Refer to NEET Chemistry Coordination Compounds MCQs Set C provided below. NEET Full Syllabus Chemistry MCQs with answers available in Pdf for free download. The MCQ Questions for Full Syllabus Chemistry with answers have been prepared as per the latest syllabus, NEET books and examination pattern suggested in Full Syllabus by NEET, NCERT and KVS. Multiple Choice Questions for Coordination Compounds are an important part of exams for Full Syllabus Chemistry and if practiced properly can help you to get higher marks. Refer to more Chapter-wise MCQs for NEET Full Syllabus Chemistry and also download more latest study material for all subjects
MCQ for Full Syllabus Chemistry Coordination Compounds
Full Syllabus Chemistry students should refer to the following multiple-choice questions with answers for Coordination Compounds in Full Syllabus. These MCQ questions with answers for Full Syllabus Chemistry will come in exams and help you to score good marks
Coordination Compounds MCQ Questions Full Syllabus Chemistry with Answers
Question: Which of the following complexes exhibits the highest paramagnetic behaviour ? (Where gly = glycine,en = ethylenediamine and bpy = bipyridyl moities). (At. number Ti = 22, V = 23, Fe = 26, Co = 27)
- a) [Ti(NH3)6]3+
- b) [V(gly)2(OH)2(NH3)2]+
- c) [Fe(en)(bpy)(NH3)2]2+
- d) [Co(OX)2(OH)2]–
Answer: [Co(OX)2(OH)2]–
Question: In which of the following coordination entities the magnitude of Δo(CFSE in octahedral field) will be maximum (at.no. Co = 27)?
- a) [Co(C2O4)3]3–
- b) [Co(H2O)6]3+
- c) [Co(NH3)6]3+
- d) [Co(CN)6]3–
Answer: [Co(CN)6]3–
Question: Which one of the following aqua complexes will exhibit the minimum paramagnetic behaviour? Atomic number.Cr = 24, Mn = 25, Fe = 26, Ni = 28)
- a) [Cr(H2O)6]2+
- b) [Mn(H2O)6]2+
- c) [Fe(H2O)6]2+
- d) [Ni(H2O)6]2+
Answer: [Ni(H2O)6]2+
Question: Which of the following will give a pair of enantiomorphs?
- a) [Pt(NH3)4][PtCl6]
- b) [Co(NH3)4Cl2]NO2
- c) [Cr(NH3)6][Co(CN)6]
- d) [Co(en)2Cl2]Cl (en = NH2CH2CH2NH2)
Answer: [Co(en)2Cl2]Cl (en = NH2CH2CH2NH2)
Question: [Co(NH3)4(NO2)2]Cl exhibits
- a) Linkage isomerism, ionization isomerism and optical isomerism
- b) Linkage isomerism, ionization isomerism and geometrical isomerism
- c) Ionization isomerism, geometrical isomerism and optical isomerism
- d) Linkage isomerism, geometrical isomerism and optical isomerism
Answer: Linkage isomerism, ionization isomerism and geometrical isomerism
Question: [Cr(H2O)6]Cl3(at. no of Cr = 24) has a magnetic moment of 3.83 BM, the correct distribution of 3d electrons in the chromium of the complex is
- a)
- b)
- c)
- d)
Answer:
Question: Which one of the following is an inner orbital complex as well as diamagnetic in behaviour? (Atomic No. : Zn = 30,Cr = 24, Co = 27, Ni = 28)
- a) [Zn(NH3)6]2+
- b) [Cr(NH3)6]3+
- c) [Co(NH3)6]3+
- d) [Ni(NH3)6]2+
Answer: [Co(NH3)6]3+
Question: Which one of the following is expected to exhibit optical isomerism ? (en = ethylenediamine)
- a) cis -[Pt (NH3)2Cl2]
- b) trans -[Co (en)2Cl2]
- c) trans -[Pt (NH3)2Cl2]
- d) cis -[Co(en)2Cl2]
Answer: trans -[Co (en)2Cl2]
Question: A co-ordination complex compound of cobalt has the molecular formula containing five ammonia molecules,one nitro group and two chlorine atoms for one cobalt atom. One mole of this compound produces three mole ions in an aqueous solution. On reacting this solution with excess of AgNO3 solution, we get two moles of AgCl as precipitate. The ionic formula for this complex would be
- a) [Co(NH3)5(NO2)] Cl2
- b) [Co(NH3)5Cl] [Cl(NO2)]
- c) [Co(NH3)4(NO2)Cl] (NH2) Cl
- d) [Co(NH3)5] [ (NO2)2Cl2]
Answer: [Co(NH3)5(NO2)] Cl2
Question: Shape of Fe(CO)5 is
- a) Octahedral
- b) Square planar
- c) Trigonal bipyramidal
- d) Square pyramidal
Answer: Trigonal bipyramidal
More Questions.....................................
Question: IUPAC name of [Pt(NH3)3(Br) (NO2)Cl] Cl is
- a) Triamminebromochloronitroplatinum (IV) chloride
- b) Triamminebromonitrochloroplatinum (IV) chloride
- c) Triamminechlorobromonitroplatinum (IV) chloride
- d) Triamminenitrochlorobromoplatinum (IV) chloride
Answer: Triamminebromochloronitroplatinum (IV) chloride
Question: Which of the following will give maximum number of isomers?
