CBSE Class 7 Science Advanced Chemistry Atomic Structure and Transformation of Matter MCQs Set 02

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Chapter-wise Objective Questions: Atomic Structure and Transformation of Matter

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Multiple Choice Questions

Question 1: Heating of a mixture consisting of potassium nitrate, carbon and sulphur involves which of the following chemical changes?
(a) decomposition and combination
(b) double decomposition
(c) combination and displacement
(d) displacement and decomposition
Show Answer & Explanation

Answer: (a) decomposition and combination

Explanation:
1. Potassium nitrate decomposes on heating: \(\ce{2KNO3 -> 2KNO2 + O2}\).
2. The oxygen released combines with sulphur and carbon: \(\ce{S + O2 -> SO2}\) and \(\ce{C + O2 -> CO2}\).
3. So the changes are decomposition and combination.

Teacher's Note:
1. This mixture is gunpowder.
2. Split the process into the decomposition step and the burning steps.

Question 2: \(\ce{CuSO4 + X -> XSO4 + Cu}\); \(\ce{CuSO4 + Y -> YSO4 + Cu}\); \(\ce{XSO4 + Y -> No reaction}\); \(\ce{CuSO4 + Z -> No reaction}\). Arrange Cu, X, Y and Z in the ascending order of reactivity.
(a) X, Y, Z, Cu
(b) Cu, Y, X, Z
(c) Cu, X, Z, Y
(d) Z, Cu, Y, X
Show Answer & Explanation

Answer: (d) Z, Cu, Y, X

Explanation:
1. X and Y both displace Cu, so each is more reactive than Cu.
2. Y cannot displace X from \(\ce{XSO4}\), so X is more reactive than Y.
3. Z cannot displace Cu, so Z is less reactive than Cu.
4. Ascending order: Z < Cu < Y < X, i.e. Z, Cu, Y, X.

Teacher's Note:
1. Ascending means least reactive first.
2. A metal that gives no reaction is less reactive.

Question 3: A metal M shows variable valencies 2 and 3. Calculate the ratio of oxygen atoms present in their corresponding sulphates.
(a) 1 : 3
(b) 3 : 1
(c) 3 : 4
(d) 3 : 2
Show Answer & Explanation

Answer: (a) 1 : 3

Explanation:
1. With valency 2 the sulphate is \(\ce{MSO4}\), with 4 oxygen atoms.
2. With valency 3 the sulphate is \(\ce{M2(SO4)3}\), with 12 oxygen atoms.
3. Ratio = 4 : 12 = 1 : 3.

Teacher's Note:
1. Find each sulphate by criss-cross.
2. Count oxygen inside the brackets as well.

Question 4: Identify the formula of the corresponding hydride of a nonmetal "X" which attains an octet configuration by gaining two electrons.
(a) \(\ce{XH}\)
(b) \(\ce{XH3}\)
(c) \(\ce{XH4}\)
(d) \(\ce{XH2}\)
Show Answer & Explanation

Answer: (d) \(\ce{XH2}\)

Explanation:
1. Gaining two electrons gives \(\ce{X^2-}\), so the valency of X is 2.
2. With hydrogen (valency 1) the hydride is \(\ce{XH2}\).

Teacher's Note:
1. Valency equals electrons gained.
2. Swap valencies with hydrogen.

Question 5: The number of valence electrons in the valence shells 1, 2, 3 of the X, Y, Z elements are 2, 8, 6, respectively. Identify the element which doesn't exist in monoatomic state.
(a) X
(b) Z
(c) Y
(d) X and Y
Show Answer & Explanation

Answer: (b) Z

Explanation:
1. X has 2 electrons in shell 1 (He), Y has 8 in shell 2 (Ne, 2, 8) and Z has 6 in shell 3 (S, 2, 8, 6).
2. X and Y are noble gases with full shells, so they exist as single atoms.
3. Z (sulphur) is reactive and does not exist as single atoms: Z.

Teacher's Note:
1. Noble gases are monoatomic.
2. Sulphur forms molecules such as S8.

