Class 12 Chemistry Practice Assignments: CBSE Class 12 Chemistry The p Block Elements Notes and Questions
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(i)conc. HNO3 is a strong oxidizing agent & attacks most metals gold & Pt.
(ii)Cr & Al do not dissolve HNO3 because of the formation of a positive film of oxide on the surface.
(iii)it oxidises non metals like I2 to HNO3, C to CO2 , S to H2so4
(iv)brown ring tes is used to detect NO‐.
PHOSPHOROUS:‐
ALLOTROPIC FORMS: White , red α‐black &β‐black . White phosphorous is more reactive red phosphorous because white P exists as discrete P4 molecules . in red P several P4molecules are linked to formed polymeric chain.
Question. Which of the following has the highest dipole moment?
(a) SbH3
(b) AsH3
(c) NH3
(d) PH3
Question. The basic character of hydrides of the V group elements decreases in the order
(a) NH3 > PH3 > AsH3 > SbH3
(b) SbH3 > AsH3 > PH3 > NH3
(c) SbH3 > PH3 > AsH3 > NH3
(d) NH3 > SbH3 > PH3 > AsH3
Question. Among the following oxides, the lowest acidic is
(a) As4O6
(b) As4O10
(c) P4O6
(d) P4O10
Question. Which of the following fluorides does not exist?
(a) NF5
(b) PF5
(c) AsF5
(d) SbF5
Question. Which one has the lowest boiling point?
(a) NH3
(b) PH3
(c) AsH3
(d) SbH3
Question. Number of electrons shared in the formation of nitrogen molecule is
(a) 6
(b) 10
(c) 2
(d) 8
Question. Nitrogen is relatively inactive element because
(a) its atom has a stable electronic configuration
(b) it has low atomic radius
(c) its electronegativity is fairly high
(d) dissociation energy of its molecule is fairly high.
Question. Pure nitrogen is prepared in the laboratory by heating a mixture of
(a) NH4OH + NaCl
(b) NH4NO3 + NaCl
(c) NH4Cl + NaOH
(d) NH4Cl + NaNO2.
Question. Which of the following statement is not correct for nitrogen?
(a) Its electronegativity is very high.
(b) d-orbitals are available for bonding.
(c) It is a typical non-metal.
(d) Its molecular size is small.
Question. Urea reacts with water to form A which will decompose to form B. B when passed through Cu2+ (aq), deep blue colour solution C is formed. What is the formula of C from the following?
(a) CuSO4
(b) [Cu(NH3)4]2+
(c) Cu(OH)2
(d) CuCO3·Cu(OH)2
Question. Aqueous solution of ammonia consists of
(a) H+
(b) OH–
(c) NH4+
(d) NH4+ and OH–.
Question. Which of the following oxides of nitrogen is paramagnetic?
(a) NO2
(b) N2O3
(c) N2O
(d) N2O5
Question. Which of the following is a nitric acid anhydride?
(a) NO
(b) NO2
(c) N2O5
(d) N2O3
Question. When copper is heated with conc. HNO3 it produces
(a) Cu(NO3)2, NO and NO2
(b) Cu(NO3)2 and N2O
(c) Cu(NO3)2 and NO2
(d) Cu(NO3)2 and NO
Question. Zn gives H2 gas with H2SO4 and HCl but not with HNO3 because
(a) Zn act as oxidising agent when react with HNO3
(b) HNO3 is weaker acid than H2SO4 and HCl
(c) in electrochemical series Zn is above hydrogen
(d) NO3– is reduced in preference to hydronium ion.
Question. Sugarcane on reaction with nitric acid gives
(a) CO2 and SO2
(b) (COOH)2
(c) 2HCOOH(two moles)
(d) no reaction.
Question. Which of the following phosphorus is the most reactive?
(a) Scarlet phosphorus
(b) White phosphorus
(c) Red phosphorus
(d) Violet phosphorus
Question. Each of the following is true for white and red phosphorus except that they
(a) are both soluble in CS2
(b) can be oxidised by heating in air
(c) consist of the same kind of atoms
(d) can be converted into one another.
Question. A compound ‘X’ upon reaction with H2O produces a colourless gas ‘Y’ with rotten fish smell. Gas ‘Y’ is absorbed in a solution of CuSO4 to give Cu3P2 as one of the products. Predict the compound ‘X’.
(a) Ca3P2
(b) NH4Cl
(c) As2O3
(d) Ca3(PO4)2
Question. PH4I + NaOH forms
(a) PH3
(b) NH3
(c) P4O6
(d) P4O10
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CBSE Class 12 Chemistry Assignments for Unit 07 The P-Block Elements
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