CBSE Class 12 Chemistry Amines MCQs Set 11

Practice MCQs for Class 12 Chemistry Unit 9 Amines

Review structured MCQ sets for Class 12 Chemistry Unit 9 Amines. Built according to official CBSE guidelines, these downloadable questions support daily revision and core concept reinforcement.

Access Unit 9 Amines Questions and Solutions

Access the complete set of multiple-choice questions for Unit 9 Amines below. This focused format allows students to isolate specific topics for thorough review and uninterrupted practice alongside official CBSE textbooks.

Multiple Choice Questions

Question 1: Acid anhydrides on reaction with primary amines give ________. [NCERT Exemplar]
(a) amide
(b) imide
(c) secondary amine
(d) imine
Show Answer & Explanation

Answer: (a) amide

Explanation:
1. C2H5NH2 + (CH3CO)2O → CH3CONHC2H5 (N-Ethylacetamide) + CH3COOH

Teacher's Note:
1. This is acylation: the acyl group replaces an H on nitrogen, so 1° and 2° amines react but 3° amines do not.

Question 2: Which is the weakest base?
(a) Aniline, C6H5NH2
(b) Piperidine, C5H10NH
(c) Cyclohexylamine, C6H11NH2
(d) CH3NH2
Show Answer & Explanation

Answer: (a) Aniline, C6H5NH2

Explanation:
1. In aniline the lone pair on nitrogen is delocalised into the benzene ring by resonance, so it is less available for protonation.
2. The other three are aliphatic amines whose lone pair is localised, so aniline is the weakest base.

Teacher's Note:
1. Cyclohexylamine and aniline look similar on paper, but only the aromatic ring pulls the lone pair into resonance.

Question 3: CH3CH2COOH NH3
⟶
A Δ
⟶
B Br2/KOH
⟶
C
The structure of ‘C’ would be
(a) CH3CH2CONH2
(b) CH3CH2NHCH3
(c) CH3CH2NH2
(d) CH3CH2CH2NH2
Show Answer & Explanation

Answer: (c) CH3CH2NH2

Explanation:
1. A is the ammonium salt CH3CH2COONH4, which on heating gives the amide B, CH3CH2CONH2.
2. Hoffmann bromamide degradation of B gives C, CH3CH2NH2, an amine with one carbon atom less.

Teacher's Note:
1. Hoffmann bromamide degradation always removes one carbon – count carbons in the amide and the product to check.

Question 4: C6H5NH2 NaNO2
⟶
HCl
B C6H5N(CH3)2
⟶
cold
C
The structure of ‘C’ would be
(a) o-CH3C6H4–N=N–C6H4CH3-o
(b) o-CH3C6H4–NH–NH–C6H4–N(CH3)2-p
(c) C6H5–N=N–C6H4–N(CH3)2-p
(d) C6H5–N=N–CH2–N(CH3)–C6H5
Show Answer & Explanation

Answer: (c) C6H5–N=N–C6H4–N(CH3)2-p

Explanation:
1. Aniline with NaNO2/HCl at 273–278 K gives benzenediazonium chloride (B).
2. B couples with N,N-dimethylaniline at the para position to give p-(dimethylamino)azobenzene (C), a yellow dye.

Teacher's Note:
1. Coupling takes place at the para position of the activated ring; the –N=N– azo link is retained.

Question 5: The method by which aniline cannot be prepared is:
(a) reduction of nitrobenzene with H2/Pd in ethanol
(b) potassium salt of phthalimide treated with chlorobenzene
(c) hydrolysis of phenyl isocyanide with acidic solution
(d) degradation of benzamide with bromine in alkaline medium
Show Answer & Explanation

Answer: (b) potassium salt of phthalimide treated with chlorobenzene

Explanation:
1. Gabriel phthalimide synthesis needs nucleophilic substitution of the halide by the phthalimide anion.
2. Aryl halides such as chlorobenzene do not undergo nucleophilic substitution easily, so aromatic primary amines cannot be made this way.

Teacher's Note:
1. Gabriel synthesis gives only primary aliphatic amines – a favourite exam statement.