Question 6: The number of neutrons is equal to the number of protons present in the nucleus of two elements and their respective dinegative ions possess 8 electrons in the L and M shells, respectively. Then the ratio of mass numbers of the two elements is
(a) 1 : 2
(b) 2 : 3
(c) 3 : 4
(d) 2 : 5
Show Answer & Explanation

Answer: (a) 1 : 2

Explanation:
1. First element: \(\ce{X^2-}\) has 8 electrons in L, so it is 2, 8; the atom is 2, 6, so Z = 8. Neutrons = 8, so A = 16.
2. Second element: \(\ce{Y^2-}\) has 8 electrons in M, so it is 2, 8, 8; the atom is 2, 8, 6, so Z = 16. Neutrons = 16, so A = 32.
3. Ratio = 16 : 32 = 1 : 2.

Teacher's Note:
1. Remove two electrons from the ion to get the atom.
2. A = protons + neutrons = 2Z here.

Question 7: Tripositive ion of an element has 13 protons and 14 neutrons. Calculate the ratio of number of electrons present in the K and M shells of the neutral atom.
(a) 2 : 3
(b) 2 : 1
(c) 1 : 1
(d) 2 : 5
Show Answer & Explanation

Answer: (a) 2 : 3

Explanation:
1. The neutral atom has 13 electrons, arranged as 2, 8, 3.
2. K : M = 2 : 3.
3. So the ratio is 2 : 3.

Teacher's Note:
1. The neutral atom has the same number of electrons as protons.
2. Neutrons are not needed.

Question 8: The ratio of number of electrons present in four shells of an element is 1 : 4 : 4 : 1, fourth shell is the valence shell. Then mass of total positive charge present in the atom is ________ times to that of mass of electron
(a) 36,740
(b) 27,555
(c) 18,370
(d) 55,110
Show Answer & Explanation

Answer: (a) 36,740

Explanation:
1. The shells hold 2, 8, 8, 2 electrons, so there are 20 electrons and Z = 20.
2. Mass of 20 protons = 20 × 1837 = 36,740 times the mass of one electron.

Teacher's Note:
1. Work out the electrons from the ratio and the K shell value of 2.
2. Multiply Z by 1837.

Question 9: The difference in the number of electrons between K and L and L and M shells is the same for an atom of element "X" (M shell is the valence shell) and the difference value is the number of valence electrons in the M shell of the other element "Y". Give the electronic configurations of their stable ions.
(a) 2, 8, 2 and 2, 8, 6
(b) 2, 8 and 2, 8
(c) 2, 8 and 2, 8, 8
(d) 2, 8, 8 and 2, 8, 8
Show Answer & Explanation

Answer: (c) 2, 8 and 2, 8, 8

Explanation:
1. For X = 2, 8, x: 8 − 2 = 8 − x, so x = 2. X is 2, 8, 2.
2. The difference is 6, so Y has 6 valence electrons in M: 2, 8, 6.
3. X loses 2 electrons to form \(\ce{X^2+}\) (2, 8) and Y gains 2 to form \(\ce{Y^2-}\) (2, 8, 8).
4. So the answer is 2, 8 and 2, 8, 8.

Teacher's Note:
1. Find X first, then Y.
2. Stable ions have octet shells.

Question 10: The colour change of \(\ce{CuSO4}\) solution can be observed when it is made to react with
(a) silver
(b) silver chloride solution
(c) zinc
(d) gold
Show Answer & Explanation

Answer: (c) zinc

Explanation:
1. Only a metal more reactive than copper can displace it from copper sulphate.
2. Zinc is more reactive, so \(\ce{CuSO4 + Zn -> ZnSO4 + Cu}\).
3. The blue solution turns colourless, so the answer is zinc.

Teacher's Note:
1. Silver and gold are below copper in the series.
2. Blue colour comes from Cu²⁺ ions.

