Practice MCQs for JEE Chemistry Redox Reactions
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Multiple Choice Questions
(a) oxidation by 3 electrons
(b) reduction by 3 electrons
(c) oxidation by 5 electrons
(d) reduction by 5 electrons
Show Answer & Explanation
Answer: (d) reduction by 5 electrons
Explanation:
1. Mn goes from +7 to +2, a decrease of 5 units.
2. So it is reduction, gaining 5 electrons.
Teacher's Note:
1. Oxidation is loss of electrons (oxidation number increases); reduction is gain of electrons (oxidation number decreases).
2. The oxidising agent is itself reduced and the reducing agent is itself oxidised.
(a) It is a redox reaction
(b) Metallic iron is a reducing agent
(c) \( \ce{Fe^3+} \) is an oxidising agent
(d) Metallic iron is reduced to \( \ce{Fe^3+} \)
Show Answer & Explanation
Answer: (d) Metallic iron is reduced to \( \ce{Fe^3+} \)
Explanation:
1. Iron goes from 0 to +3, so it is oxidised (not reduced) and acts as a reducing agent.
2. Statement (d) is therefore wrong.
Teacher's Note:
1. Oxidation is loss of electrons (oxidation number increases); reduction is gain of electrons (oxidation number decreases).
2. The oxidising agent is itself reduced and the reducing agent is itself oxidised.
(a) oxidation of \( \ce{Cu^2+} \)
(b) reduction of \( \ce{Cu^2+} \)
(c) hydrolysis of \( \ce{CuSO4} \)
(d) ionisation of \( \ce{CuSO4} \)
Show Answer & Explanation
Answer: (b) reduction of \( \ce{Cu^2+} \)
Explanation:
1. \( \ce{Cu^2+ + 2e^- -> Cu} \): the copper ions gain electrons and are reduced to metallic copper.
Teacher's Note:
1. Oxidation is loss of electrons (oxidation number increases); reduction is gain of electrons (oxidation number decreases).
2. The oxidising agent is itself reduced and the reducing agent is itself oxidised.
(a) \( \ce{C2O4^2-} \)
(b) \( \ce{MnO4^-} \)
(c) \( \ce{Mn^2+} \)
(d) \( \ce{H^+} \)
Show Answer & Explanation
Answer: (a) \( \ce{C2O4^2-} \)
Explanation:
1. Carbon goes from +3 (oxalate) to +4 (CO2): it is oxidised.
2. The species oxidised is the reductant: oxalate ion.
Teacher's Note:
1. Oxidation is loss of electrons (oxidation number increases); reduction is gain of electrons (oxidation number decreases).
2. The oxidising agent is itself reduced and the reducing agent is itself oxidised.
(a) \( \ce{F2} \)
(b) \( \ce{Cl2} \)
(c) \( \ce{I2} \)
(d) \( \ce{Br2} \)
Show Answer & Explanation
Answer: (a) \( \ce{F2} \)
Explanation:
1. Oxidising power decreases down the halogen group.
2. Fluorine has the highest reduction potential (+2.87 V).
Teacher's Note:
1. Oxidation is loss of electrons (oxidation number increases); reduction is gain of electrons (oxidation number decreases).
2. The oxidising agent is itself reduced and the reducing agent is itself oxidised.
(a) \( \ce{HClO4} \)
(b) \( \ce{HClO3} \)
(c) \( \ce{HClO2} \)
(d) \( \ce{HOCl} \)
Show Answer & Explanation
Answer: (d) \( \ce{HOCl} \)
Explanation:
1. In dilute aqueous solution the oxidising power of the oxyacids of chlorine decreases with increasing oxidation state of Cl.
2. HOCl (Cl = +1) is the strongest oxidising agent.
Teacher's Note:
1. A species whose element is in an intermediate oxidation state can act both as an oxidising and as a reducing agent.
2. In a balanced equation both atoms and charge must balance on the two sides.
(a) It acts as a reducing agent only
(b) It acts as both oxidising and reducing agent
(c) It is neither an oxidiser nor a reducer
(d) It acts as an oxidising agent only
Show Answer & Explanation
Answer: (b) It acts as both oxidising and reducing agent
Explanation:
1. Oxygen in \( \ce{H2O2} \) is in the intermediate oxidation state -1 (between -2 and 0).
2. It can therefore be reduced to -2 or oxidised to 0.
Teacher's Note:
1. A species whose element is in an intermediate oxidation state can act both as an oxidising and as a reducing agent.
2. In a balanced equation both atoms and charge must balance on the two sides.
(a) \( \ce{H2SO4} \)
(b) \( \ce{SO2} \)
(c) \( \ce{H2S} \)
(d) \( \ce{HNO3} \)
Show Answer & Explanation
Answer: (b) \( \ce{SO2} \)
Explanation:
1. Sulphur in \( \ce{SO2} \) is +4, intermediate between -2 and +6.
2. In \( \ce{H2SO4} \) (+6) and \( \ce{HNO3} \) (+5) the element is at its maximum, and in \( \ce{H2S} \) (-2) at its minimum.