Question 6: In the chemical reaction:
CH3CH2NH2 + CHCl3 + 3KOH → A + B + 3H2O
The compounds A and B are respectively:
(a) CH3CH2CONH2 and 3KCl
(b) CH3CH2NC and K2CO3
(c) CH3CH2NC and 3KCl
(d) CH3CH2CN and 3KCl
Show Answer & Explanation

Answer: (c) CH3CH2NC and 3KCl

Explanation:
1. This is the carbylamine reaction of a primary amine.
2. CH3CH2NH2 + CHCl3 + 3KOH → CH3CH2NC + 3KCl + 3H2O; the foul-smelling ethyl isocyanide is formed.

Teacher's Note:
1. Only primary amines give the carbylamine test; balance it by noting that 3 Cl atoms end up as 3KCl.

Question 7: Considering the basic strength of amines in aqueous solution, which one has the smallest pKb value?
(a) (CH3)2NH
(b) C6H5NH2
(c) CH3NH2
(d) (CH3)3N
Show Answer & Explanation

Answer: (a) (CH3)2NH

Explanation:
1. In aqueous solution the order of basicity of methylamines is (CH3)2NH > CH3NH2 > (CH3)3N, due to combined inductive, solvation and steric effects.
2. Aniline is the weakest base. The strongest base, (CH3)2NH, has the smallest pKb.

Teacher's Note:
1. Smaller pKb means stronger base; in water the secondary methylamine is the strongest.

Question 8: Which of the following compounds will give a significant amount of meta product during mono-nitration?
(a) Phenol, C6H5OH
(b) Phenyl acetate, C6H5OCOCH3
(c) Aniline, C6H5NH2
(d) Acetanilide, C6H5NHCOCH3
Show Answer & Explanation

Answer: (c) Aniline, C6H5NH2

Explanation:
1. In the strongly acidic nitrating mixture, aniline is protonated to the anilinium ion, C6H5NH3+.
2. The –NH3+ group is meta-directing, so about 47% m-nitroaniline is formed.

Teacher's Note:
1. Protect the amino group by acetylation when you want mainly the para nitro product.

Question 9: The final product (C) in the following sequence of reactions is:
C6H5NH2 Br2/H2O
⟶
A NaNO2
⟶
HCl
B (i) HBF4
⟶
(ii) Δ
C
(a) 4-nitro-2-fluoro-N-bromoaniline
(b) 2-bromo-4-fluorotoluene
(c) 4-bromo-2,6-difluoroaniline
(d) 1,3,5-tribromo-2-fluorobenzene
Show Answer & Explanation

Answer: (d) 1,3,5-tribromo-2-fluorobenzene

Explanation:
1. Aniline with bromine water gives 2,4,6-tribromoaniline (A), which is diazotised to the diazonium salt (B).
2. B with HBF4 gives the diazonium fluoroborate, which on heating gives 2,4,6-tribromofluorobenzene, i.e. 1,3,5-tribromo-2-fluorobenzene (C).

Teacher's Note:
1. Balz–Schiemann reaction (HBF4, then heat) is the way to put F on a benzene ring.

Question 10: In the reaction
p-CH3C6H4CONH2 (i) NaOH, Br2
⟶
(ii) C6H5COCl
A
the structure of product A is:
(a) p-CH3C6H4–NH–CO–C6H5
(b) p-CH3C6H4–CO–O–CO–C6H5
(c) C6H5–NH–CO–C6H4–CH3-p
(d) p-CH3C6H4–CO–NH–CO–C6H5
Show Answer & Explanation

Answer: (a) p-CH3C6H4–NH–CO–C6H5

Explanation:
1. Hoffmann bromamide degradation of p-toluamide gives p-toluidine, p-CH3C6H4NH2.
2. Benzoylation of p-toluidine with C6H5COCl gives the amide p-CH3C6H4NHCOC6H5.

Teacher's Note:
1. In Hoffmann degradation the –CONH2 carbon is lost and N becomes attached directly to the ring.

Question 11: A positive carbylamine test is given by
(a) N,N-Dimethylaniline
(b) 2,4-Dimethylaniline
(c) N-Methyl-o-methylaniline
(d) N-Methylbenzylamine
Show Answer & Explanation

Answer: (b) 2,4-Dimethylaniline

Explanation:
1. The carbylamine test is given only by primary amines (aliphatic or aromatic).
2. 2,4-Dimethylaniline is a primary amine; the others are secondary or tertiary amines.

Teacher's Note:
1. Look at the nitrogen, not the ring: methyl groups on the ring do not change a primary amine into a secondary one.

