CBSE Class 10 Physics The Gas Laws MCQs Set 18

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Multiple Choice Questions

Question 1: The two factors that can change the volume of a given mass of gas are
(a) colour and temperature
(b) pressure and the shape of the vessel only
(c) mass and density
(d) temperature and pressure
Show Answer & Explanation

Answer: (d) temperature and pressure

Explanation:
1. A gas has no fixed volume, so its volume changes with the pressure on it and with its temperature.
2. Mass is fixed in this case and density depends on volume.

Teacher's Note:
1. Solids and liquids are almost incompressible, so their volume depends on temperature only.
2. To study one factor, the other is kept constant.

Question 2: For the same rise in temperature, the order of expansion of solids, liquids and gases is
(a) liquids expand more than gases
(b) solids expand more than liquids
(c) solids expand least and gases expand most
(d) all three expand equally
Show Answer & Explanation

Answer: (c) solids expand least and gases expand most

Explanation:
1. Solids have strong forces between their particles and expand least.
2. Liquids expand more than solids.
3. Gases expand most.

Teacher's Note:
1. This is why gases are used in gas thermometers.
2. The coefficient of cubical expansion of a gas is about 1/273 per °C.

Question 3: The absolute temperature corresponding to -10 °C is
(a) -263 K
(b) 10 K
(c) 263 K
(d) 283 K
Show Answer & Explanation

Answer: (c) 263 K

Explanation:
1. T = t + 273.
2. T = -10 + 273 = 263 K.

Teacher's Note:
1. The Kelvin scale never has negative values.
2. 0 K corresponds to -273 °C.

Question 4: A graph of volume against temperature for a gas at constant pressure is extended backwards. At absolute zero the volume of a given mass of the gas would become
(a) double its volume at 0 °C
(b) equal to its volume at 0 °C
(c) zero
(d) infinite
Show Answer & Explanation

Answer: (c) zero

Explanation:
1. V is proportional to T.
2. At T = 0 K, V = 0, in theory.
3. Real gases liquefy before this temperature is reached.

Teacher's Note:
1. This is why absolute zero is called the ideal gas scale zero.
2. 0 K has never been reached exactly.

Question 5: The volume coefficient of a gas under constant pressure is the fraction ______ of its volume at 0 °C by which the volume increases for each °C rise of temperature. The fraction is
(a) 1/100
(b) 1/373
(c) 273
(d) 1/273
Show Answer & Explanation

Answer: (d) 1/273

Explanation:
1. By Charles' law all gases expand by 1/273 of their volume at 0 °C for every °C rise, at constant pressure.
2. So the volume coefficient is 1/273 = 0.00366 per °C.

Teacher's Note:
1. The pressure coefficient at constant volume has the same value for a perfect gas.
2. The value is the same for all gases.

Question 6: For a perfect gas, with P the pressure, V the volume and T the absolute temperature, the quantity PV/T is
(a) a constant for a given mass of gas
(b) proportional to T
(c) inversely proportional to P
(d) zero at room temperature
Show Answer & Explanation

Answer: (a) a constant for a given mass of gas

Explanation:
1. Combining Boyle's and Charles' laws gives PV/T = constant.
2. Hence P1V1/T1 = P2V2/T2.

Teacher's Note:
1. This is called the general gas equation.
2. For one mole the constant is R = 8.31 J/mol K.

Question 7: Under constant pressure, the volume of a given mass of gas is proportional to its absolute temperature. This is a statement of
(a) Pascal's law
(b) Charles' law
(c) Newton's law of cooling
(d) Boyle's law
Show Answer & Explanation

Answer: (b) Charles' law

Explanation:
1. Keeping the pressure fixed and varying only the temperature leads to V proportional to T.
2. That is Charles' law.

Teacher's Note:
1. Boyle's law is about P and V at constant temperature.
2. V1/T1 = V2/T2 for constant pressure.

Question 8: If a quantity A is inversely proportional to a quantity B, then which of the following is constant?
(a) the sum A + B
(b) the ratio A / B
(c) the difference A - B
(d) the product A × B
Show Answer & Explanation

Answer: (d) the product A × B

Explanation:
1. A is proportional to 1/B means A = k/B.
2. Hence AB = k, a constant.

Teacher's Note:
1. As B increases, A decreases.
2. For Boyle's law PV = constant at fixed temperature.