Question 11: Identify the ratio of the coefficients of the products CuO, \(\ce{NO2}\) and \(\ce{H2O}\) formed when hydrated copper nitrate is thermally decomposed.
\(\ce{Cu(NO3)2.6H2O -> CuO + NO2 + H2O + O2}\)
(a) 2 : 3 : 1
(b) 1 : 2 : 6
(c) 1 : 1.5 : 1
(d) 3 : 2 : 1
Show Answer & Explanation

Answer: (b) 1 : 2 : 6

Explanation:
1. Balance: \(\ce{2Cu(NO3)2.6H2O -> 2CuO + 4NO2 + O2 + 12H2O}\).
2. Check oxygen: 24 on the left; 2 + 8 + 2 + 12 = 24 on the right.
3. The coefficients of CuO, \(\ce{NO2}\) and \(\ce{H2O}\) are 2, 4 and 12, so the ratio is 1 : 2 : 6.

Teacher's Note:
1. Balance Cu and N first, then H and O.
2. Divide by the common factor 2.

Question 12: Which of the following chemical change is a photolytic decomposition reaction?
(a) Decomposition of HOCl on standing
(b) Formation of hydrogen chloride from their constituent elements
(c) Decomposition of limestone
(d) Both 1 and 2
Show Answer & Explanation

Answer: (a) Decomposition of HOCl on standing

Explanation:
1. Photolytic means decomposition by light.
2. HOCl breaks down in light: \(\ce{2HOCl -> 2HCl + O2}\).
3. Formation of HCl from elements is a combination, and limestone decomposes by heat. So the answer is (a).

Teacher's Note:
1. Photo means light.
2. Check which options are decompositions at all.

Question 13: Which of the following involves only a physical change?
(a) dissolution of lime in water
(b) dissolution of carbon dioxide in water at high pressure
(c) dissolution of concentrated acid in water
(d) electrolysis of water
Show Answer & Explanation

Answer: (c) dissolution of concentrated acid in water

Explanation:
1. Dissolving lime and passing electricity through water make new substances, and carbon dioxide reacts with water to form carbonic acid.
2. Mixing a concentrated acid with water only dilutes it.
3. So only dissolution of concentrated acid in water is physical.

Teacher's Note:
1. Dilution leaves the acid unchanged.
2. Check for a new substance.

Question 14: Arrange the points in sequence to draw the geometrical representation of an atom which is represented as \(\ce{^{A}_{Z}X}\).
(a) calculation of the number of protons and neutrons
(b) identification of the atomic number and mass number of the given element
(c) placement of the electrons in shells around the nucleus according to the electronic configuration
(d) writing the electronic configuration of the atom
(e) protons and neutrons are shown in nucleus
(a) baedc
(b) bacde
(c) abced
(d) ecbad
Show Answer & Explanation

Answer: (a) baedc

Explanation:
1. Identify Z and A (b).
2. Calculate protons and neutrons (a).
3. Show them in the nucleus (e).
4. Write the electronic configuration (d).
5. Place the electrons in the shells (c).
6. So the sequence is b, a, e, d, c.

Teacher's Note:
1. Nucleus first, then the shells.
2. You need Z and A before anything else.

Question 15: (a) \(\ce{H2 + Br2 -> 2HBr}\)
(b) \(\ce{HBr + NaOH -> NaBr + H2O}\)
(c) \(\ce{2NaBr + Cl2 -> 2NaCl + Br2}\)
(d) \(\ce{2NaCl -> 2Na + Cl2}\)
Arrange the above reactions in order as double displacement reaction, combination reaction, decomposition reaction and displacement reaction.
(a) badc
(b) bdac
(c) bacd
(d) abdc
Show Answer & Explanation

Answer: (a) badc

Explanation:
1. Double displacement: (b), since two compounds exchange radicals.
2. Combination: (a), two elements form one compound.
3. Decomposition: (d), one compound gives two elements.
4. Displacement: (c), chlorine displaces bromine.
5. So the order is b, a, d, c.

Teacher's Note:
1. Identify each reaction type first.
2. Then write them in the order asked.