Question 12: Which of the following reactions forms benzylamine?
(a) C6H5NO2 Sn/HCl
⟶

(b) C6H5CONH2 NaOBr
⟶

(c) C6H5CN H+/H2O
⟶

(d) Phthalimide (i) KOH
⟶
(ii) C6H5CH2Br, (iii) aq. OH−
Show Answer & Explanation

Answer: (d) Phthalimide (i) KOH
⟶
(ii) C6H5CH2Br, (iii) aq. OH−

Explanation:
1. Gabriel phthalimide synthesis: potassium phthalimide reacts with benzyl bromide to give N-benzylphthalimide, which on alkaline hydrolysis gives benzylamine, C6H5CH2NH2.
2. Sn/HCl gives aniline, NaOBr (Hoffmann) gives aniline, and acid hydrolysis of C6H5CN gives benzoic acid.

Teacher's Note:
1. Benzyl halides react readily in Gabriel synthesis, unlike aryl halides.

Question 13: Which reagent among the following can effect the conversion?
CH3–C≡N → CH3CH2NH2
(a) H3O+ (hydrolysis)
(b) Ammoniacal AgNO3
(c) LiAlH4
(d) NaBH4
Show Answer & Explanation

Answer: (c) LiAlH4

Explanation:
1. Nitriles are reduced to primary amines by LiAlH4 (or by H2/Ni or Pt).
2. NaBH4 is too mild to reduce the C≡N group, and acid hydrolysis gives a carboxylic acid.

Teacher's Note:
1. Reduction of a nitrile adds a CH2 to the amine: R–CN gives R–CH2NH2, so the carbon count stays the same.

Question 14: In which of the following pairs of amines does the first have a lower pKb value than the second?
(a) aniline, m-nitroaniline
(b) m-toluidine, p-toluidine
(c) p-chloroaniline, aniline
(d) aniline, p-aminophenol
Show Answer & Explanation

Answer: (a) aniline, m-nitroaniline

Explanation:
1. Lower pKb means stronger base. The electron-withdrawing –NO2 group makes m-nitroaniline a weaker base than aniline, so aniline has the lower pKb.
2. p-Toluidine and p-aminophenol are stronger bases than m-toluidine and aniline respectively, and p-chloroaniline is weaker than aniline.

Teacher's Note:
1. Electron-releasing groups (CH3, OH) at the para position raise basicity; electron-withdrawing groups (NO2, Cl) lower it.

Question 15: Bromobenzene can be prepared from benzene diazonium chloride when it is treated with
(a) H3PO2/H2O
(b) Br2; HBr
(c) CuBr/HBr
(d) Br2, CCl4
Show Answer & Explanation

Answer: (c) CuBr/HBr

Explanation:
1. Sandmeyer reaction: C6H5N2+Cl− + CuBr/HBr → C6H5Br + N2.
2. H3PO2 replaces the diazonium group by H, giving benzene.

Teacher's Note:
1. Sandmeyer uses Cu(I) halides; Gattermann uses Cu powder with HX – both give aryl halides.

Question 16: Match Column I with Column II:
Column IColumn II
(A) Ammonolysis(p) Amine with lesser no. of carbon atoms
(B) Gabriel phthalimide synthesis(q) Detection of primary amine
(C) Hoffmann bromamide degradation(r) Reaction of phthalimide with KOH and R–X
(D) Carbylamine reaction(s) Reaction of alkyl halides with NH3

(a) A–s, B–r, C–p, D–q
(b) A–p, B–q, C–r, D–s
(c) A–r, B–s, C–p, D–q
(d) A–s, B–r, C–q, D–p
Show Answer & Explanation

Answer: (a) A–s, B–r, C–p, D–q

Explanation:
1. Ammonolysis is the reaction of alkyl halides with NH3 (s); Gabriel synthesis uses phthalimide, KOH and R–X (r).
2. Hoffmann bromamide degradation gives an amine with one carbon atom less (p); the carbylamine reaction detects primary amines (q).

Teacher's Note:
1. Link each named reaction to its reagent or use – these four are the most asked preparation/test reactions of amines.