Question 9: The relation \(\dfrac{P_1V_1}{T_1}=\dfrac{P_2V_2}{T_2}\) for a gas includes
(a) Boyle's law only
(b) neither of them
(c) both Boyle's law and Charles' law
(d) Charles' law only
Show Answer & Explanation

Answer: (c) both Boyle's law and Charles' law

Explanation:
1. At constant T it gives P1V1 = P2V2, which is Boyle's law.
2. At constant P it gives V1/T1 = V2/T2, which is Charles' law.
3. At constant V it gives P1/T1 = P2/T2, the pressure law.

Teacher's Note:
1. It is called the general gas equation.
2. It is used when pressure, volume and temperature all change.

Question 10: For an ideal gas, the volume coefficient at constant pressure compared with the pressure coefficient at constant volume is
(a) equal to it
(b) double it
(c) greater than it
(d) less than it
Show Answer & Explanation

Answer: (a) equal to it

Explanation:
1. Both coefficients equal 1/273 per °C for a perfect gas.
2. Hence they are equal.

Teacher's Note:
1. This is why the same absolute scale can be defined by either the constant-volume or the constant-pressure gas thermometer.
2. Real gases show small differences.

Question 11: For one mole of any perfect gas the value of PV/T is the same for all gases. It is called the universal gas constant and equals
(a) 273 J mol⁻¹ K⁻¹
(b) 22.4 J mol⁻¹ K⁻¹
(c) 8.31 J mol⁻¹ K⁻¹
(d) 1.013 × 10⁵ J mol⁻¹ K⁻¹
Show Answer & Explanation

Answer: (c) 8.31 J mol⁻¹ K⁻¹

Explanation:
1. At S.T.P. one mole occupies 22.4 × 10⁻³ m³, P = 1.013 × 10⁵ Pa, T = 273 K.
2. R = PV/T = (1.013 × 10⁵ × 22.4 × 10⁻³) / 273 = 8.31 J/K mol.

Teacher's Note:
1. PV = RT for one mole and PV = nRT for n moles.
2. 1.013 × 10⁵ Pa is standard atmospheric pressure.

Question 12: The volume of a gas at 27 °C is 100 cm³. At constant pressure its volume at 54 °C is nearly
(a) 200 cm³
(b) 109 cm³
(c) 150 cm³
(d) 50 cm³
Show Answer & Explanation

Answer: (b) 109 cm³

Explanation:
1. Absolute temperatures: T1 = 300 K, T2 = 327 K.
2. V2 = V1 T2 / T1 = 100 × 327 / 300 = 109 cm³.
3. The volume does not double when the Celsius temperature doubles.

Teacher's Note:
1. Always convert to kelvin before using Charles' law.
2. Volume doubles when the absolute temperature doubles, that is, from 27 °C to 327 °C.

Question 13: The volume of a gas depends on
(a) temperature alone
(b) pressure alone
(c) neither pressure nor temperature
(d) both pressure and temperature
Show Answer & Explanation

Answer: (d) both pressure and temperature

Explanation:
1. Boyle's law shows V depends on P at constant T.
2. Charles' law shows V depends on T at constant P.
3. So it depends on both.

Teacher's Note:
1. The general gas equation combines the two.
2. The volume of a solid depends on temperature only.

Question 14: The temperature 30 °C on the Kelvin scale is
(a) 243 K
(b) -243 K
(c) 303 K
(d) 30 K
Show Answer & Explanation

Answer: (c) 303 K

Explanation:
1. T = 30 + 273 = 303 K.

Teacher's Note:
1. Add 273 to the Celsius temperature.
2. The size of one kelvin equals the size of one degree Celsius.

Question 15: All perfect gases increase by 1/273 of their volume at 0 °C for every 1 °C rise in temperature, the pressure being constant. This is a statement of
(a) Boyle's law
(b) Avogadro's law
(c) Charles' law
(d) Archimedes' principle
Show Answer & Explanation

Answer: (c) Charles' law

Explanation:
1. This describes expansion with temperature at constant pressure.
2. That is Charles' law, also stated as V1/T1 = V2/T2.

Teacher's Note:
1. 1/273 is the volume coefficient.
2. Boyle's law concerns pressure and volume at constant temperature.

Question 16: The volume of a gas kept at constant temperature is 600 cm³. Its volume when the pressure is trebled is
(a) 1800 cm³
(b) 200 cm³
(c) 150 cm³
(d) 250 cm³
Show Answer & Explanation

Answer: (b) 200 cm³

Explanation:
1. Boyle's law: P1V1 = P2V2.
2. P2 = 3P1, so V2 = 600 / 3 = 200 cm³.