Teacher's Note:
1. A species whose element is in an intermediate oxidation state can act both as an oxidising and as a reducing agent.
2. In a balanced equation both atoms and charge must balance on the two sides.
(a) \( \ce{NaNO2} \)
(b) \( \ce{NaNO3} \)
(c) \( \ce{HI} \)
(d) \( \ce{SnCl2} \)
Show Answer & Explanation
Answer: (b) \( \ce{NaNO3} \)
Explanation:
1. Nitrogen in \( \ce{NaNO3} \) is already at its highest oxidation state (+5), so it can only be reduced.
2. The other three can be oxidised.
Teacher's Note:
1. A species whose element is in an intermediate oxidation state can act both as an oxidising and as a reducing agent.
2. In a balanced equation both atoms and charge must balance on the two sides.
(a) \( \ce{F^-} \)
(b) \( \ce{Cl^-} \)
(c) \( \ce{Br^-} \)
(d) \( \ce{I^-} \)
Show Answer & Explanation
Answer: (d) \( \ce{I^-} \)
Explanation:
1. The ease of oxidation of halide ions increases down the group.
2. Iodide is the strongest reducing agent.
Teacher's Note:
1. Oxidation is loss of electrons (oxidation number increases); reduction is gain of electrons (oxidation number decreases).
2. The oxidising agent is itself reduced and the reducing agent is itself oxidised.
(a) \( \ce{2FeCl2 + 2HCl + H2O2 -> 2FeCl3 + 2H2O} \)
(b) \( \ce{Cl2 + H2O2 -> 2HCl + O2} \)
(c) \( \ce{2HI + H2O2 -> 2H2O + I2} \)
(d) \( \ce{H2SO3 + H2O2 -> H2SO4 + H2O} \)
Show Answer & Explanation
Answer: (b) \( \ce{Cl2 + H2O2 -> 2HCl + O2} \)
Explanation:
1. A reducing agent is oxidised. In (b) oxygen of H2O2 goes from -1 to 0 in O2 while Cl2 is reduced.
2. In (a), (c) and (d) H2O2 is reduced to water.
Teacher's Note:
1. Oxidation is loss of electrons (oxidation number increases); reduction is gain of electrons (oxidation number decreases).
2. The oxidising agent is itself reduced and the reducing agent is itself oxidised.
(a) oxidised only
(b) reduced only
(c) proton acceptor only
(d) both oxidised and reduced
Show Answer & Explanation
Answer: (d) both oxidised and reduced
Explanation:
1. Bromine goes from 0 to +1 (HOBr) and from 0 to -1 (HBr).
2. It is oxidised and reduced at the same time: a disproportionation.
Teacher's Note:
1. A species whose element is in an intermediate oxidation state can act both as an oxidising and as a reducing agent.
2. In a balanced equation both atoms and charge must balance on the two sides.
(a) reducing agent
(b) oxidising agent
(c) bleaching agent
(d) none of the above
Show Answer & Explanation
Answer: (a) reducing agent
Explanation:
1. Ag(+1) is reduced to Ag(0) and oxygen of H2O2 is oxidised from -1 to 0.
2. So H2O2 is the reducing agent.
Teacher's Note:
1. Oxidation is loss of electrons (oxidation number increases); reduction is gain of electrons (oxidation number decreases).
2. The oxidising agent is itself reduced and the reducing agent is itself oxidised.
(a) P is oxidised only
(b) P is reduced only
(c) P is oxidised as well as reduced
(d) Na is reduced
Show Answer & Explanation
Answer: (c) P is oxidised as well as reduced
Explanation:
1. P goes from 0 to -3 in \( \ce{PH3} \) (reduction) and from 0 to +1 in \( \ce{NaH2PO2} \) (oxidation).
Teacher's Note:
1. A species whose element is in an intermediate oxidation state can act both as an oxidising and as a reducing agent.
2. In a balanced equation both atoms and charge must balance on the two sides.
(a) +7
(b) -5
(c) +6
(d) +5
Show Answer & Explanation
Answer: (a) +7
Explanation:
1. x + 4(-2) = -1, so x = +7.
Teacher's Note:
1. Assign oxidation numbers with the rules: sum = charge of the species, O is usually -2, H is +1, halogens in halides -1.
2. Write x for the unknown element, then solve the sum of all oxidation numbers.
(a) +6
(b) +2
(c) 1
(d) +4
Show Answer & Explanation
Answer: (b) +2
Explanation:
1. Barium is an alkaline earth metal, always +2; the peroxide ion is \( \ce{O2^2-} \).
Teacher's Note:
1. Assign oxidation numbers with the rules: sum = charge of the species, O is usually -2, H is +1, halogens in halides -1.