Question 17: Match Column I with Column II:
Column IColumn II
(A) Benzene sulphonyl chloride(p) Zwitter ion
(B) Sulphanilic acid(q) Hinsberg reagent
(C) Alkyl diazonium salts(r) Dyes
(D) Aryl diazonium salts(s) Conversion to alcohols

(a) A–p, B–q, C–s, D–r
(b) A–q, B–p, C–s, D–r
(c) A–q, B–p, C–r, D–s
(d) A–s, B–r, C–q, D–p
Show Answer & Explanation

Answer: (b) A–q, B–p, C–s, D–r

Explanation:
1. Benzenesulphonyl chloride is Hinsberg reagent (q); sulphanilic acid exists as a zwitter ion (p).
2. Alkyl diazonium salts are unstable and are converted to alcohols (s); aryl diazonium salts are used to make azo dyes (r).

Teacher's Note:
1. Sulphanilic acid is high-melting and insoluble in organic solvents because it is a dipolar ion, H3N+–C6H4–SO3−.

Question 18: Which of the following shows the correct reaction for nitrobenzene reduction ?
(a) Nitrobenzene reacts with Zn dust and NH4Cl to produce aniline
(b) Nitrobenzene reacts with LiAlH4 to produce phenylhydroxylamine
(c) Nitrobenzene reacts with Fe and HCl to produce nitrosobenzene
(d) Nitrobenzene reacts with Zn dust and NH4Cl to produce phenylhydroxylamine
Show Answer & Explanation

Answer: (d) Nitrobenzene reacts with Zn dust and NH4Cl to produce phenylhydroxylamine

Explanation:
1. Reduction of nitrobenzene with Zn dust and NH4Cl (neutral medium) gives N-phenylhydroxylamine.
2. C6H5NO2 Zn/NH4Cl
⟶
 
C6H5NHOH

Teacher's Note:
1. The product of nitrobenzene reduction depends on the medium: acidic (Fe/HCl, Sn/HCl) gives aniline, neutral (Zn/NH4Cl) gives phenylhydroxylamine, LiAlH4 gives azobenzene.

Question 19: Which of the following compounds will not undergo Friedel-Crafts reaction easily ?
(a) Nitrobenzene
(b) Toluene
(c) Cumene
(d) Xylene
Show Answer & Explanation

Answer: (a) Nitrobenzene

Explanation:
1. –NO2 is a powerful deactivating group. It reduces the electron density in the benzene ring considerably. As a result, it does not undergo F.C. reactions.

Teacher's Note:
1. This is why nitrobenzene is often used as a solvent for Friedel-Crafts reactions.

Question 20: Number of structural isomers possible from the molecular formula C3H9N is
(a) 5
(b) 2
(c) 3
(d) 4
Show Answer & Explanation

Answer: (d) 4

Explanation:
1. Four structural isomers are possible. These are :
2. (i) CH3CH2CH2NH2 (Propan-1-amine) (ii) CH3–CH(NH2)–CH3 (Propan-2-amine)
3. (iii) CH3–NH–CH2CH3 (N-Methylethanamine) (iv) (CH3)3N (N,N-Dimethylmethanamine)

Teacher's Note:
1. Count 1°, 2° and 3° amines separately so that none is missed: 2 + 1 + 1 = 4.

Question 21: The total number of structural isomers possible for the amine with molecular formula C4H11N is
(a) 5
(b) 6
(c) 7
(d) 8
Show Answer & Explanation

Answer: (d) 8

Explanation:
1. Eight structural isomers are possible:
2. 1° amines (4): CH3CH2CH2CH2NH2, CH3CH2CH(NH2)CH3, (CH3)2CHCH2NH2, (CH3)3CNH2
3. 2° amines (3): CH3NHCH2CH2CH3, CH3NHCH(CH3)2, CH3CH2NHCH2CH3
4. 3° amine (1): (CH3)2NCH2CH3

Teacher's Note:
1. Students often forget (CH3)3CNH2 and CH3NHCH(CH3)2; check every carbon skeleton.

Question 22: The product of the following reaction is
CH3–CN Na(Hg) + C2H5OH
⟶
 
X
(a) CH3–CONH2
(b) CH3CH2–NH2
(c) C2H6
(d) CH3–NH–CH3
Show Answer & Explanation

Answer: (b) CH3CH2–NH2

Explanation:
1. Nascent hydrogen from sodium amalgam and ethanol reduces the nitrile to a primary amine (Mendius reduction).
2. CH3–C≡N + 4[H] → CH3CH2NH2

Teacher's Note:
1. Reduction of a nitrile gives a 1° amine with the same number of carbon atoms, so it ascends the series compared with the alkyl halide used to make the nitrile.

