JEE Chemistry Redox Reactions MCQs Set 11

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Multiple Choice Questions

Question 1: In acid solution, the change \( \ce{MnO4^- -> Mn^2+} \) involves
(a) oxidation by 3 electrons
(b) reduction by 3 electrons
(c) oxidation by 5 electrons
(d) reduction by 5 electrons
Show Answer & Explanation

Answer: (d) reduction by 5 electrons

Explanation:
1. Mn goes from +7 to +2, a decrease of 5 units.
2. So it is reduction, gaining 5 electrons.

Teacher's Note:
1. Oxidation is loss of electrons (oxidation number increases); reduction is gain of electrons (oxidation number decreases).
2. The oxidising agent is itself reduced and the reducing agent is itself oxidised.

Question 2: In the reaction \( \ce{4Fe + 3O2 -> 4Fe^3+ + 6O^2-} \), which statement is incorrect?
(a) It is a redox reaction
(b) Metallic iron is a reducing agent
(c) \( \ce{Fe^3+} \) is an oxidising agent
(d) Metallic iron is reduced to \( \ce{Fe^3+} \)
Show Answer & Explanation

Answer: (d) Metallic iron is reduced to \( \ce{Fe^3+} \)

Explanation:
1. Iron goes from 0 to +3, so it is oxidised (not reduced) and acts as a reducing agent.
2. Statement (d) is therefore wrong.

Teacher's Note:
1. Oxidation is loss of electrons (oxidation number increases); reduction is gain of electrons (oxidation number decreases).
2. The oxidising agent is itself reduced and the reducing agent is itself oxidised.

Question 3: When iron or zinc is added to \( \ce{CuSO4} \) solution, copper is precipitated. It is due to
(a) oxidation of \( \ce{Cu^2+} \)
(b) reduction of \( \ce{Cu^2+} \)
(c) hydrolysis of \( \ce{CuSO4} \)
(d) ionisation of \( \ce{CuSO4} \)
Show Answer & Explanation

Answer: (b) reduction of \( \ce{Cu^2+} \)

Explanation:
1. \( \ce{Cu^2+ + 2e^- -> Cu} \): the copper ions gain electrons and are reduced to metallic copper.

Teacher's Note:
1. Oxidation is loss of electrons (oxidation number increases); reduction is gain of electrons (oxidation number decreases).
2. The oxidising agent is itself reduced and the reducing agent is itself oxidised.

Question 4: In the reaction \( \ce{C2O4^2- + MnO4^- + H^+ -> Mn^2+ + CO2 + H2O} \) the reductant is
(a) \( \ce{C2O4^2-} \)
(b) \( \ce{MnO4^-} \)
(c) \( \ce{Mn^2+} \)
(d) \( \ce{H^+} \)
Show Answer & Explanation

Answer: (a) \( \ce{C2O4^2-} \)

Explanation:
1. Carbon goes from +3 (oxalate) to +4 (CO2): it is oxidised.
2. The species oxidised is the reductant: oxalate ion.

Teacher's Note:
1. Oxidation is loss of electrons (oxidation number increases); reduction is gain of electrons (oxidation number decreases).
2. The oxidising agent is itself reduced and the reducing agent is itself oxidised.

Question 5: Which of the following is the most powerful oxidising agent?
(a) \( \ce{F2} \)
(b) \( \ce{Cl2} \)
(c) \( \ce{I2} \)
(d) \( \ce{Br2} \)
Show Answer & Explanation

Answer: (a) \( \ce{F2} \)

Explanation:
1. Oxidising power decreases down the halogen group.
2. Fluorine has the highest reduction potential (+2.87 V).

Teacher's Note:
1. Oxidation is loss of electrons (oxidation number increases); reduction is gain of electrons (oxidation number decreases).
2. The oxidising agent is itself reduced and the reducing agent is itself oxidised.

Question 6: Of the four oxyacids of chlorine, the strongest oxidising agent in dilute aqueous solution is
(a) \( \ce{HClO4} \)
(b) \( \ce{HClO3} \)
(c) \( \ce{HClO2} \)
(d) \( \ce{HOCl} \)
Show Answer & Explanation

Answer: (d) \( \ce{HOCl} \)

Explanation:
1. In dilute aqueous solution the oxidising power of the oxyacids of chlorine decreases with increasing oxidation state of Cl.
2. HOCl (Cl = +1) is the strongest oxidising agent.