Question 16: \(\ce{2KMnO4 + H2SO4 + 5H2C2O4 -> K2SO4 + 2MnSO4 + 10CO2 + 8H2O}\)
Potassium permanganate oxidizes oxalic acid in an acidic medium as per the above chemical reaction. Identify the coefficient of \(\ce{H2SO4}\) in the above equation.
(a) 3
(b) 4
(c) 5
(d) 2
Show Answer & Explanation

Answer: (a) 3

Explanation:
1. Sulphur on the right: 1 in \(\ce{K2SO4}\) and 2 in \(\ce{2MnSO4}\), total 3.
2. So \(\ce{H2SO4}\) must have the coefficient 3.
3. Hydrogen check: 6 + 10 = 16 on the left and 16 on the right.

Teacher's Note:
1. Count sulphur on the product side.
2. Verify with hydrogen.

Question 17: What will be the formula of the sulphate of a trivalent metal that is \(\ce{M^3+}\)?
(a) \(\ce{M2(SO4)3}\)
(b) \(\ce{MSO4}\)
(c) \(\ce{M2SO4}\)
(d) \(\ce{MSO3}\)
Show Answer & Explanation

Answer: (a) \(\ce{M2(SO4)3}\)

Explanation:
1. Sulphate is \(\ce{SO4^2-}\).
2. Criss-cross gives \(\ce{M2(SO4)3}\).

Teacher's Note:
1. Swap 3 and 2.
2. Keep the radical in brackets.

Question 18: Match the element in column A with the electronic configuration given in column B.
Column A: (A) Chlorine (B) Scandium (C) Manganese (D) Beryllium
Column B: (a) 2, 2 (b) 2, 8, 7 (c) 2, 8, 9, 2 (d) 2, 8, 13, 2
(a) A → c, B → d, C → a, D → b
(b) A → d, B → a, C → b, D → c
(c) A → b, B → c, C → d, D → a
(d) A → d, B → a, C → c, D → b
Show Answer & Explanation

Answer: (c) A → b, B → c, C → d, D → a

Explanation:
1. Chlorine (Z = 17) is 2, 8, 7: A → b.
2. Scandium (Z = 21) is 2, 8, 9, 2: B → c.
3. Manganese (Z = 25) is 2, 8, 13, 2: C → d.
4. Beryllium (Z = 4) is 2, 2: D → a.
5. So the answer is A → b, B → c, C → d, D → a.

Teacher's Note:
1. Use the atomic numbers of the elements.
2. The sums must match Z.

Question 19:
Assertion (A): Mass number of carbon is 12.
Reason (R): Carbon possesses equal number of all three fundamental particles.
(a) Both A and R are true, and R is the correct explanation of A.
(b) Both A and R are true, but R is not the correct explanation of A.
(c) A is true, but R is false.
(d) A is false, but R is true.
Show Answer & Explanation

Answer: (b) Both A and R are true, but R is not the correct explanation of A.

Explanation:
1. A is true: carbon has 6 protons and 6 neutrons, so its mass number is 12.
2. R is true: it has 6 protons, 6 neutrons and 6 electrons.
3. But equal numbers alone do not fix the mass number at 12 (it could be any number), so R does not explain A.
4. So both are true but R is not the correct explanation: (b).

Teacher's Note:
1. The mass number depends on the actual count of protons and neutrons.
2. An explanation must lead directly to the statement.

Question 20: Identify the atomic number of the element which possesses same number of electrons in the L and M shells and is a metal.
(a) 18
(b) 19
(c) 16
(d) 17
Show Answer & Explanation

Answer: (b) 19

Explanation:
1. Equal numbers in L and M means 8 and 8, so the configuration starts 2, 8, 8.
2. Argon (18) has 2, 8, 8 but is a noble gas, not a metal.
3. Z = 19 is 2, 8, 8, 1, which is potassium, a metal: 19.

Teacher's Note:
1. Write out the configurations.
2. 16 and 17 have fewer than 8 in M.