Question 23: C6H5CONHCH3 can be converted into C6H5CH2NHCH3 by
(a) NaBH4
(b) H2–Pd/C
(c) LiAlH4
(d) Zn–Hg/HCl
Show Answer & Explanation

Answer: (c) LiAlH4

Explanation:
1. LiAlH4 reduces the >C=O group of an amide to –CH2–, converting the amide into the corresponding amine.
2. C6H5CONHCH3 LiAlH4
⟶
 
C6H5CH2NHCH3

Teacher's Note:
1. NaBH4 is too mild to reduce amides; amide → amine needs LiAlH4.

Question 24: Ethylamine can be prepared by the action of bromine and caustic potash on which of the following compound ?
(a) Acetamide
(b) Propanamide
(c) Formamide
(d) Methyl cyanide
Show Answer & Explanation

Answer: (b) Propanamide

Explanation:
1. Hofmann bromamide reaction gives an amine with one carbon atom less than the amide.
2. CH3CH2CONH2 + Br2 + 4KOH → CH3CH2NH2 + K2CO3 + 2KBr + 2H2O

Teacher's Note:
1. For a 2-carbon amine by Hofmann bromamide reaction, start with a 3-carbon amide.

Question 25: The product ‘Y’ in the following reaction sequence is
Benzene Conc. HNO3
⟶
Conc. H2SO4
X LiAlH4
⟶
 
Y
(a) C6H5NH2
(b) C6H5NHOH
(c) C6H5–N=N–C6H5
(d) C6H5–NH–NH–C6H5
Show Answer & Explanation

Answer: (c) C6H5–N=N–C6H5

Explanation:
1. X is nitrobenzene. Nitrobenzene on reduction with LiAlH4 gives azobenzene.
2. 2 C6H5NO2 LiAlH4
⟶
 
C6H5N=NC6H5

Teacher's Note:
1. Two molecules of nitrobenzene combine during LiAlH4 reduction, so the product has two benzene rings joined by –N=N–.

Question 26: Identify the product of the following reaction :
Cyclohexyl bromide (bromocyclohexane) + NH3 →
(a) Cyclohexylamine, C6H11–NH2
(b) Dicyclohexylamine, C6H11–NH–C6H11
(c) N-Bromocyclohexylamine, C6H11–NHBr
(d) Cyclohexene
Show Answer & Explanation

Answer: (d) Cyclohexene

Explanation:
1. 2° Alkyl halides preferably undergo dehydrohalogenation (elimination) to give alkenes.
2. Thus, option (d) is correct.

Teacher's Note:
1. With alkyl halides, NH3 can act as a nucleophile or as a base; the more substituted the carbon bearing the halogen, the more elimination competes.

Question 27: Amine that cannot be prepared by Gabriel phthalimide synthesis is
(a) aniline
(b) benzylamine
(c) n-butylamine
(d) isobutylamine
Show Answer & Explanation

Answer: (a) aniline

Explanation:
1. Aniline being an arylamine cannot be prepared by Gabriel phthalimide reaction while all others being aliphatic primary amines can be easily prepared by this method.

Teacher's Note:
1. Aryl halides do not undergo nucleophilic substitution with the phthalimide anion, so aromatic 1° amines cannot be made this way.

Question 28: Which of the following reactions will not give a primary amine ?
(a) CH3CONH2 Br2/KOH
⟶
 

(b) CH3CN LiAlH4
⟶
 

(c) CH3NC LiAlH4
⟶
 

(d) CH3CONH2 LiAlH4
⟶
 
Show Answer & Explanation

Answer: (c) CH3NC LiAlH4
⟶
 

Explanation:
1. LiAlH4 reduces isocyanides to 2° amines, i.e.,
2. CH3NC LiAlH4
⟶
 
CH3NHCH3

Teacher's Note:
1. Nitriles (–C≡N) reduce to 1° amines, but isocyanides (–N≡C) reduce to 2° amines because the N is already bonded to carbon on both sides.

