NCERT Class 11 Chemistry Organic Chemistry Some Basic Priciples and Techniques

Read and download NCERT Class 11 Chemistry Organic Chemistry Some Basic Priciples and Techniques chapter in NCERT book for Class 11 Chemistry. You can download latest NCERT eBooks for 2022 chapter wise in PDF format free from Studiestoday.com. This Chemistry textbook for Class 11 is designed by NCERT and is very useful for students. Please also refer to the NCERT solutions for Class 11 Chemistry to understand the answers of the exercise questions given at the end of this chapter

Organic Chemistry Some Basic Principles And Techniques Class 11 Chemistry NCERT

Class 11 Chemistry students should refer to the following NCERT Book chapter Organic Chemistry Some Basic Principles And Techniques in standard 11. This NCERT Book for Grade 11 Chemistry will be very useful for exams and help you to score good marks

Organic Chemistry Some Basic Principles And Techniques NCERT Class 11

ORGANIC CHEMISTRY – SOME BASIC PRINCIPLES

AND TECHNIQUES

In the previous unit you have learnt that the element carbon has the unique property called catenation due to which it forms covalent bonds with other carbon atoms. It also forms covalent bonds with atoms of other elements like hydrogen, oxygen, nitrogen, sulphur, phosphorus and halogens. The resulting compounds are studied under a separate branch of chemistry called organic chemistry. This unit incorporates some basic principles and techniques of analysis required for understanding the formation and properties of organic compounds.

12.1 GENERAL INTRODUCTION

Organic compounds are vital for sustaining life on earth and include complex molecules like genetic information bearing deoxyribonucleic acid (DNA) and proteins that constitute essential compounds of our blood, muscles and skin. Organic chemicals appear in materials like clothing, fuels, polymers, dyes and medicines.

These are some of the important areas of application of these compounds. Science of organic chemistry is about two hundred years old. Around the year 1780, chemists began to distinguish between organic compounds obtained from plants and animals and inorganic compounds prepared from mineral sources. Berzilius, a Swedish chemist proposed that a ‘vital force’ was responsible for the formation of organic compounds. However, this notion was rejected in 1828 when F. Wohler synthesised an organic compound, urea from an inorganic compound, ammonium cyanate.

                                 NH4 CNO → NH2CONH2

The pioneering synthesis of acetic acid by Kolbe (1845) and that of methane by Berthelot (1856) showed conclusively that organic compounds could be synthesised from inorganic sources in a laboratory.

The development of electronic theory of covalent bonding ushered organic chemistry into its modern shape.

12.2 TETRAVALENCE OF CARBON: SHAPES OF ORGANIC COMPOUNDS

12.2.1 The Shapes of Carbon Compounds

The knowledge of fundamental concepts of molecular structure helps in understanding and predicting the properties of organic compounds. You have already learnt theories of valency and molecular structure in Unit 4. Also, you already know that tetravalence of carbon and the formation of covalent bonds by it are explained in terms of its electronic configuration and the hybridisation of s and p orbitals. It may be recalled that formation and the shapes of molecules like methane (CH4), ethene (C2H4), ethyne (C2H2) are explained in terms of the use of sp3, sp2 and sp hybrid orbitals by carbon atoms in the respective molecules.

Hybridisation influences the bond length and bond enthalpy (strength) in organic compounds. The sp hybrid orbital contains more s character and hence it is closer to its nucleus and forms shorter and stronger bonds than the sp3 hybrid orbital. The sp2 hybrid orbital is intermediate in s character between sp and sp3 and, hence, the length and enthalpy of the bonds it forms, are also intermediate between them. The change in hybridisation affects the electronegativity of carbon. The greater the s character of the hybrid orbitals, the greater is the

electronegativity. Thus, a carbon atom having an sp hybrid orbital with 50% s character is more electronegative than that possessing sp2 or sp3 hybridised orbitals. This relative electronegativity is reflected in several physical and chemical properties of the molecules concerned, about which you will learn in later units.

12.2.2 Some Characteristic Features of π Bonds

In a π (pi) bond formation, parallel orientation of the two p orbitals on adjacent atoms is necessary for a proper sideways overlap. Thus, inH2C=CH2 molecule all the atoms must be in the same plane. The p orbitals are mutually parallel and both the p orbitals are perpendicular to the plane of the molecule. Rotation of one CH2 fragment with respect to other interferes with maximum overlap of p orbitals and, therefore, such rotation about carbon-carbon double bond (C=C) is restricted. The electron charge cloud of the π bond is located above and below the plane of bonding atoms. This results in the electrons being easily available to the attacking reagents. In general, π bonds provide  the most reactive centres in the molecules containing multiple bonds.