Question 21: If \(\ce{X-}\) ion has 10 neutrons and 9 protons, then the electronic configuration of the atom of the element X is
(a) 2, 8, 1
(b) 2, 7
(c) 2, 8
(d) 2, 8, 8
Show Answer & Explanation

Answer: (b) 2, 7

Explanation:
1. The atom has 9 protons, so 9 electrons.
2. They are arranged 2, 7.
3. So the configuration is 2, 7.

Teacher's Note:
1. Atom and ion differ by the extra electron.
2. Neutrons do not change the configuration.

Question 22:
Assertion (A): Copper exhibits variable valency.
Reason (R): Copper loses two electrons from its valence shell and it can also lose one more electron from the second last shell.
(a) Both A and R are true, and R is the correct explanation of A.
(b) Both A and R are true, but R is not the correct explanation of A.
(c) A is true, but R is false.
(d) A is false, but R is true.
Show Answer & Explanation

Answer: (c) A is true, but R is false.

Explanation:
1. A is true: copper forms \(\ce{Cu+}\) and \(\ce{Cu^2+}\).
2. R is false: copper has only one electron in its valence shell, so it loses one electron from the valence shell and, to form \(\ce{Cu^2+}\), one more from the second last shell.
3. So A is true and R is false: (c).

Teacher's Note:
1. Copper is 2, 8, 18, 1.
2. Check the number of valence electrons before accepting R.

Question 23: The ratio of difference in the number of electrons between K and M shells is 3 : 2 for X and Y elements, respectively. "X" possesses stable electronic configuration and M is the valence shell for both X and Y. The electronic configurations of X and Y are respectively
(a) 2, 8, 5 and 2, 8, 4
(b) 2, 8, 8 and 2, 8, 6
(c) 2, 8, 8 and 2, 6, 6
(d) 2, 8, 6 and 2, 8, 4
Show Answer & Explanation

Answer: (b) 2, 8, 8 and 2, 8, 6

Explanation:
1. X is stable with M as valence shell: 2, 8, 8, difference 6.
2. For Y: (8 − 2) : (x − 2) = 3 : 2, so x = 6.
3. So X is 2, 8, 8 and Y is 2, 8, 6.

Teacher's Note:
1. Use the ratio to find the unknown.
2. Y has the M shell with 6 electrons.

Question 24: Which of the following is not a chemical change?
(a) passing of steam over a red hot coke
(b) change in the colour of dil nitric acid upon long standing
(c) absorption of moisture by \(\ce{P2O5}\)
(d) absorption of moisture by \(\ce{CaCl2}\)
Show Answer & Explanation

Answer: (d) absorption of moisture by \(\ce{CaCl2}\)

Explanation:
1. Steam with red hot coke and the colour change of nitric acid make new substances, and \(\ce{P2O5}\) reacts with water to form an acid.
2. Calcium chloride only absorbs water without any reaction, so it is not a chemical change.

Teacher's Note:
1. Look for a new substance.
2. Deliquescence is physical.

Question 25: The atomic numbers of three elements A, B and C are 10, 18 and 8, respectively. Identify the element which is chemically reactive.
(a) A
(b) B
(c) C
(d) both A and B
Show Answer & Explanation

Answer: (c) C

Explanation:
1. A is 2, 8 and B is 2, 8, 8: both have an octet and are inactive.
2. C is 2, 6 and needs 2 more electrons, so it is reactive: C.

Teacher's Note:
1. Write the configurations.
2. Octet means stable.

Question 26: If a dipositive ion of an element "X" consists of 12 protons and 12 neutrons and another dipositive ion of an element "Y" consists of 18 electrons and twice the number of electrons of dipositive ion X is the number of neutrons of Y. Then, the mass numbers would be in the ratio of
(a) 1 : 2
(b) 3 : 5
(c) 12 : 19
(d) 2 : 3
Show Answer & Explanation

Answer: (b) 3 : 5

Explanation:
1. X: 12 protons + 12 neutrons = 24. \(\ce{X^2+}\) has 10 electrons.
2. Y: \(\ce{Y^2+}\) has 18 electrons, so Y has 20 protons. Neutrons of Y = 2 × 10 = 20, so A = 40.
3. Ratio = 24 : 40 = 3 : 5.