Assertion–Reason Questions

Question 29:
Assertion (A): Propanamide on treatment with bromine and potassium hydroxide gives propanamine.
Reason (R): During this reaction, one carbon of amide is lost as carbonate ion.
(a) Both A and R are true, and R is the correct explanation of A.
(b) Both A and R are true, but R is not the correct explanation of A.
(c) A is true, but R is false.
(d) A is false, but R is true.
Show Answer & Explanation

Answer: (d) A is false, but R is true.

Explanation:
1. Correct Assertion. Propanamide on treatment with Br2 and KOH gives ethanamine.
2. CH3CH2CONH2 + Br2 + 4KOH → CH3CH2NH2 + K2CO3 + 2KBr + 2H2O. So A is false but R is true.

Teacher's Note:
1. The carbonyl carbon of the amide leaves as CO32−, so the amine always has one carbon fewer.

Question 30:
Assertion (A): Gabriel phthalimide reaction can be used to prepare aniline.
Reason (R): Bromobenzene does not react with potassium phthalimide to form N-phenylphthalimide.
(a) Both A and R are true, and R is the correct explanation of A.
(b) Both A and R are true, but R is not the correct explanation of A.
(c) A is true, but R is false.
(d) A is false, but R is true.
Show Answer & Explanation

Answer: (d) A is false, but R is true.

Explanation:
1. Correct Assertion. Aniline cannot be prepared by Gabriel phthalimide reaction.
2. Bromobenzene, an aryl halide, does not undergo nucleophilic substitution with potassium phthalimide, so R is true and A is false.

Teacher's Note:
1. Gabriel synthesis works only for aliphatic 1° amines made from alkyl halides that undergo SN2.

Question 31:
Assertion (A): Aniline cannot be prepared by Gabriel phthalimide reaction.
Reason (R): Aryl halides do not undergo nucleophilic substitution reactions under ordinary laboratory conditions.
(a) Both A and R are true, and R is the correct explanation of A.
(b) Both A and R are true, but R is not the correct explanation of A.
(c) A is true, but R is false.
(d) A is false, but R is true.
Show Answer & Explanation

Answer: (a) Both A and R are true, and R is the correct explanation of A.

Explanation:
1. Aniline would need the reaction of potassium phthalimide with C6H5Cl or C6H5Br.
2. Since aryl halides do not undergo nucleophilic substitution under ordinary conditions, this step fails; so R correctly explains A.

Teacher's Note:
1. The partial double-bond character of the C–X bond in aryl halides (resonance) is the root cause of their low reactivity towards nucleophiles.

Question 32:
Assertion (A): Primary aliphatic and aromatic primary amines are obtained by reduction of the corresponding nitro compounds with H2/Pd-C.
Reason (R): Aromatic 1° amines are less basic than aliphatic 1° amines.
(a) Both A and R are true, and R is the correct explanation of A.
(b) Both A and R are true, but R is not the correct explanation of A.
(c) A is true, but R is false.
(d) A is false, but R is true.
Show Answer & Explanation

Answer: (b) Both A and R are true, but R is not the correct explanation of A.

Explanation:
1. Correct explanation. Catalytic hydrogenation reduces –NO2 to –NH2 irrespective of the fact whether it is attached to an alkyl group or an aryl group.
2. R is also true but has nothing to do with the reduction.

Teacher's Note:
1. In A-R questions, check whether R actually answers “why” for A; here basicity has no bearing on how the amine is made.

Question 33:
Assertion (A): Bromocyclohexane on treatment with ammonia gives cyclohexene.
Reason (R): Secondary alkyl halides on treatment with a base predominantly undergo elimination reaction.
(a) Both A and R are true, and R is the correct explanation of A.
(b) Both A and R are true, but R is not the correct explanation of A.
(c) A is true, but R is false.
(d) A is false, but R is true.
Show Answer & Explanation

Answer: (a) Both A and R are true, and R is the correct explanation of A.

Explanation:
1. NH3 acts as a base and removes HBr from the 2° alkyl halide bromocyclohexane, giving cyclohexene.
2. Since 2° alkyl halides with a base mainly undergo elimination, R explains A.

Teacher's Note:
1. Ammonolysis works best with 1° alkyl halides; with 2° and especially 3° halides elimination competes strongly.