Please refer to attached file for NCERT Class 11 Chemistry Organic Chemistry- Some Basic Priciples and Techniques

Tags: 

 


Click to View or Download pdf file
Click for more Chemistry Study Material
Chapter 1 Some Basic Concepts of Chemistry
NCERT Class 11 Chemistry Some Basic Concepts Of Chemistry
Chapter 2 Structure of Atom
NCERT Class 11 Chemistry Structure of Atom
Chapter 3 Classification of Elements and Periodicity in Properties
NCERT Class 11 Chemistry Classification of Elements and Periodicity In Properties
Chapter 4 Chemical Bonding and Molecular Structure
NCERT Class 11 Chemistry Chemical Bonding and Molecular Structure
Chapter 5 States of Matter
NCERT Class 11 Chemistry State Of Matter
Chapter 6 Thermodynamics
NCERT Class 11 Chemistry Thermodynamics
Chapter 7 Equilibrium
NCERT Class 11 Chemistry Equilibrium
Chapter 8 Redox Reactions
NCERT Class 11 Chemistry Redox Reactions
Chapter 9 Hydrogen
NCERT Class 11 Chemistry Hydrogen
Chapter 10 The s-Block Elements
NCERT Class 11 Chemistry The s Block Elements
Chapter 11 The p-Block Elements
NCERT Class 11 Chemistry The p Block Elements
Chapter 12 Organic Chemistry – Some Basic Principles & Techniques
NCERT Class 11 Chemistry Organic Chemistry Some Basic Priciples and Techniques
Chapter 13 Hydrocarbons
NCERT Class 11 Chemistry Hydrocarbons
Chapter 14 Environmental Chemistry
NCERT Class 11 Chemistry Environmental Chemistry
Other Chapters
NCERT Class 11 Chemistry Lab Manual Purification and Criteria of Purity
NCERT Class 11 Chemistry Lab Manual Systematics Qualitative Analysis
NCERT Class 11 Chemistry Lab Manual Basic Laboratory Techniques
NCERT Class 11 Chemistry Lab Manual Titrimetric Analysis
NCERT Class 11 Chemistry Lab Manual Chemical Equilibrium Ionic Equilibrium
NCERT Class 11 Chemistry Lab Manual Information about Investigatory Projects
NCERT Class 11 Chemistry Lab Manual Introduction
NCERT Class 11 Chemistry Lab Manual ph and ph change in Aqueous Solutions
Part I Answer to Some Selected Problems
NCERT Class 11 Chemistry Answer of Some Selected Problems
Part I Appendices
NCERT Class 11 Chemistry Appendix 3
NCERT Class 11 Chemistry Appendix 4 Physical Constants
NCERT Class 11 Chemistry Appendix 5 Some Useful Conversion Factores
NCERT Class 11 Chemistry Appendix 6 Thernodynamic Data at 298 K
NCERT Class 11 Chemistry Appendix 7 Standard Potentials at 298 K in Electrochemical order
NCERT Class 11 Chemistry Appendix 1
NCERT Class 11 Chemistry Appendix 2 Elements Their Atomic Number and Molar Mass
Part II Answer to Some Selected Problems
NCERT Class 11 Chemistry Answer to Some Selected Problems

Latest NCERT & CBSE News

Read the latest news and announcements from NCERT and CBSE below. Important updates relating to your studies which will help you to keep yourself updated with latest happenings in school level education. Keep yourself updated with all latest news and also read articles from teachers which will help you to improve your studies, increase motivation level and promote faster learning

CBSE Term 2 Board Examinations

CBSE vide Circular No.Acad-51/2021 dated 5th July, 2021, notified that in the session 2021-2022, Board Examinations would be conducted in two terms, i.e.. Term I and Term II. This decision was taken due to the uncertainty arising out of COVID 19 Pandemic. Term I...

CBSE OMR Sheet Guidelines for Term 1

You are aware that the CBSE will be using OMR for the first time for assessment of both the Classes-X and XII in Term-I examinations. Hence, there is a need that all the students appearing in the Term-l examinations and the schools sponsoring these students should have...

All India Children Educational Audio Video Festival

The Central Institute of Educational Technology (CIET), a constituent unit of National Council of Educational Research and Training (NCERT), is inviting entries for the 26th All India Children’s Educational Audio Video Festival (AICEAVF). This festival showcases the...

Board Exams Date Sheet Class 10 and Class 12

Datesheet for CBSE Board Exams Class 10  (Scroll down for Class 12 Datesheet) Datesheet for CBSE Board Exams Class 12

Surya Namaskar Project on 75th Anniversary of Independence Day

Ministry of Education, Govt of India vide letter No. F.No. 12-5/2020-IS-4 dated 16.12.2021 has intimated that under the banner Azadi ka Amrit Mahotsav the National Yogasanasports Federation has decided to run a project of 750 million Surya Namaskar from 01 January 2022...

National Youth Day and Birth Anniversary of Swami Vivekananda

Ministry of Education, Govt. of India vide D.O No. 12-4/2021-IS.4 dated 04.01.2022 intimated that 12 January 2022 will be celebrated as “National Youth Day” and “Birth Anniversary of Swami Vivekananda”.   All Schools affiliated to CBSE may celebrate 12 January 2022 as...