Teacher's Note:
1. Dipositive means two electrons lost.
2. Compute each mass number separately.

Question 27: The formula of chloride of a metal is \(\ce{MCl2}\). What is the valency of the metal?
(a) 4
(b) 3
(c) 1
(d) 2
Show Answer & Explanation

Answer: (d) 2

Explanation:
1. Chloride has valency 1 and two are present.
2. So the metal has valency 2.

Teacher's Note:
1. The Cl subscript gives the metal's valency.
2. Test with criss-cross.

Question 28: Heating solid ammonium chloride involves change in the ________.
(a) physical state only
(b) physical state as well as chemical composition
(c) colour only
(d) both colour and volume only
Show Answer & Explanation

Answer: (b) physical state as well as chemical composition

Explanation:
1. Solid \(\ce{NH4Cl}\) sublimes (a physical change).
2. It also decomposes into \(\ce{NH3}\) and \(\ce{HCl}\) (a chemical change).
3. So the answer is physical state as well as chemical composition.

Teacher's Note:
1. Two changes occur together.
2. Decomposition changes composition.

Question 29: Arrange the following points in a sequence to draw the geometrical representation of \(\ce{^{40}_{20}Ca}\).
(a) Protons and neutrons are shown in the nucleus.
(b) Writing the electronic configuration of the atom.
(c) Arrange the electrons in shells around the nucleus following the electronic configuration.
(d) Calculation of the number of protons and neutrons.
(e) Identification of the atomic number and mass number of the atom.
(a) edcba
(b) edabc
(c) abcde
(d) cabde
Show Answer & Explanation

Answer: (b) edabc

Explanation:
1. Identify Z = 20 and A = 40 (e).
2. Calculate 20 protons and 20 neutrons (d).
3. Show them in the nucleus (a).
4. Write the configuration 2, 8, 8, 2 (b).
5. Place the electrons in the shells (c).
6. So the order is e, d, a, b, c.

Teacher's Note:
1. Start with the data, end with the electrons.
2. The nucleus is drawn before the shells.

Question 30: Four types of reactions are given below in a particular order.
(a) displacement reaction
(b) combination reaction
(c) double displacement
(d) decomposition reaction
Follow this sequence to arrange the following reactions:
(a) \(\ce{A + B -> AB}\).
(b) \(\ce{AB -> A + B}\)
(c) \(\ce{AB + C -> CB + A}\)
(d) \(\ce{AC + BD -> AD + BC}\)
(a) cadb
(b) bacd
(c) bdac
(d) acbd
Show Answer & Explanation

Answer: (a) cadb

Explanation:
1. Displacement: \(\ce{AB + C -> CB + A}\) (c).
2. Combination: \(\ce{A + B -> AB}\) (a).
3. Double displacement: \(\ce{AC + BD -> AD + BC}\) (d).
4. Decomposition: \(\ce{AB -> A + B}\) (b).
5. So the order is c, a, d, b.

Teacher's Note:
1. Label each reaction first.
2. Then follow the order of the types given.

Question 31: Identify the coefficients of the products CuO and \(\ce{NO2}\) formed respectively when hydrated copper nitrate is thermally decomposed.
\(\ce{2Cu(NO3)2.6H2O -> CuO + NO2 + 12H2O + O2}\)
(a) 3, 4
(b) 2, 4
(c) 4, 5
(d) 2, 3
Show Answer & Explanation

Answer: (b) 2, 4

Explanation:
1. Copper: 2 Cu on the left, so CuO has coefficient 2.
2. Nitrogen: 4 N on the left, so \(\ce{NO2}\) has coefficient 4.
3. Oxygen check: 24 on the left and 2 + 8 + 12 + 2 = 24 on the right.
4. So the coefficients are 2 and 4.

Teacher's Note:
1. Balance metal and nitrogen first.
2. Check oxygen last.

