequence of reactions :–

8. Identify the missing reagent/product in the following reactions :

Please click the link below to download pdf file for CBSE Class 12 Chemistry notes and questions for Amines Part C.