Teacher's Note:
1. A species whose element is in an intermediate oxidation state can act both as an oxidising and as a reducing agent.
2. In a balanced equation both atoms and charge must balance on the two sides.

Question 7: Identify the correct statement about \( \ce{H2O2} \).
(a) It acts as a reducing agent only
(b) It acts as both oxidising and reducing agent
(c) It is neither an oxidiser nor a reducer
(d) It acts as an oxidising agent only
Show Answer & Explanation

Answer: (b) It acts as both oxidising and reducing agent

Explanation:
1. Oxygen in \( \ce{H2O2} \) is in the intermediate oxidation state -1 (between -2 and 0).
2. It can therefore be reduced to -2 or oxidised to 0.

Teacher's Note:
1. A species whose element is in an intermediate oxidation state can act both as an oxidising and as a reducing agent.
2. In a balanced equation both atoms and charge must balance on the two sides.

Question 8: Which of the following behaves as both an oxidising and a reducing agent?
(a) \( \ce{H2SO4} \)
(b) \( \ce{SO2} \)
(c) \( \ce{H2S} \)
(d) \( \ce{HNO3} \)
Show Answer & Explanation

Answer: (b) \( \ce{SO2} \)

Explanation:
1. Sulphur in \( \ce{SO2} \) is +4, intermediate between -2 and +6.
2. In \( \ce{H2SO4} \) (+6) and \( \ce{HNO3} \) (+5) the element is at its maximum, and in \( \ce{H2S} \) (-2) at its minimum.

Teacher's Note:
1. A species whose element is in an intermediate oxidation state can act both as an oxidising and as a reducing agent.
2. In a balanced equation both atoms and charge must balance on the two sides.

Question 9: Which of the following is NOT a reducing agent?
(a) \( \ce{NaNO2} \)
(b) \( \ce{NaNO3} \)
(c) \( \ce{HI} \)
(d) \( \ce{SnCl2} \)
Show Answer & Explanation

Answer: (b) \( \ce{NaNO3} \)

Explanation:
1. Nitrogen in \( \ce{NaNO3} \) is already at its highest oxidation state (+5), so it can only be reduced.
2. The other three can be oxidised.

Teacher's Note:
1. A species whose element is in an intermediate oxidation state can act both as an oxidising and as a reducing agent.
2. In a balanced equation both atoms and charge must balance on the two sides.

Question 10: The strongest reducing agent among the halide ions is
(a) \( \ce{F^-} \)
(b) \( \ce{Cl^-} \)
(c) \( \ce{Br^-} \)
(d) \( \ce{I^-} \)
Show Answer & Explanation

Answer: (d) \( \ce{I^-} \)

Explanation:
1. The ease of oxidation of halide ions increases down the group.
2. Iodide is the strongest reducing agent.

Teacher's Note:
1. Oxidation is loss of electrons (oxidation number increases); reduction is gain of electrons (oxidation number decreases).
2. The oxidising agent is itself reduced and the reducing agent is itself oxidised.

Question 11: In which of the following reactions is \( \ce{H2O2} \) a reducing agent?
(a) \( \ce{2FeCl2 + 2HCl + H2O2 -> 2FeCl3 + 2H2O} \)
(b) \( \ce{Cl2 + H2O2 -> 2HCl + O2} \)
(c) \( \ce{2HI + H2O2 -> 2H2O + I2} \)
(d) \( \ce{H2SO3 + H2O2 -> H2SO4 + H2O} \)
Show Answer & Explanation

Answer: (b) \( \ce{Cl2 + H2O2 -> 2HCl + O2} \)

Explanation:
1. A reducing agent is oxidised. In (b) oxygen of H2O2 goes from -1 to 0 in O2 while Cl2 is reduced.
2. In (a), (c) and (d) H2O2 is reduced to water.

Teacher's Note:
1. Oxidation is loss of electrons (oxidation number increases); reduction is gain of electrons (oxidation number decreases).
2. The oxidising agent is itself reduced and the reducing agent is itself oxidised.