Question 34:
Assertion (A): Both aliphatic and aromatic 1° amines give carbylamine test.
Reason (R): In carbylamine reaction, a mixture of 1° amine and carbon tetrachloride is heated in presence of alcoholic KOH.
(a) Both A and R are true, and R is the correct explanation of A.
(b) Both A and R are true, but R is not the correct explanation of A.
(c) A is true, but R is false.
(d) A is false, but R is true.
Show Answer & Explanation

Answer: (c) A is true, but R is false.

Explanation:
1. Correct reason. A mixture of 1° amine and CHCl3 is heated in presence of alcoholic KOH.
2. R–NH2 + CHCl3 + 3KOH (alc.) Δ
⟶
 
R–NC + 3KCl + 3H2O. So A is true but R is false.

Teacher's Note:
1. The carbylamine test needs chloroform (CHCl3), which forms dichlorocarbene with alcoholic KOH; CCl4 does not.

Question 35:
Assertion (A): Methylamine is more basic than trimethylamine.
Reason (R): +I-effect of the three methyl groups predominates over the stability of the conjugate acid due to H-bonding.
(a) Both A and R are true, and R is the correct explanation of A.
(b) Both A and R are true, but R is not the correct explanation of A.
(c) A is true, but R is false.
(d) A is false, but R is true.
Show Answer & Explanation

Answer: (c) A is true, but R is false.

Explanation:
1. Correct R. Greater stability of the conjugate acid due to H-bonding over stability due to +I-effect of the three CH3 groups makes CH3NH2 more basic than (CH3)3N.
2. So A is true but R is false.

Teacher's Note:
1. In aqueous solution, solvation (H-bonding) of the ammonium ion often outweighs the +I-effect; the order for methylamines is 2° > 1° > 3°.

Question 36:
Assertion (A): o-Toluidine is a weaker base than p-toluidine.
Reason (R): At o-position CH3 group exerts less + I-effect than at p-position.
(a) Both A and R are true, and R is the correct explanation of A.
(b) Both A and R are true, but R is not the correct explanation of A.
(c) A is true, but R is false.
(d) A is false, but R is true.
Show Answer & Explanation

Answer: (c) A is true, but R is false.

Explanation:
1. Correct reason. Due to ortho effect, o-toluidine is a weaker base than p-toluidine.
2. So A is true but R is false.

Teacher's Note:
1. Almost any group at the ortho position (electron-donating or withdrawing) lowers the basicity of aniline – this is the ortho effect.

Download Chapter MCQs: Class 12 Chemistry Unit 9 Amines

About Unit 9 Amines MCQs for Class 12 Chemistry

Test your conceptual understanding of Unit 9 Amines with these targeted multiple-choice questions. Designed in alignment with the latest CBSE curriculum for Class 12 Chemistry, these problem sets build accuracy and prepare students for objective exams.

How to Verify Your MCQ Answers

Each question includes structured solution keys mapped directly to standard CBSE textbooks, helping students evaluate their reasoning and correct mistakes early in their revision.

Enhance Speed with Online MCQ Tests

Wrap up your chapter revision by testing your knowledge against standard question formats. Everything on our platform is provided free of charge.

FAQs

Where can I access latest CBSE Class 12 Chemistry Amines MCQs Set 11?

You can get most exhaustive CBSE Class 12 Chemistry Amines MCQs Set 11 for free on StudiesToday.com. These MCQs for Class 12 Chemistry are updated for the 2026-27 academic session as per CBSE examination standards.

Are Assertion-Reasoning and Case-Study MCQs included in the Chemistry Class 12 material?

Yes, our CBSE Class 12 Chemistry Amines MCQs Set 11 include the latest type of questions, such as Assertion-Reasoning and Case-based MCQs. 50% of the CBSE paper is now competency-based.

How do practicing Chemistry MCQs help in scoring full marks in Class 12 exams?

By solving our CBSE Class 12 Chemistry Amines MCQs Set 11, Class 12 students can improve their accuracy and speed which is important as objective questions provide a chance to secure 100% marks in the Chemistry.

Do you provide answers and explanations for CBSE Class 12 Chemistry Amines MCQs Set 11?

Yes, Chemistry MCQs for Class 12 have answer key and brief explanations to help students understand logic behind the correct option as its important for 2026 competency-focused CBSE exams.

Can I practice these Chemistry Class 12 MCQs online?

Yes, you can also access online interactive tests for CBSE Class 12 Chemistry Amines MCQs Set 11 on StudiesToday.com as they provide instant answers and score to help you track your progress in Chemistry.