CBSE Class 12 Chemistry Coordination Chemistry Assignment

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LEVEL-1 QUESTIONS
 
1.Define Ligand . Give one example also.
The ion or molecules which are coordinately bonded to central metalatom in the coordination entity are called ligands.
 
2. Why Coordination compounds are coloured?
Due to d-d transition.
 
3. What is Homoleptic complexes?
The complexes in which a metal is bound to only one kind of donorgroups. E.g., [Co(NH3)6]3+
 
4. What is the Oxidation no. of cobalt in K[Co(CO)4]?
+1
 
5. Explain each of the following: coordination entity, ligand, coordination number, coordination polyhedron, homoleptic and heteroleptic.
Answer
(i)Coordination entity:
A coordination entity is an electrically charged radical or species carrying a positive ornegative charge. In a coordination entity, the central atom or ion is surrounded by a suitablenumber of
neutral molecules or negative ions ( called ligands)
 
(ii)Ligands
The neutral molecules or negatively charged ions that surround the metal atom in acoordination entity or a coordinal complex are known as ligands. For example,,Cl−, −OH. Ligands are usually polar in nature and possess at least one unshared pair ofvalence electrons.
 
(iii)Coordination number:
The total number of ligands (either neutral molecules or negative ions) that get attached tothe central metal atom in the coordination sphere is called the coordination number of thecentral metal atom. It is also referred to as its ligancy.
 
(vi)Coordination polyhedron:
Coordination polyhedrons about the central atom can be defined as the spatial arrangement of the ligands that are directly attached to the central metal ion in the coordination sphere.
 
(v)Homoleptic complexes:
These are those complexes in which the metal ion is bound to only one kind of a donorgroup.
 
(vi)Heteroleptic complexes:
Heteroleptic complexes are those complexes where the central metal ion is bound to morethan one
type of a donor group.
 
6. What is meant by unidentate, didentate and ambidentate ligands? Give two examples for each.
Answer A ligand may contain one or more unshared pairs of electrons which are called the donorsites of ligands. Now, depending on the number of these donor sites, ligands can be classifiedas follows:
 
(a)Unidentate ligands: Ligands with only one donor sites are called unidentate ligands. Fore.g., ,Cl− etc.
 
(b)Didentate ligands: Ligands that have two donor sites are called didentate ligands. Fore.g.,

(a) Ethane-1,2-diamine

(b) Oxalate ion

(c)Ambidentate ligands:
Ligands that can attach themselves to the central metal atom through two different atoms arecalled ambidentate ligands.

7.Write the name of each of the following complex compound
(a) [Co(NH3)4(H2O)2]Cl3
(b) [Pt(NH3)4][NiCl4]
Ans. (a) Tetraamminediaquacobalt(III)chloride
(b) Tetraammineplatinum(II)tetrachloridonickelate(II)

Write the IUPAC name of [CrCl2(en)(NH3)2]+
Ans. Diamminedichloridoethane-1,2-diamminechromium(III)ion

Why only transition metals are known to form π complexes?
Ans. Transition metals have empty d-orbitals into which the electron-pairs can be donated by ligands containing π electrons, i.e, electrons in their π molecular orbital.

10. CO is a stronger ligand than NH3. Why?
Ans. Back bonding.

11. What is crystal field splitting energy?
Energy difference between eg and t2g level.

12. Differentiate between:

a) Didentate and Polydentate ligand

Didentate ligand : Two binding sites

Polydentate ligand: more than two binding sites

b) Chelate ligand and ambidentate ligand

Chelate ligand : Forms cyclic structure.

ambidentate ligand : Bind through either of the atoms.
 
 
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Chapter Assignment & Practice Material for Class 12 Chemistry Unit 5 Coordination Compounds

Revision Assignment: Unit 5 Coordination Compounds (CBSE)

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Steps to Complete Unit 5 Coordination Compounds Assignments Successfully

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  2. Self-Evaluation: Solve exercises independently before inspecting professional answer guides.
  3. Progress Monitoring: Note down complex formulas or concepts, clearing them up using available online practice aids.

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