Question 12: In the reaction \( \ce{H2O + Br2 -> HOBr + HBr} \), the best description of the behaviour of bromine is
(a) oxidised only
(b) reduced only
(c) proton acceptor only
(d) both oxidised and reduced
Show Answer & Explanation

Answer: (d) both oxidised and reduced

Explanation:
1. Bromine goes from 0 to +1 (HOBr) and from 0 to -1 (HBr).
2. It is oxidised and reduced at the same time: a disproportionation.

Teacher's Note:
1. A species whose element is in an intermediate oxidation state can act both as an oxidising and as a reducing agent.
2. In a balanced equation both atoms and charge must balance on the two sides.

Question 13: In the reaction \( \ce{Ag2O + H2O2 -> 2Ag + H2O + O2} \), \( \ce{H2O2} \) acts as
(a) reducing agent
(b) oxidising agent
(c) bleaching agent
(d) none of the above
Show Answer & Explanation

Answer: (a) reducing agent

Explanation:
1. Ag(+1) is reduced to Ag(0) and oxygen of H2O2 is oxidised from -1 to 0.
2. So H2O2 is the reducing agent.

Teacher's Note:
1. Oxidation is loss of electrons (oxidation number increases); reduction is gain of electrons (oxidation number decreases).
2. The oxidising agent is itself reduced and the reducing agent is itself oxidised.

Question 14: In the reaction \( \ce{P + NaOH -> PH3 + NaH2PO2} \) (balanced form: \( \ce{4P + 3NaOH + 3H2O -> PH3 + 3NaH2PO2} \))
(a) P is oxidised only
(b) P is reduced only
(c) P is oxidised as well as reduced
(d) Na is reduced
Show Answer & Explanation

Answer: (c) P is oxidised as well as reduced

Explanation:
1. P goes from 0 to -3 in \( \ce{PH3} \) (reduction) and from 0 to +1 in \( \ce{NaH2PO2} \) (oxidation).

Teacher's Note:
1. A species whose element is in an intermediate oxidation state can act both as an oxidising and as a reducing agent.
2. In a balanced equation both atoms and charge must balance on the two sides.

Question 15: The oxidation number of Mn in \( \ce{MnO4^-} \) is
(a) +7
(b) -5
(c) +6
(d) +5
Show Answer & Explanation

Answer: (a) +7

Explanation:
1. x + 4(-2) = -1, so x = +7.

Teacher's Note:
1. Assign oxidation numbers with the rules: sum = charge of the species, O is usually -2, H is +1, halogens in halides -1.
2. Write x for the unknown element, then solve the sum of all oxidation numbers.

Question 16: The oxidation number of Ba in barium peroxide is
(a) +6
(b) +2
(c) 1
(d) +4
Show Answer & Explanation

Answer: (b) +2

Explanation:
1. Barium is an alkaline earth metal, always +2; the peroxide ion is \( \ce{O2^2-} \).

Teacher's Note:
1. Assign oxidation numbers with the rules: sum = charge of the species, O is usually -2, H is +1, halogens in halides -1.
2. Write x for the unknown element, then solve the sum of all oxidation numbers.

Question 17: Chlorine is in the +1 oxidation state in
(a) \( \ce{HCl} \)
(b) \( \ce{HClO4} \)
(c) \( \ce{ICl} \)
(d) \( \ce{Cl2O} \)
Show Answer & Explanation

Answer: (d) \( \ce{Cl2O} \)

Explanation:
1. In HCl and ICl chlorine is the more electronegative atom, so it is -1.
2. In \( \ce{HClO4} \) it is +7. In \( \ce{Cl2O} \): 2x + (-2) = 0, so x = +1.

Teacher's Note:
1. Assign oxidation numbers with the rules: sum = charge of the species, O is usually -2, H is +1, halogens in halides -1.
2. Write x for the unknown element, then solve the sum of all oxidation numbers.

Question 18: In the reaction \( \ce{Cl2 + H2S -> 2HCl + S} \), the oxidation number of sulphur changes from
(a) 0 to 2
(b) 2 to 0
(c) -2 to 0
(d) -2 to -1
Show Answer & Explanation

Answer: (c) -2 to 0

Explanation:
1. Sulphur in H2S is -2 and in elemental S it is 0: it is oxidised.

Teacher's Note:
1. Assign oxidation numbers with the rules: sum = charge of the species, O is usually -2, H is +1, halogens in halides -1.
2. Write x for the unknown element, then solve the sum of all oxidation numbers.