Question 32: If the formula of a metal ion is \(\ce{M^2+}\), then the formula of its dihydrogen phosphate is
(a) \(\ce{M2(PO4)3}\)
(b) \(\ce{MHPO4}\)
(c) \(\ce{M(H2PO4)2}\)
(d) \(\ce{M2HPO4}\)
Show Answer & Explanation

Answer: (c) \(\ce{M(H2PO4)2}\)

Explanation:
1. Dihydrogen phosphate is \(\ce{H2PO4-}\).
2. Criss-cross with \(\ce{M^2+}\) gives \(\ce{M(H2PO4)2}\).

Teacher's Note:
1. Use brackets for a repeated radical.
2. Do not confuse it with hydrogen phosphate.

Question 33: Match the elements in column A with the valency exhibited by the element given in column B.
Column A: (A) Neon (B) Oxygen (C) Potassium (D) Boron (E) Silicon
Column B: (a) 4 (b) 3 (c) 2 (d) 1 (e) 0
(a) A → b, B → c, C → d, D → e, E → a
(b) A → b, B → c, C → a, D → e, E → d
(c) A → e, B → d, C → a, D → b, E → c
(d) A → e, B → c, C → d, D → b, E → a
Show Answer & Explanation

Answer: (d) A → e, B → c, C → d, D → b, E → a

Explanation:
1. Neon (2, 8) is inactive: valency 0, A → e.
2. Oxygen (2, 6) gains 2: valency 2, B → c.
3. Potassium (2, 8, 8, 1) loses 1: valency 1, C → d.
4. Boron (2, 3) loses 3: valency 3, D → b.
5. Silicon (2, 8, 4) has valency 4, E → a.
6. So the answer is option (d).

Teacher's Note:
1. Write the configuration of each element.
2. Valency is the electrons lost, gained or zero.

Question 34:
Assertion (A): The total mass of the protons of a boron atom is 6185 times the total mass of electrons.
Reason (R): Mass of one proton is 1837 times the mass of electron.
(a) Both A and R are true, and R is the correct explanation of A.
(b) Both A and R are true, but R is not the correct explanation of A.
(c) A is true, but R is false.
(d) A is false, but R is true.
Show Answer & Explanation

Answer: (d) A is false, but R is true.

Explanation:
1. R is true: a proton is about 1837 times as heavy as an electron.
2. Boron has 5 protons, so their total mass is 5 × 1837 = 9185 times the mass of one electron (and 1837 times the mass of its 5 electrons). The value 6185 in A is wrong.
3. So A is false and R is true: (d).

Teacher's Note:
1. Multiply the number of protons by 1837 to compare with one electron.
2. Check the arithmetic in A.

Question 35: Identify the number of neutrons present in a pair of elements with atomic numbers 20 and 13, if their mass numbers are 40 and 27, respectively.
(a) 20 and 13
(b) 13 and 20
(c) 17 and 20
(d) 20 and 14
Show Answer & Explanation

Answer: (d) 20 and 14

Explanation:
1. Neutrons = A − Z.
2. 40 − 20 = 20 and 27 − 13 = 14.
3. So the numbers are 20 and 14.

Teacher's Note:
1. Subtract the atomic number from the mass number.
2. Do it for each element.

Question 36: Tripositive ion, i.e., \(\ce{X^3+}\) has 13 protons and 14 neutrons. Calculate the number of electrons present in the M shell of the neutral atom.
(a) 2
(b) 1
(c) 3
(d) 5
Show Answer & Explanation

Answer: (c) 3

Explanation:
1. The neutral atom has 13 electrons: 2, 8, 3.
2. So the M shell has 3 electrons.

Teacher's Note:
1. Neutral atom: electrons = protons.
2. Fill K, L, then M.

Question 37:
Assertion (A): Sodium forms a monovalent ion.
Reason (R): Sodium loses only one electron from the second last shell.
(a) Both A and R are true, and R is the correct explanation of A.
(b) Both A and R are true, but R is not the correct explanation of A.
(c) A is true, but R is false.
(d) A is false, but R is true.
Show Answer & Explanation

Answer: (c) A is true, but R is false.

