CBSE Class 12 Chemistry 2025 Sample Paper Set 05 Solved

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SECTION A

Q.1 Which of the following aldehydes will undergo disproportionation with conc. NaOH to give corresponding alcohol and acid?
a) (CH3)3CCHO
b) C6H5CHO
c) HCHO
d) All of these

Answer : d

Q.2 A hexadentate ligand is used in treatment of lead poisoning. Identify the ligand
a) Ethane-1,2-diamine
b) EDTA
c) Dimethylglyoxime
d) oxalate

Answer : b

Q.3 The best reagent for converting, 2-phenylpropanamide into 1-phenylethanamine is:
a) excess H2/Pt
b) NaOH/Br2
c) NaBH4
d) LiAlH4/ether

Answer : b

Q.4 Total vapour pressure of a mixture of 1 mol A (pA° = 150 torr) and 2 moles B (pB° = 240 torr) is 200 torr. In this case: -
a) There is a positive deviation from Raoult's law
b) There is a negative deviation from Raoult's law
c) There is no deviation from Raoult's law
d) None of these

Answer : b

Q.5 Match the properties with the elements of 3d series:
(i) Element with highest M.P. in 3d series        (p) Cr3+
(ii) Element showing +3 oxidation state only   (q) Cr
(iii) Most stable ion in aqueous solution           (r) Fe
                                                                        (s) Sc
a) (i) (q), (ii) (s),(iii) (p)
b) (i) (s),(ii) (q),(iii) (r)
c) (i) (q), (ii) (p), (iii) (r)
d) (i) (p),(ii) (q),(iii) (r)

Answer : a

Q.6 SN1 reaction of alkyl halides lead to
a) Retention of configuration
b) Racemisation
c) Inversion of configuration
d) None of these

Answer : b

Q.7 Which of the following alcohol reacts fastest with conc. HCl and anhydrous ZnCl2
a) Butan-1-ol
b) Butan-2-ol
c) 2-Methylbutan-1-ol
d) 2-Methylpentan-2-ol

Answer : d

Q.8 The correct statement about charging of the lead storage battery is:
a) PbSO4 at anode is reduced to Pb.
b) PbSO4 at cathode is reduced to Pb.
c) PbSO4 at cathode is oxidised to Pb.
d) PbSO4 at anode is oxidised to PbO2.

Answer : a

Q.9 If the rate of the reaction is equal to the rate constant, the order of the reaction is
a) 3
b) 0
c) 1
d) 2

Answer : b

 

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