Practice MCQs for JEE Chemistry Coordination Compounds
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Question. A similarity between optical and geometrical isomerism is that
(a) both are included in stereoisomerism
(b) they have no similarity
(c) if in a compound one is present then so is the other
(d) each gives equal number of isomers for a given compound
Answer: A
Question. The type of isomerism present in nitropentaamminechromium (III) chloride is
(a) linkage
(b) polymerization
(c) ionization
(d) optical
Answer: A
Question. The geometry of Ni(CO)4 and Ni(PPh3)2Cl2 are
(a) both tetrahedral
(b) None of these
(c) tetrahedral and square planar
(d) both square planar
Answer: A
Question. Which of the following facts about the complex [Cr(NH3)6]Cl3 is wrong?
(a) The complex is an outer orbital complex
(b) The complex gives white precipitate with silver nitrate solution.
(c) The complex is paramagnetic
(d) The complex involves d2sp3 hybridisation and is octahedral in shape.
Answer: A
Question. Atomic number of Cr and Fe are respectively 25 and 26, which of the following is paramagnetic?
(a) [Cr(NH3)6]+3
(b) [Fe(CO)5]
(c) [Cr(CO)6]
(d) None of these
Answer: A
Question. CN– is a strong field ligand. This is due to the fact that
(a) it is a pseudohalide
(b) it can accept electrons from metal species
(c) it forms high spin complexes with metal species
(d) it carries negative charge
Answer: A
Question. [Sc(H2O)6]3+ ion is
(a) colourless and diamagnetic
(b) coloured and octahedral
(c) colourless and paramagnetic
(d) coloured and paramagnetic
Answer: A
Question. Which of the following complexes exhibits the highest paramagnetic behaviour ?
(a) [Co(ox)2(OH)2]2–
(b) [Ti(NH3)6]3+
(c) Both
(d) None of these
Answer: A
Question. Which of these statements about [Co(CN)6]3– is true ?
(a) [Co(CN)6]3– has no unpaired electrons and will be in a low-spin configuration.
(b) [Co(CN)6]3– has no unpaired electrons and will be in a high-spin configurtion.
(c) Both
(d) None of these
Answer: A
Question. The complex ion which has highest magnetic moment among the following is
(a) [CoF6]3–
(b) [Co(NH3)6]3+
(c) [Ni(CN)4]2–
(d) None of these
Answer: A
Question. Which of the following is the limitation of valence bond theory?
(a) All of these
(b) It does not explain the colour exhibited by coordination compounds
(c) It does not give quantitative interpretation of magnetic data.
(d) It does not distinguish between weak and strong ligands
Answer: A
Question. Among the following complexes the one which shows zero crystal field stabilization energy (CFSE):
(a) [Fe(H2O)6]3+
(b) [Co(H2O)6]3+
(c) [Co(H2O)6]2+
(d) None of these
Answer: A
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