Refer to NEET Chemistry Coordination Compounds MCQs Set B provided below. NEET Full Syllabus Chemistry MCQs with answers available in Pdf for free download. The MCQ Questions for Full Syllabus Chemistry with answers have been prepared as per the latest syllabus, NEET books and examination pattern suggested in Full Syllabus by NEET, NCERT and KVS. Multiple Choice Questions for Coordination Compounds are an important part of exams for Full Syllabus Chemistry and if practiced properly can help you to get higher marks. Refer to more Chapter-wise MCQs for NEET Full Syllabus Chemistry and also download more latest study material for all subjects
MCQ for Full Syllabus Chemistry Coordination Compounds
Full Syllabus Chemistry students should refer to the following multiple-choice questions with answers for Coordination Compounds in Full Syllabus. These MCQ questions with answers for Full Syllabus Chemistry will come in exams and help you to score good marks
Coordination Compounds MCQ Questions Full Syllabus Chemistry with Answers
Question: The total number of electrons donated by ligands to platinum ion in [Pt(en)2Cl2] is
- a) 8
- b) 10
- c) 12
- d) 14
Answer: 12
Question: The IUPAC name of [Ni(CN)4]2– is
- a) Tetracyanonickel (II) ion
- b) Tetracyanonickelate (II) ion
- c) Tetracyanonickel (0) ion
- d) Tetracyanonickelate (0) ion
Answer: Tetracyanonickelate (II) ion
Question: Out of following which ligand is a π acid ligand?
- a) CO
- b) NH3
- c) Cl–
- d) H2O
Answer: CO
Question: Which of the following is not an ambidentate ligand?
- a) CN–
- b)
- c) SCN–
- d) NH3
Answer: NH3
Question: Primary and secondary valencies of Cu in [Cu(NH3)4]SO4 is
- a) 4, 4
- b) 2, 4
- c) 4, 1
- d) 4, 2
Answer: 2, 4
Question: Oxidation number of platinum in cis-platin
- a) Zero
- b) +2
- c) +4
- d) +6
Answer: +2
Question: IUPAC name of K[BF4]
- a) Potassium tetrafluoroborate
- b) Tetrafluoroboron (III) potassium
- c) Potassiumtetrafluoridoborate (III)
- d) Tetrafluoridoboron (III) potassium
Answer: Potassiumtetrafluoridoborate (III)
Question: Aq. solution of KCl.MgCl2.6H2O will give test of
- a) K+ and Mg2+ only
- b) K+ and Cl– only
- c) K+, Mg2+ and Cl–
- d) Mg2+ and H2O only
Answer: K+, Mg2+ and Cl–
Question: Aqueous solution of CoCl3.6NH3 upon addition with AgNO3 produces 3 moles white precipitate. Primary and secondary valency of metal in this complex is
- a) 3, 6
- b) 2, 6
- c) 3, 3
- d) 6, 4
Answer: 3, 6
Question: Which of the following complex is homoleptic?
- a) H2[PtCl6]
- b) Li[AlH4]
- c) [Ni(CO)4]
- d) All of these
Answer: All of these
Question: Structural formula of tetraaquadichloridochromium(III) chloride
- a) [(H2O)4Cl2Cr]Cl2
- b) [Cl2(H2O)4Cr]Cl3
- c) [Cr(H2O)4Cl2]Cl
- d) [Cr(H2O)4Cl3]
Answer: [Cr(H2O)4Cl2]Cl
Question: Which of the following is not a polydentate ligand?
- a) Oxalate ion
- b) Ethylenediamine
- c) Thiocyanato
- d) EDTA
Answer: Thiocyanato
Question: The complex [Cr(H2O)5Cl]Br and [Cr(H2O)5Br]Cl shows
- a) Linkage isomerism
- b) Ionisation isomerism
- c) Hydrate isomerism
- d) Co-ordination isomerism
Answer: Ionisation isomerism
Question: Oxidation number of platinum in cis-platin
- a) Zero
- b) +2
- c) +4
- d) +6
Answer: +2
Question: Which of the following octahedral complexes do not show geometrical isomerism?
- a) [Co(NH3)3Cl3]
- b) [PtCl2(NH3)4]
- c) [Pt(NH3)2Cl2]
- d) [Co(en)3]3+
Answer: [Co(en)3]3+
Question: Coordination isomerism exhibited by
- a) [Cr(en)2Cl2]NO2
- b) [Co(NH3)5Br]SO4
- c) [Pt(NH3)4] [CuCl4]
- d) [Co(NH3)5Cl]Cl2
Answer: [Pt(NH3)4] [CuCl4]
Question: Which one of the following complexes will have six isomers?
- a) [Co(en)NH3Cl2]Cl
- b) [Cr(H2O)4Cl2]Cl
- c) [Co(ox)3]3–
- d) [Co(en)2Br2]Cl
Answer: [Co(en)2Br2]Cl
Question: How many isomers are possible in [Cr(en)2Br2]?
