Advanced Study Material for Class 10 Science: Chapter 02 Acids Bases Salts
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Practice Class 10 Science Resources: Chapter 02 Acids Bases Salts
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This is a compact exam revision page for Class 10 Science Chapter 2, Acids, Bases and Salts. It gathers the key definitions, indicator colours, general reactions, pH facts, the family of chemicals made from common salt, the important equations, memory aids and the usual mistakes made in board answers.
Key Definitions
- Acid: a substance that gives H+ (H3O+) ions in aqueous solution. Acids taste sour and turn blue litmus red. Alcohol and glucose contain hydrogen but do not give H+ ions, so they are not acids.
- Base: a substance that reacts with an acid to form salt and water. Alkali: a base that dissolves in water and gives OH− ions, for example NaOH and KOH. All alkalis are bases but not all bases are alkalis.
- Indicator: a substance that shows a different colour (or smell) in acidic and basic media. Natural: litmus, turmeric, red cabbage, petunia, hydrangea. Synthetic: methyl orange, phenolphthalein. Olfactory: onion, vanilla essence.
- Neutralisation: reaction of an acid with a base to form salt and water; H+(aq) + OH−(aq) → H2O(l). It gives out heat.
- pH: the negative logarithm (base 10) of the hydrogen ion concentration, pH = −log[H+]. The scale runs from 0 to 14; a higher H+ concentration means a lower pH.
- Dilution: mixing an acid or base with water, which lowers the concentration of H3O+ or OH− ions per unit volume. It is highly exothermic, so always add the acid to water slowly with stirring.
- Water of crystallisation: the fixed number of water molecules chemically combined with one formula unit of a salt in its crystals, for example CuSO4·5H2O. Hydrated salts contain it; anhydrous salts do not.
- Salt: compound formed when an acid reacts with a base. Salts with the same positive or negative ion form a family, for example NaCl and Na2SO4 are sodium salts.
Indicator Colours at a Glance
| Indicator | In acid | In base |
|---|---|---|
| Blue litmus | Turns red | Stays blue |
| Red litmus | Stays red | Turns blue |
| Phenolphthalein | Colourless | Pink |
| Methyl orange | Red (pinkish red) | Yellow |
| Turmeric | Yellow (no change) | Reddish brown |
| China rose | Dark pink | Green |
| Universal indicator / pH paper | Orange to red | Blue to violet |
| Onion or vanilla (olfactory) | Smell is retained | Smell is lost |
Reactions of Acids and Bases
| Reaction | General form | Example |
|---|---|---|
| Acid + metal | Salt + hydrogen | Zn + H2SO4 → ZnSO4 + H2↑. Hydrogen burns with a pop sound. |
| Base + metal (Zn, Al) | Salt + hydrogen | Zn + 2NaOH → Na2ZnO2 + H2↑ (sodium zincate) |
| Acid + metal carbonate or hydrogencarbonate | Salt + water + carbon dioxide | Na2CO3 + 2HCl → 2NaCl + H2O + CO2↑; NaHCO3 + HCl → NaCl + H2O + CO2↑ |
| Acid + base | Salt + water (neutralisation) | NaOH + HCl → NaCl + H2O |
| Acid + metal oxide | Salt + water (metal oxides are basic) | CuO + 2HCl → CuCl2 + H2O |
| Base + non-metal oxide | Salt + water (non-metal oxides are acidic) | Ca(OH)2 + CO2 → CaCO3 + H2O |
| CO2 and lime water | Milky, then clear with excess CO2 | Ca(OH)2 + CO2 → CaCO3↓ + H2O; CaCO3 + H2O + CO2 → Ca(HCO3)2 |
Ions, Strength and pH
- Acids show acidic behaviour only in water, where they give H+ ions. Dry HCl gas does not change dry blue litmus; moist litmus turns red. Solutions of acids and bases conduct electricity because they contain ions; glucose and alcohol solutions do not.
- Strong acids (HCl, H2SO4, HNO3) ionise almost completely; weak acids (CH3COOH, H2CO3, citric acid) ionise only partly. Strong bases: NaOH, KOH, Ca(OH)2; weak bases: NH4OH, Mg(OH)2.