Explanation:
1. A is true: sodium (2, 8, 1) loses one electron and forms \(\ce{Na+}\).
2. R is false: the electron is lost from the outermost (valence) shell, not the second last shell.
3. So A is true and R is false: (c).

Teacher's Note:
1. Sodium has one valence electron.
2. Check which shell the electron comes from.

Question 38: The difference in the number of electrons between K and L and L and M shells is the same for an atom of an element X (M shell is the valence shell). And the difference of value is the number of valence electrons in the M shell of the other element Y. The electronic configurations of stable ions of X and Y are respectively
(a) 2, 8, 2 and 2, 8, 6
(b) 2, 8 and 2, 8
(c) 2, 8 and 2, 8, 8
(d) 2, 8, 8 and 2, 8, 8
Show Answer & Explanation

Answer: (c) 2, 8 and 2, 8, 8

Explanation:
1. For X: 8 − 2 = 8 − x gives x = 2, so X is 2, 8, 2. The difference is 6, so Y is 2, 8, 6.
2. X loses 2 electrons: \(\ce{X^2+}\) is 2, 8.
3. Y gains 2 electrons: \(\ce{Y^2-}\) is 2, 8, 8.
4. So the answer is 2, 8 and 2, 8, 8.

Teacher's Note:
1. Find the elements first.
2. Metal loses, nonmetal gains.

Question 39: Which of the following is a chemical change?
(a) formation of clouds
(b) formation of rust
(c) manufacture of milk powder from milk
(d) formation of black coating on the walls of a tube light
Show Answer & Explanation

Answer: (b) formation of rust

Explanation:
1. Clouds, milk powder and the black coating on a tube light involve no new substance.
2. Rust is a new compound, so formation of rust is a chemical change.

Teacher's Note:
1. Rusting makes hydrated ferric oxide.
2. The others are physical.

Question 40: The atomic numbers of the elements X, Y and Z are 2, 10 and 16, respectively. Identify the element which doesn't exist in monoatomic state.
(a) X
(b) Z
(c) Y
(d) X and Y
Show Answer & Explanation

Answer: (b) Z

Explanation:
1. X is helium and Y is neon: noble gases that exist as single atoms.
2. Z is sulphur (2, 8, 6), a reactive element that exists as molecules: Z.

Teacher's Note:
1. Noble gases are monoatomic.
2. Reactive elements form molecules.

Question 41: The number of neutrons is equal to the number of protons present in the nucleus of two elements X and Y and their dinegative ions possess 8 electrons in the L and M shells, respectively. Then the ratio of mass numbers of the two elements is
(a) 1 : 2
(b) 2 : 3
(c) 3 : 4
(d) 2 : 5
Show Answer & Explanation

Answer: (a) 1 : 2

Explanation:
1. X: \(\ce{X^2-}\) is 2, 8, so X is 2, 6 with Z = 8 and A = 16.
2. Y: \(\ce{Y^2-}\) is 2, 8, 8, so Y is 2, 8, 6 with Z = 16 and A = 32.
3. Ratio = 16 : 32 = 1 : 2.

Teacher's Note:
1. A = 2Z when neutrons equal protons.
2. Remove two electrons from the ion to get the atom.

Question 42: If a solid non-metal "X" forms an oxide of type \(\ce{X2O5}\), then the valency of X is
(a) 3
(b) 5
(c) 6
(d) 4
Show Answer & Explanation

Answer: (b) 5

Explanation:
1. In \(\ce{X2O5}\) the total negative charge is 5 × 2 = 10 for two X atoms.
2. So each X has valency 5.
3. Criss-cross check: \(\ce{X^5+}\) with \(\ce{O^2-}\) gives \(\ce{X2O5}\).

Teacher's Note:
1. Swap the subscripts to read the valency.
2. X has 5 and oxygen has 2.

Multiple Choice Questions (MCQs) for Class 7 Chemistry Atomic Structure and Transformation of Matter

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