Question 19: The oxidation number of cobalt in \( \ce{K[Co(CO)4]} \) is
(a) +1
(b) +3
(c) -1
(d) -3
Show Answer & Explanation

Answer: (c) -1

Explanation:
1. K is +1, CO is neutral, and the complex ion carries a charge of -1.
2. So Co = -1.

Teacher's Note:
1. Assign oxidation numbers with the rules: sum = charge of the species, O is usually -2, H is +1, halogens in halides -1.
2. Write x for the unknown element, then solve the sum of all oxidation numbers.

Question 20: When \( \ce{K2Cr2O7} \) is converted to \( \ce{K2CrO4} \), the change in the oxidation state of chromium is
(a) 0
(b) 6
(c) 4
(d) 3
Show Answer & Explanation

Answer: (a) 0

Explanation:
1. Chromium is +6 in both dichromate and chromate: the change is zero (no redox).

Teacher's Note:
1. Assign oxidation numbers with the rules: sum = charge of the species, O is usually -2, H is +1, halogens in halides -1.
2. Write x for the unknown element, then solve the sum of all oxidation numbers.

Question 21: In the conversion \( \ce{Br2 -> BrO3^-} \), the oxidation state of bromine changes from
(a) -1 to -1
(b) 0 to -1
(c) 0 to +5
(d) 0 to -5
Show Answer & Explanation

Answer: (c) 0 to +5

Explanation:
1. Br2 is 0; in \( \ce{BrO3^-} \): x + 3(-2) = -1, so x = +5.

Teacher's Note:
1. Assign oxidation numbers with the rules: sum = charge of the species, O is usually -2, H is +1, halogens in halides -1.
2. Write x for the unknown element, then solve the sum of all oxidation numbers.

Question 22: The oxidation state of sulphur in \( \ce{H2S2O8} \) (peroxodisulphuric acid) is
(a) +2
(b) +4
(c) +6
(d) +7
Show Answer & Explanation

Answer: (c) +6

Explanation:
1. The molecule has one peroxide link, so two oxygen atoms are -1 and six are -2.
2. 2(+1) + 2x + 2(-1) + 6(-2) = 0 gives x = +6.

Teacher's Note:
1. Assign oxidation numbers with the rules: sum = charge of the species, O is usually -2, H is +1, halogens in halides -1.
2. Write x for the unknown element, then solve the sum of all oxidation numbers.

Question 23: The oxidation state of nitrogen in \( \ce{N3H} \) (hydrazoic acid) is
(a) +1/3
(b) +3
(c) -1
(d) -1/3
Show Answer & Explanation

Answer: (d) -1/3

Explanation:
1. +1 + 3x = 0, so x = -1/3 (average oxidation state).

Teacher's Note:
1. Assign oxidation numbers with the rules: sum = charge of the species, O is usually -2, H is +1, halogens in halides -1.
2. Write x for the unknown element, then solve the sum of all oxidation numbers.

Question 24: The oxidation state of Pt in \( \ce{[Pt(C2H4)Cl3]^-} \) is
(a) +1
(b) +2
(c) +3
(d) +4
Show Answer & Explanation

Answer: (b) +2

Explanation:
1. Ethene is neutral and each Cl is -1: x + 0 + 3(-1) = -1, so x = +2.

Teacher's Note:
1. Assign oxidation numbers with the rules: sum = charge of the species, O is usually -2, H is +1, halogens in halides -1.
2. Write x for the unknown element, then solve the sum of all oxidation numbers.

Question 25: Sulphur has the highest oxidation state in
(a) \( \ce{SO2} \)
(b) \( \ce{H2SO4} \)
(c) \( \ce{Na2S2O3} \)
(d) \( \ce{Na2S4O6} \)
Show Answer & Explanation

Answer: (b) \( \ce{H2SO4} \)

Explanation:
1. SO2: +4; H2SO4: +6; Na2S2O3: +2; Na2S4O6: +2.5 (average).
2. The highest is +6 in H2SO4.

Teacher's Note:
1. Assign oxidation numbers with the rules: sum = charge of the species, O is usually -2, H is +1, halogens in halides -1.
2. Write x for the unknown element, then solve the sum of all oxidation numbers.

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