NCERT Class 12 Chemistry Solutions Coordination Compounds

NCERT Class 12 Chemistry Solutions Coordination Compounds - NCERT Solutions prepared for CBSE students by the best teachers in Delhi. 

Class XII  Chemistry

Chapter 9 – Coordination Compounds

Question 1:

Explain the bonding in coordination compounds in terms of Werner’s postulates.

Answer

Werner’s postulates explain the bonding in coordination compounds as follows:

(i) A metal exhibits two types of valencies namely, primary and secondary valencies. Primary valencies are satisfied by negative ions while secondary valencies are satisfied by both negative and neutral ions.

(In modern terminology, the primary valency corresponds to the oxidation number of the metal ion, whereas the secondary valency refers to the coordination number of the metalion.

(ii) A metal ion has a definite number of secondary valencies around the central atom. Also, these valencies project in a specific direction in the space assigned to the definite geometry of the coordination compound.

(iii) Primary valencies are usually ionizable, while secondary valencies are non-ionizable.

 

Question 2:

Explain with two examples each of the following: coordination entity, ligand, coordination number, coordination polyhedron, homoleptic and heteroleptic.

Answer

(i) Coordination entity: A coordination entity is an electrically charged radical or species carrying a positive or negative charge. In a coordination entity, the central atom or ion is surrounded by a suitable number of neutral molecules or negative ions ( called ligands). 

(ii) Ligands: The neutral molecules or negatively charged ions that surround the metal atom in a coordination entity or a coordinal complex are known as ligands. 

(iii) Coordination number: The total number of ligands (either neutral molecules or negative ions) that get attached to the central metal atom in the coordination sphere is called the coordination number of the central metal atom. It is also referred to as its ligancy.

 

Question 3:

Using IUPAC norms write the formulas for the following:

(i) Tetrahydroxozincate(II)

(ii) Potassium tetrachloridopalladate(II)

(iii) Diamminedichloridoplatinum(II)

(iv) Potassium tetracyanonickelate(II)

(v) Pentaamminenitrito-O-cobalt(III)

(vi) Hexaamminecobalt(III) sulphate

(vii) Potassium tri(oxalato)chromate(III)

(viii) Hexaammineplatinum(IV)

(ix) Tetrabromidocuprate(II)

(x) Pentaamminenitrito-N-cobalt(III) 


Students should free download the NCERT solutions and get better marks in exams. Studiestoday.com panel of teachers recommend students to practice questions in NCERT books and download NCERT solutions.

Tags: 

 


Click to View or Download pdf file
Click for more Chemistry Study Material

Latest NCERT & CBSE News

Read the latest news and announcements from NCERT and CBSE below. Important updates relating to your studies which will help you to keep yourself updated with latest happenings in school level education. Keep yourself updated with all latest news and also read articles from teachers which will help you to improve your studies, increase motivation level and promote faster learning

Revised Datesheet for Class 10 and 12 Board Exams

Revised date sheet for Class 12 - scroll down for datesheet for class 10 Revised datesheet for Class 10

Latest CBSE Syllabus for 2021 2022 PDF Download

Latest Syllabus for Class 12 for 2021 2022 Latest Syllabus for Class 11 for 2021 2022 Latest Syllabus for Class 10 for 2021 2022 Latest Syllabus for Class 9 for 2021 2022 CBSE has issued the latest syllabus for the academic year 2021 2022 which is applicable for all...

Time management for CBSE students

The first thing to learn about Time Management is that time is theoretical so you can’t really manage it. What you do when you get into time management, is that you manage yourself. You decide what has to be done, when it must be done and how to do it in the stipulated...

SOF Science Olympiad Foundation

SOF~ The most desired name for Olympiads in the Educational World! SOF” refers to the Science Olympiad Foundation. It is an Academic Institution assisting educational based competition and enhancing competitive spirit among the School- Level students. The Science...

SOF IMO International Mathematics Olympiad

SOF IMO refers to the International Mathematics Olympiad organised by SOF, the Science Olympiad Foundation. SOF is the educational foundation involved in the academic upgradation of students. This Olympiad is a maths competitive examination conducted for the aspiring...

Pariksha pe charcha 2021 video released by CBSE

Pariksha pe charcha 2021 video released by CBSE

×
Studies Today