NEET Chemistry Nitroalkanes Amines And Diazonium Salts Revision Notes

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Amines
 
Structure of amines: Trigonal Pyramidal
Basicity of Amines
 
a) Aliphatic Amine:
 
Basic Strength: NH3 < RNH2 < R2NH < R3N,
 
b) Aromatic Amine:
 
Basic Strength: NH3 > Ar- NH2 > Ar2- NH2
Benzene ring decreases the electron density over N atom due to resonance effect.
 
NEET Chemistry Nitroalkanes Amines and Diazonium Salts Revision Notes
 
Preparation of Amines
 
NEET Chemistry Nitroalkanes Amines and Diazonium Salts Revision Notes1
 
NEET Chemistry Nitroalkanes Amines and Diazonium Salts Revision Notes2
 
 
Chemical Reactions
 
a) Acylation:
 
RNH2 + R'COCl→ R'CO NHR an N-substituted amide
R2NH + R'COCl → R'CO.NR2 an N,N disubstituted amide
 
b) Benzoylation (Schotten Baumann Reaction)
 
Primary amine reacts with benzoyl chloride to give the acylated product
 
c) Carbylamine Reaction (Given Only by Primary Amines):
 
C2H5NH2 + CHCl3 + 3KOH → C2H5NC + 3KCl + 3H2O
C6H5 NH2 + CHCl3 + 3KOH → C6H5NC + 3KCl + 3H2O
 
d) Action with Aldehyde and Ketone:
NEET-Chemistry-Nitroalkanes-Amines-and-Diazonium-Salts-Revision-Notes 1
 
e) Hofmann Mustard Oil Reaction:
NEET-Chemistry-Nitroalkanes-Amines-and-Diazonium-Salts-Revision-Notes 2
 
f) Reaction with Carbonyl Chloride: C2H5 – NH2 + COCl2 → C2H5NCO + 2HCl
 
g) Hofmann Elimination:
When a quaternary ammonium hydroxide is heated strongly (125° or higher) it decomposes to yield water, a tertiary amine and an alkene
NEET-Chemistry-Nitroalkanes-Amines-and-Diazonium-Salts-Revision-Notes 3
h) The diazonium salts of amines:
NEET-Chemistry-Nitroalkanes-Amines-and-Diazonium-Salts-Revision-Notes 4
 
 
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