- a) 2
- b) 3
- c) 6
- d) 1
Answer: 3
Question: The hybridisation of Ni in [Ni(CO)4] is
- a) sp3
- b) dsp2
- c) sp2
- d) sp3d
Answer: sp3
Question: Which of the following is/are inner orbital complex?
- a) [Fe(CN)6]4–
- b) [Cr(NH3)6]3+
- c) [Mn(CN)6]3–
- d) All of these
Answer: All of these
Question: Number of unpaired electrons present in [Ni(H2O)6]2+
- a) Two
- b) One
- c) Four
- d) Three
Answer: Two
Question: The spin magnetic moment of iron in K3[Fe(CN)6]
- a) √3 BM
- b) √5 BM
- c) √15 BM
- d) √24 BM
Answer: √3 BM
Question: Which one of the following is paramagnetic in nature?
- a) Ni(CO)4
- b) [Ni(CN)4]2–
- c) K4[Fe(CN)6]
- d) [FeF6]4–
Answer: [FeF6]4–
Question: Which of the following does not show optical activity?
- a) [Co(NH3)4Cl2]
- b) [Cr(ox)3]3–
- c) [Co(ox)2(NH3)2]Cl
- d) [Co(en)(NH3)2(H2O)2]Cl2
Answer: [Co(NH3)4Cl2]
Question: [Fe(H2O)6]3+ and [Fe(CN)6]3– differ in
- a) Oxidation number
- b) Coordination number
- c) Structure
- d) Magnetic nature
Answer: Magnetic nature
Question: The spin only magnetic moment of [MnBr4]2– is 5.9 B.M. Geometry of the complex ion is
- a) Tetrahedral
- b) Octahedral
- c) Square planar
- d) Pentagonal pyramidal
Answer: Tetrahedral
Question: Which of the following statements are incorrect?
- a) If Δ0< P, high spin state is more stable
- b) NO2 is a strong ligand
- c) Colour of a complex depends upon nature of metal ion only
- d) Δ0> Δt
Answer: Colour of a complex depends upon nature of metal ion only
Question: According to crystal field theory, five d-orbitals of an octahedral complex split to give
- a) Two orbitals with lower energy and three orbitals with higher energy
- b) Three orbitals with lower energy and two orbitals with higher energy
- c) One orbital with lower energy and four orbitals with higher energy
- d) Four orbitals with lower energy and one orbital with higher energy
Answer: Three orbitals with lower energy and two orbitals with higher energy
Question: Which of the following complex is most stable?
- a) [M(NH3)6]2+
- b) [M(NH3)6]3+
- c) [Men2(NH3)2]3+
- d) [M(en)3]3+
Answer: [M(en)3]3+
Question: In the formation of octahedral complex, ligands approach towards _______ and _______ orbital of central metal.
- a) dxy,dx2- y2
- b) dx2- y2,dz2
- c) dxy, dyz
- d) dz2, dxz
Answer: dx2- y2,dz2
More Questions............................................
Question: Which reagent can be used to identify Ni2+ ion?
- a) Resorcinol
- b) Dimethyl glyoxime
- c) Diphenyl benzidine
- d) Potassium ferrocyanide
Answer: Dimethyl glyoxime
Question: Which of the following is not organometallic complex?
- a) Grignard reagent
- b) Ferrocene
- c) Trans-platin
- d) Diethyl zinc
Answer: Trans-platin
Question: Stability of the complex depends on
- a) Oxidation state
- b) Nature of ligand
- c) Geometry of complex
- d) All of these
Answer: All of these
Question: π bonding is not involved in
- a) Ferrocene
- b) Dibenzene chromium
- c) Zeise’s salt
- d) Grignard reagent
Answer: Grignard reagent
Question: Which of the following will show optical activity?
- a)
- b)
- c) [Co(NH3)6]3+
- d)
Answer:
Question: Which is a diamagnetic complex?
- a) [Fe(H2O)6]3+
- b) [Fe(H2O)6]2+
- c) [Fe(CN)6]3–
- d) [Fe(CN)6]4–
Answer: [Fe(CN)6]4–
Question: The hybridization of 'Cr' in the complex [Cr(NO2)4 (NH3)2]- is
- a) sp3d2
- b) sp3d
- c) d2sp3
- d) sp3
Answer: d2sp3
Question: IUPAC name of H2[PtCl6] is
- a) Dihydrogen hexachloridoplatinum (IV)
- b) Hexachloridoplatinic (IV) acid
- c) Dihydrogen hexachloridoplatinic (IV) acid
- d) Hexachloridoplatinum (IV) acid
Answer: Hexachloridoplatinic (IV) acid
Question: The geometry of [Ni(CO)4] and [PdCl4]2– respectively are
- a) Both are tetrahedral
- b) Both are square planar
- c) Square planar and tetrahedral
- d) Tetrahedral and square planar
Answer: Tetrahedral and square planar
Question: Write the increasing order of the value is CFSES (Δ0) for the following species
I. [Co(NH3)6]3+
II. [Rh(NH3)6]3+
III. [Ir(NH3)6]3+
- a) III < II < I
- b) I < II < III
- c) II < I < III
- d) I < III < II
Answer: I < II < III
Question: Which of the following is correct statement?
