JEE Physics Thermodynamics MCQs Set 22

Practice MCQs for JEE Physics Thermodynamics

Access targeted multiple-choice questions for Thermodynamics designed to align with the latest JEE academic syllabus for JEE Physics. These objective practice sets help students evaluate their conceptual understanding and improve exam readiness.

Access Thermodynamics Questions and Solutions

Access the complete set of multiple-choice questions for Thermodynamics below. This focused format allows students to isolate specific topics for thorough review and uninterrupted practice alongside official JEE textbooks.

Multiple Choice Questions

Question 1: A sample of an ideal gas is taken through the cyclic process abca. The change in the internal energy of the gas along the path ca is \(-180\) J. The gas absorbs 250 J of heat along the path ab and 60 J along the path bc. The work done by the gas along the path abc is
(a) 120 J
(b) 100 J
(c) 130 J
(d) 140 J
Show Answer & Explanation

Answer: (c) 130 J

Explanation:
1. Over the cycle \( \Delta U=0 \), so \( \Delta U_{ab}+\Delta U_{bc}=-\Delta U_{ca}=180 \) J.
2. Heat absorbed along abc \( =250+60=310 \) J, so \( W_{abc}=Q-\Delta U=310-180=130 \) J.

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 2: When heat Q is supplied to a diatomic gas of rigid molecules at constant volume, its temperature increases by \( \Delta T \). The heat required to produce the same change in temperature at constant pressure is
(a) \( \dfrac23Q \)
(b) \( \dfrac53Q \)
(c) \( \dfrac32Q \)
(d) \( \dfrac75Q \)
Show Answer & Explanation

Answer: (d) \( \dfrac75Q \)

Explanation:
1. \( Q=nC_V\Delta T=n\cdot\tfrac52R\Delta T \).
2. At constant pressure \( Q'=n\cdot\tfrac72R\Delta T=\dfrac75Q \).

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 3: Two processes A and B take a gas from the same initial state i to the same final state f on a p-V diagram, both being expansions, with the curve of A lying above that of B. If \( \Delta Q_A \), \( \Delta Q_B \) are the heats absorbed and \( \Delta U_A \), \( \Delta U_B \) the changes in internal energy, then
(a) \( \Delta Q_A\gt \Delta Q_B,\ \Delta U_A\gt \Delta U_B \)
(b) \( \Delta Q_A\gt \Delta Q_B,\ \Delta U_A=\Delta U_B \)
(c) \( \Delta Q_A\lt \Delta Q_B,\ \Delta U_A\lt \Delta U_B \)
(d) \( \Delta Q_A=\Delta Q_B,\ \Delta U_A=\Delta U_B \)
Show Answer & Explanation

Answer: (b) \( \Delta Q_A\gt \Delta Q_B,\ \Delta U_A=\Delta U_B \)

Explanation:
1. \( \Delta U \) depends only on the end states, so \( \Delta U_A=\Delta U_B \).
2. Work is the area under the curve: \( W_A\gt W_B \). By \( Q=\Delta U+W \), \( \Delta Q_A\gt \Delta Q_B \).

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 4: On a p-V diagram four curves start from a common point: a is a horizontal line, b is a gently falling curve, c is a more steeply falling curve and d is a vertical line going down. Which assignment of the processes isochoric, isobaric, isothermal and adiabatic, in that order, is correct?
(a) a, d, b, c
(b) d, a, c, b
(c) d, a, b, c
(d) a, d, c, b
Show Answer & Explanation

Answer: (c) d, a, b, c

Explanation:
1. A vertical line is constant volume (isochoric) and a horizontal line is constant pressure (isobaric).
2. The adiabatic curve \( pV^\gamma= \) const is steeper than the isotherm \( pV= \) const, so b is isothermal and c is adiabatic: d, a, b, c.

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 5: A gas goes through the cyclic process CAB on a p-V diagram: from C (V = 1 m\(^3\), p = 6.0 Pa) at constant pressure to A (V = 5 m\(^3\), p = 6.0 Pa), then at constant volume down to B (V = 5 m\(^3\), p = 1 Pa), then along a straight line back to C. The work done in the cycle is
(a) 5 J
(b) 1 J
(c) 30 J
(d) 10 J
Show Answer & Explanation

Answer: (d) 10 J

Explanation:
1. Net work is the area enclosed: a right triangle with base \( 5-1=4 \) m\(^3\) and height \( 6-1=5 \) Pa.
2. Area \( =\tfrac12\times4\times5=10 \) J; the cycle runs C to A to B to C, so the work done by the gas is positive.