- pH below 7 is acidic, 7 is neutral and above 7 is basic. Each fall of one pH unit means ten times more H+ ions. Dilution moves the pH of an acid up towards 7 and of a base down towards 7.
| Where pH matters | Fact |
|---|---|
| Human body | Blood, tears and saliva keep pH about 7.0 to 7.8; stomach acid (HCl) has pH about 2 |
| Tooth decay | Starts when the pH of the mouth falls below 5.5; toothpaste is basic and neutralises the acid |
| Soil | Most crops grow best near pH 6.5 to 7.0; acidic soil is treated with quick lime, slaked lime or chalk |
| Stings | Ant, bee and nettle stings contain methanoic (formic) acid; rub baking soda. Wasp sting is basic; use vinegar |
| Indigestion | Excess stomach acid is neutralised by antacids such as milk of magnesia, Mg(OH)2 |
pH of Salts
| Salt of | Solution | pH | Examples |
|---|---|---|---|
| Strong acid + strong base | Neutral | 7 | NaCl, KNO3, Na2SO4 |
| Strong acid + weak base | Acidic | less than 7 | NH4Cl, CuSO4, FeCl3 |
| Weak acid + strong base | Basic | more than 7 | Na2CO3, NaHCO3, CH3COONa |
Chemicals from Common Salt
| Compound | Formula | Preparation | Main uses |
|---|---|---|---|
| Sodium hydroxide | NaOH | 2NaCl + 2H2O → 2NaOH + Cl2 + H2 (electrolysis of brine). Cl2 forms at the anode, H2 at the cathode, NaOH near the cathode | Soap, paper, artificial fibres |
| Bleaching powder | CaOCl2 | Ca(OH)2 + Cl2 → CaOCl2 + H2O | Bleaching cotton and wood pulp, disinfecting drinking water, oxidising agent |
| Baking soda | NaHCO3 | NaCl + H2O + CO2 + NH3 → NH4Cl + NaHCO3 | Antacid, baking powder (with tartaric acid), soda-acid fire extinguisher |
| Washing soda | Na2CO3·10H2O | 2NaHCO3 → Na2CO3 + H2O + CO2, then Na2CO3 + 10H2O → Na2CO3·10H2O | Glass, soap and paper industries; removing permanent hardness of water |
| Plaster of Paris | CaSO4·½H2O | CaSO4·2H2O → CaSO4·½H2O + 1½H2O on heating gypsum at 373 K. With water it sets: CaSO4·½H2O + 1½H2O → CaSO4·2H2O | Plaster for fractured bones, toys, statues, smooth surfaces |
Water of Crystallisation
- Blue copper sulphate crystals, CuSO4·5H2O, turn white on heating because they lose the five water molecules: CuSO4·5H2O → CuSO4 + 5H2O. A few drops of water restore the blue colour.
- Number of water molecules: copper sulphate 5, washing soda 10, gypsum 2, green vitriol FeSO4·7H2O 7, plaster of Paris half.
- Sodium chloride, baking soda and sodium carbonate (soda ash) are anhydrous.
Important Equations to Practise
- 2NaOH + H2CO3 → Na2CO3 + 2H2O
- ZnO + 2NaOH → Na2ZnO2 + H2O (zinc oxide is amphoteric)
- 2Al + 3H2SO4 → Al2(SO4)3 + 3H2↑
- Mg(OH)2 + 2HNO3 → Mg(NO3)2 + 2H2O
- CaCO3 + 2HCl → CaCl2 + H2O + CO2↑ (egg shell, marble and limestone are calcium carbonate)
- CaOCl2 + CO2 → CaCO3 + Cl2 (bleaching powder loses chlorine in air)
- SO3 + H2O → H2SO4; Na2O + H2O → 2NaOH; CaO + H2O → Ca(OH)2
- 2NaOH + CO2 → Na2CO3 + H2O
- 2NaCl + H2SO4 (conc.) → Na2SO4 + 2HCl↑
Memory Aids
- Litmus: Acid makes Blue litmus Red (A-B-R); base does the opposite to red litmus.
- Low pH, high H+: the two numbers move in opposite directions.
- Always Add Acid to water (A-A-W), never water to acid.
- Hydrated salt water counts: copper sulphate 5, gypsum 2, washing soda 10.
- Salt pH rule: the stronger parent decides the nature of the salt; if both parents are strong the salt is neutral.
Common Mistakes
| Mistake | Correction |
|---|---|
| Mixing up the colours of pH paper or universal indicator for weak and strong acids and bases | Learn the colour chart once: red for strong acid, orange or yellow for weak acid, green for neutral, blue or violet for bases |
| Writing wrong formulae, for example plaster of Paris as CaSO4·H2O | Derive formulae from valencies and remember: plaster of Paris CaSO4·½H2O, gypsum CaSO4·2H2O |
| Not balancing the equation, which leads to wrong products | Balance every equation and write the state symbols if asked |
| Saying chlorine is formed at the cathode in the chlor-alkali process | Chlorine forms at the anode; hydrogen forms at the cathode |
| Writing that baking soda and washing soda are the same | Baking soda is NaHCO3 (no water of crystallisation); washing soda is Na2CO3·10H2O |
| Saying a salt is neutral because it is a salt | Check the parent acid and base; Na2CO3 is basic and NH4Cl is acidic |
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