- a) [Ti(H2O)6]3+ is coloured complex
- b) [Si(H2O)6]4+ is colourless complex
- c) d - d transition is not possible in [Si(H2O)6]4+ complex
- d) All of these
Answer: All of these
Question: Which of the following will have greatest molar conductance at infinite dilution?
- a) [Pt(NH3)5Cl]Cl3
- b) [Pt(NH3)4Cl2]Cl2
- c) [Pt(NH3)2Cl4]
- d) [Pt(NH3)6]Cl4
Answer: [Pt(NH3)6]Cl4
Question: Which of the following is the high spin complex?
- a) [Cr(gly)3]
- b) [CoBr2Cl2(SCN)2]3–
- c) [Fe(CN)6]3–
- d) Na[PtBrCl(NO2)2(NH3)2]
Answer: [CoBr2Cl2(SCN)2]3–
Question: The coordination number and magnetic moment of the complex [Cr(C2O4)2(NH3)2]– respectively is
- a) 6, 3.87 BM
- b) 4, 3.87 BM
- c) 6, 3.46 BM
- d) 4, 1.73 BM
Answer: 6, 3.87 BM
Question: Number of geometrical isomers possible for [MABCDEF] is
- a) 6
- b) 10
- c) 15
- d) 12
Answer: 15
Question: How many optical isomers are possible for [MABCD]?
- a) 1
- b) 2
- c) 3
- d) Zero
Answer: Zero
Question: [Ni(gly)2] shows two stereoisomers. Those are
- a) Geometrical
- b) Optical
- c) Does not show isomerism
- d) Both (1) & (2)
Answer: Optical
Question: Naming of ligand in [M(en)2]n+ starts with
- a) Di
- b) Bi
- c) Bis
- d) Any of these
Answer: Bis
Question: Which of the following has primary valency “2”?
- a) [Co(NH3)5Cl]Cl
- b) [Co(NH3)4Cl2]Cl
- c) [Co(NH3)3Cl3]
- d) [Co(H2O)4Cl2]Cl
Answer: [Co(NH3)5Cl]Cl
Question: If the value of C.F.S.E. for “Ni” is Δ0 then it is for Pd should be
- a) 1.1Δ0
- b) 0.5 Δ0
- c) 1.5 Δ0
- d) 2 Δ0
Answer: 1.5 Δ0
Question: Ligand to form a complex which is used to treat hard water
- a) NH3
- b) ox
- c) en
- d) EDTA
Answer: EDTA
Question: Which of the following is not bidentate ligand?
- a) acac
- b) ox
- c) en
- d) dien
Answer: dien
Question: Which of the following is flexidentate?
- a) CO
- b) en
- c) EDTA
- d) Cl–
Answer: EDTA
Question: The value of ‘spin only’ magnetic moment, follows the correct order?
- a) [Fe(CN)6]4– > [CoCl4]2– > [MnCl4]2–
- b) [MnCl4]2– > [Fe(CN)6]4– > [CoCl4]2–
- c) [Fe(CN)6]4– > [MnCl4]2– > [CoCl4]2–
- d) [MnCl4]2– > [CoCl4]2– > [Fe(CN)6]4–
Answer: [MnCl4]2– > [CoCl4]2– > [Fe(CN)6]4–
Question: How many hydrogen bonded water molecules are present in blue vitriol?
- a) Zero
- b) One
- c) Four
- d) Five
Answer: One
Question: If Δ0 is the crystal field stabilisation energy of a ligand and P is the energy required for electron pairing in an orbital, then ligand is called weak ligand if
- a) Δ0> P
- b) Δ0< P
- c) Δ0= P
- d) Unpredictable
Answer: Δ0< P
Question: The complex compound bearing square planar geometry is
- a) Ni(CO)4
- b) [Ni(CN)4]2–
- c) [Mn(CN)6]3–
- d) [MnCl4]2–
Answer: [Ni(CN)4]2–
Question: The complex compound having maximum magnetic moment is
- a) [CoF6]3–
- b) [Cr(NH3)6]3+
- c) [FeF6]3–
- d) [Mn(CN)6]4–
Answer: [FeF6]3–
Question: Which of the following is not π-acid ligand?
- a) CO
- b) F–
- c) C2H4
- d) NO+
Answer: F–
Question: The complex compound in which metal is not present in zero oxidation state?
- a) Mn2(CO)10
- b) [Ni(CO)4]
- c) [Cr(C6H6)2]
- d) K[PtCl3(C2H4)]
Answer: K[PtCl3(C2H4)]
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