2. Write x for the unknown element, then solve the sum of all oxidation numbers.
(a) \( \ce{HCl} \)
(b) \( \ce{HClO4} \)
(c) \( \ce{ICl} \)
(d) \( \ce{Cl2O} \)
Show Answer & Explanation
Answer: (d) \( \ce{Cl2O} \)
Explanation:
1. In HCl and ICl chlorine is the more electronegative atom, so it is -1.
2. In \( \ce{HClO4} \) it is +7. In \( \ce{Cl2O} \): 2x + (-2) = 0, so x = +1.
Teacher's Note:
1. Assign oxidation numbers with the rules: sum = charge of the species, O is usually -2, H is +1, halogens in halides -1.
2. Write x for the unknown element, then solve the sum of all oxidation numbers.
(a) 0 to 2
(b) 2 to 0
(c) -2 to 0
(d) -2 to -1
Show Answer & Explanation
Answer: (c) -2 to 0
Explanation:
1. Sulphur in H2S is -2 and in elemental S it is 0: it is oxidised.
Teacher's Note:
1. Assign oxidation numbers with the rules: sum = charge of the species, O is usually -2, H is +1, halogens in halides -1.
2. Write x for the unknown element, then solve the sum of all oxidation numbers.
(a) +1
(b) +3
(c) -1
(d) -3
Show Answer & Explanation
Answer: (c) -1
Explanation:
1. K is +1, CO is neutral, and the complex ion carries a charge of -1.
2. So Co = -1.
Teacher's Note:
1. Assign oxidation numbers with the rules: sum = charge of the species, O is usually -2, H is +1, halogens in halides -1.
2. Write x for the unknown element, then solve the sum of all oxidation numbers.
(a) 0
(b) 6
(c) 4
(d) 3
Show Answer & Explanation
Answer: (a) 0
Explanation:
1. Chromium is +6 in both dichromate and chromate: the change is zero (no redox).
Teacher's Note:
1. Assign oxidation numbers with the rules: sum = charge of the species, O is usually -2, H is +1, halogens in halides -1.
2. Write x for the unknown element, then solve the sum of all oxidation numbers.
(a) -1 to -1
(b) 0 to -1
(c) 0 to +5
(d) 0 to -5
Show Answer & Explanation
Answer: (c) 0 to +5
Explanation:
1. Br2 is 0; in \( \ce{BrO3^-} \): x + 3(-2) = -1, so x = +5.
Teacher's Note:
1. Assign oxidation numbers with the rules: sum = charge of the species, O is usually -2, H is +1, halogens in halides -1.
2. Write x for the unknown element, then solve the sum of all oxidation numbers.
(a) +2
(b) +4
(c) +6
(d) +7
Show Answer & Explanation
Answer: (c) +6
Explanation:
1. The molecule has one peroxide link, so two oxygen atoms are -1 and six are -2.
2. 2(+1) + 2x + 2(-1) + 6(-2) = 0 gives x = +6.
Teacher's Note:
1. Assign oxidation numbers with the rules: sum = charge of the species, O is usually -2, H is +1, halogens in halides -1.
2. Write x for the unknown element, then solve the sum of all oxidation numbers.
(a) +1/3
(b) +3
(c) -1
(d) -1/3
Show Answer & Explanation
Answer: (d) -1/3
Explanation:
1. +1 + 3x = 0, so x = -1/3 (average oxidation state).
Teacher's Note:
1. Assign oxidation numbers with the rules: sum = charge of the species, O is usually -2, H is +1, halogens in halides -1.
2. Write x for the unknown element, then solve the sum of all oxidation numbers.
(a) +1
(b) +2
(c) +3
(d) +4
Show Answer & Explanation
Answer: (b) +2
Explanation:
1. Ethene is neutral and each Cl is -1: x + 0 + 3(-1) = -1, so x = +2.
Teacher's Note:
1. Assign oxidation numbers with the rules: sum = charge of the species, O is usually -2, H is +1, halogens in halides -1.
2. Write x for the unknown element, then solve the sum of all oxidation numbers.
(a) \( \ce{SO2} \)
(b) \( \ce{H2SO4} \)
(c) \( \ce{Na2S2O3} \)
(d) \( \ce{Na2S4O6} \)
Show Answer & Explanation
Answer: (b) \( \ce{H2SO4} \)
Explanation:
1. SO2: +4; H2SO4: +6; Na2S2O3: +2; Na2S4O6: +2.5 (average).
2. The highest is +6 in H2SO4.
Teacher's Note:
1. Assign oxidation numbers with the rules: sum = charge of the species, O is usually -2, H is +1, halogens in halides -1.
2. Write x for the unknown element, then solve the sum of all oxidation numbers.
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