Teacher's Note:
1. Volume falls to one third when the pressure triples.
2. The pressure and volume of a gas at fixed temperature are inversely proportional.

Question 17: A gas of volume 200 cm³ at constant pressure and 47 °C is heated to 127 °C. The new volume is
(a) 250 cm³
(b) 600 cm³
(c) 300 cm³
(d) 400 cm³
Show Answer & Explanation

Answer: (a) 250 cm³

Explanation:
1. T1 = 47 + 273 = 320 K and T2 = 127 + 273 = 400 K.
2. V2 = V1 T2 / T1 = 200 × 400 / 320 = 250 cm³.

Teacher's Note:
1. Use kelvin temperatures.
2. Doubling the Celsius temperature would give the wrong answer.

Question 18: The pressure of a gas at constant volume and temperature 27 °C is 80 cm of mercury. Its pressure at 87 °C is
(a) 90 cm of mercury
(b) 96 cm of mercury
(c) 120 cm of mercury
(d) 100 cm of mercury
Show Answer & Explanation

Answer: (b) 96 cm of mercury

Explanation:
1. T1 = 300 K, T2 = 360 K and V is constant.
2. P2 = P1 T2 / T1 = 80 × 360 / 300 = 96 cm of mercury.

Teacher's Note:
1. At constant volume pressure is proportional to the absolute temperature.
2. This is Charles' pressure law.

Question 19: The volume of a gas at 27 °C is 500 cm³ and at 87 °C it is 600 cm³ at the same pressure. The volume coefficient of the gas is
(a) 1/360 per °C
(b) 1/300 per °C
(c) 1/273 per °C
(d) 1/100 per °C
Show Answer & Explanation

Answer: (c) 1/273 per °C

Explanation:
1. V = V0(1 + α t).
2. 500 = V0(1 + 27α) and 600 = V0(1 + 87α).
3. Dividing, 5(1 + 87α) = 6(1 + 27α), so 273α = 1 and α = 1/273.

Teacher's Note:
1. The method works for any pair of volumes at the same pressure.
2. The value 1/273 shows the gas behaves ideally.

Question 20: The pressure of a gas at 27 °C is 72 cm of mercury and at 177 °C it is 108 cm of mercury, with volume constant. The pressure coefficient of the gas is
(a) 1/273 per °C
(b) 1/450 per °C
(c) 1/150 per °C
(d) 1/300 per °C
Show Answer & Explanation

Answer: (a) 1/273 per °C

Explanation:
1. P = P0(1 + α t).
2. 72 = P0(1 + 27α) and 108 = P0(1 + 177α).
3. Dividing, 2(1 + 177α) = 3(1 + 27α), so 273α = 1.

Teacher's Note:
1. Pressure coefficient and volume coefficient are both 1/273 for a perfect gas.
2. The same working is used for both.

Question 21: The volume of a gas is 300 cm³ at 70 cm of mercury pressure. If the pressure is raised to 80 cm at constant temperature, the new volume is
(a) 262.5 cm³
(b) 240 cm³
(c) 342.9 cm³
(d) 285 cm³
Show Answer & Explanation

Answer: (a) 262.5 cm³

Explanation:
1. Boyle's law: P1V1 = P2V2.
2. 70 × 300 = 80 × V2, so V2 = 21 000 / 80 = 262.5 cm³.

Teacher's Note:
1. Pressure and volume change in opposite directions.
2. Check that V2 is smaller than V1 when pressure rises.

Question 22: The pressure of one standard atmosphere, 76 cm of mercury, in SI units is nearly (density of mercury 13.6 × 10³ kg/m³, g = 9.8 m/s²)
(a) 1.013 × 10⁷ Pa
(b) 1.013 × 10⁵ Pa
(c) 7.6 × 10⁴ Pa
(d) 1.013 × 10³ Pa
Show Answer & Explanation

Answer: (b) 1.013 × 10⁵ Pa

Explanation:
1. P = hdg with h = 0.76 m.
2. P = 0.76 × 13.6 × 10³ × 9.8 = 1.013 × 10⁵ N/m² (Pa).

Teacher's Note:
1. 1 bar = 10⁵ Pa, so this is about 1.013 bar.
2. Convert h to metres.

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