- a) [Co(NH3)4Cl2]
- b) [Ni(en) (NH3)4]2+
- c) [Ni (C2O4) (en)2]2–
- d) [Cr (SCN)2(NH3)4]+
Answer: [Cr (SCN)2(NH3)4]+
Question: Coordination number of Ni in [Ni (C2O4)3]4– is
- a) 3
- b) 6
- c) 4
- d) 2
Answer: 6
Question: Shape of Fe(CO)5 is
- a) Octahedral
- b) Square planar
- c) Trigonal bipyramidal
- d) Square pyramidal
Answer: Trigonal bipyramidal
Question: Which one of the following is expected to exhibit optical isomerism ? (en = ethylenediamine)
- a) cis -[Pt (NH3)2Cl2]
- b) trans -[Co (en)2Cl2]
- c) trans -[Pt (NH3)2Cl2]
- d) cis -[Co(en)2Cl2]
Answer: trans -[Co (en)2Cl2]
Question: The number of unpaired electrons in the complex ion [CoF6]3– is (Atomic no. : Co = 27)
- a) 2
- b) 3
- c) 4
- d) Zero
Answer: 4
Question: Atomic number of Cr and Fe are respectively 24 and 26, which of the following is paramagnetic?
- a) [Cr(CO)6]
- b) [Fe(CO)5]
- c) [Fe(CN)6]4–
- d) [Cr(NH3)6]3+
Answer: [Cr(NH3)6]3+
Question: According to IUPAC nomenclature sodium nitroprusside is named as
- a) Sodium nitroferricyanide
- b) Sodium nitroferrocyanide
- c) Sodium pentacyanonitrosyl ferrate (II)
- d) Sodium pentancyanonitrosyl ferrate (III)
Answer: Sodium pentacyanonitrosyl ferrate (II)
Question: The anion of acetylacetone (acac) forms Co(acac)3 chelate with Co3+. The rings of the chelate are
- a) Three membered
- b) Five membered
- c) Four membered
- d) Six membered
Answer: Six membered
Question: Which of the following coordination compounds would exhibit optical isomerism?
- a) Pentaamminenitrocobalt (III) iodide
- b) Diamminedichloroplatinum (II)
- c) Trans dicyanobis (ethylenediamine) chromium (III) chloride
- d) Tris-(ethylenediamine) cobalt (III) bromide
Answer: Tris-(ethylenediamine) cobalt (III) bromide
Question: Which one of the following octahedral complexes will not show geometric isomerism? (A and B are monodentate ligands)
- a) [MA2B4]
- b) [MA3B3]
- c) [MA4B2]
- d) [MA5B]
Answer: [MA5B]
Question: Atomic number of Cr and Fe are respectively 24 and 26, which of the following is paramagnetic?
- a) [Cr(CO)6]
- b) [Fe(CO)5]
- c) [Fe(CN)6]4–
- d) [Cr(NH3)6]3+
Answer: [Cr(NH3)6]3+
Question: Which of the following is not bidentate ligand?
- a) acac
- b) ox
- c) en
- d) dien
Answer: dien
Question: Which one of the following is an inner orbital complex as well as diamagnetic in behaviour? (Atomic No. : Zn = 30,Cr = 24, Co = 27, Ni = 28)
- a) [Zn(NH3)6]2+
- b) [Cr(NH3)6]3+
- c) [Co(NH3)6]3+
- d) [Ni(NH3)6]2+
Answer: [Co(NH3)6]3+
Question: The d electron configuration of Cr2+, Mn2+, Fe2+ and Ni2+ are 3d4, 3d5, 3d6 and 3d8 respectively. Which one of the following aqua complexes will exhibit the maximum paramagnetic behaviour? (At. No. Cr = 24, Mn = 25, Fe = 26,Ni = 28)
- a) [Fe(H2O)6]2+
- b) [Ni(H2O)6]2+
- c) [Cr(H2O)6]2+
- d) [Mn(H2O)6]2+
Answer: [Mn(H2O)6]2+
Question: Number of geometrical isomers possible for [MABCDEF] is
- a) 6
- b) 10
- c) 15
- d) 12
Answer: 15
Question: Which statement is incorrect?
- a) Ni(CO)4- tetrahedral, paramagnetic
- b) Ni(CN)4–2 - square planar, diamagnetic
- c) Ni(CO)4– tetrahedral, diamagnetic
- d) [Ni(Cl)4]–2 – tetrahedral, paramagnetic
Answer: Ni(CO)4- tetrahedral, paramagnetic
Question: A co-ordination complex compound of cobalt has the molecular formula containing five ammonia molecules,one nitro group and two chlorine atoms for one cobalt atom. One mole of this compound produces three mole ions in an aqueous solution. On reacting this solution with excess of AgNO3 solution, we get two moles of AgCl as precipitate. The ionic formula for this complex would be
- a) [Co(NH3)5(NO2)] Cl2
- b) [Co(NH3)5Cl] [Cl(NO2)]
- c) [Co(NH3)4(NO2)Cl] (NH2) Cl
- d) [Co(NH3)5] [ (NO2)2Cl2]
Answer: [Co(NH3)5(NO2)] Cl2
Question: Stability of the complex depends on
- a) Oxidation state
- b) Nature of ligand
- c) Geometry of complex
- d) All of these
Answer: All of these
Question: Which of the following is not organometallic complex?
- a) Grignard reagent
- b) Ferrocene
- c) Trans-platin
- d) Diethyl zinc
Answer: Trans-platin
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