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 6: Half a mole of an ideal monoatomic gas is heated at constant pressure of 1 atm from 20 \(^\circ\)C to 90 \(^\circ\)C. The work done by the gas is close to (take R = 8.31 J/mol-K)
(a) 581 J
(b) 291 J
(c) 146 J
(d) 73 J
Show Answer & Explanation

Answer: (b) 291 J

Explanation:
1. Isobaric work \( W=nR\Delta T \).
2. \( W=0.5\times8.31\times70\approx291 \) J.

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 7: Three Carnot engines operate in series between a heat source at temperature \( T_1 \) and a heat sink at temperature \( T_4 \). There are two other reservoirs at temperatures \( T_2 \) and \( T_3 \), with \( T_1\gt T_2\gt T_3\gt T_4 \) (engine 1 works between \( T_1 \) and \( T_2 \), engine 2 between \( T_2 \) and \( T_3 \), engine 3 between \( T_3 \) and \( T_4 \)). The three engines are equally efficient if
(a) \( T_2=(T_1^3T_4)^{1/4};\ T_3=(T_1T_4^3)^{1/4} \)
(b) \( T_2=(T_1T_4)^{1/2};\ T_3=(T_1^2T_4)^{1/3} \)
(c) \( T_2=(T_1^2T_4)^{1/3};\ T_3=(T_1T_4^2)^{1/3} \)
(d) \( T_2=(T_1T_4^2)^{1/3};\ T_3=(T_1^2T_4)^{1/3} \)
Show Answer & Explanation

Answer: (c) \( T_2=(T_1^2T_4)^{1/3};\ T_3=(T_1T_4^2)^{1/3} \)

Explanation:
1. Equal efficiencies mean equal ratios: \( \dfrac{T_2}{T_1}=\dfrac{T_3}{T_2}=\dfrac{T_4}{T_3}=r \), so \( r^3=\dfrac{T_4}{T_1} \).
2. \( T_2=T_1r=T_1^{2/3}T_4^{1/3} \) and \( T_3=T_1r^2=T_1^{1/3}T_4^{2/3} \).

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 8: Two Carnot engines A and B are operated in series. The first one, A, receives heat at \( T_1 \) (= 600 K) and rejects to a reservoir at temperature \( T_2 \). The second engine B receives the heat rejected by the first engine and in turn rejects heat to a reservoir at \( T_3 \) (= 400 K). The temperature \( T_2 \) if the work outputs of the two engines are equal is
(a) 600 K
(b) 400 K
(c) 300 K
(d) 500 K
Show Answer & Explanation

Answer: (d) 500 K

Explanation:
1. For a Carnot engine \( W=Q_1\dfrac{T_{hot}-T_{cold}}{T_{hot}} \), and the heat rejected by A is the heat received by B. Heat is proportional to temperature through the chain \( \dfrac{Q_1}{T_1}=\dfrac{Q_2}{T_2}=\dfrac{Q_3}{T_3} \).
2. Equal work: \( Q_1-Q_2=Q_2-Q_3\Rightarrow T_1-T_2=T_2-T_3\Rightarrow T_2=\dfrac{600+400}2=500 \) K.

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 9: Two moles of an ideal monoatomic gas occupies a volume V at 27 \(^\circ\)C. The gas expands adiabatically to a volume 2V. The final temperature of the gas and the change in its internal energy are close to (R = 8.3 J/mol-K)
(a) 195 K and 2.7 kJ
(b) 189 K and \(-2.7\) kJ
(c) 189 K and 2.7 kJ
(d) 195 K and \(-2.7\) kJ
Show Answer & Explanation

Answer: (b) 189 K and \(-2.7\) kJ

Explanation:
1. Adiabatic: \( T_2=T_1\left(\dfrac{V_1}{V_2}\right)^{\gamma-1}=300\left(\dfrac12\right)^{2/3}\approx189 \) K.
2. \( \Delta U=nC_V\Delta T=2\times\tfrac32\times8.3\times(189-300)\approx-2.7 \) kJ (the internal energy decreases).

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 10: n moles of an ideal gas undergo a process from state A \( (V_0,\,2p_0) \) to state B \( (2V_0,\,p_0) \) along a straight line on the p-V diagram. The maximum temperature of the gas during the process will be
(a) \( \dfrac{3p_0V_0}{2nR} \)
(b) \( \dfrac{9p_0V_0}{2nR} \)
(c) \( \dfrac{9p_0V_0}{4nR} \)
(d) \( \dfrac{9p_0V_0}{nR} \)
Show Answer & Explanation

Answer: (c) \( \dfrac{9p_0V_0}{4nR} \)

Explanation:
1. The line is \( p=3p_0-\dfrac{p_0}{V_0}V \), so \( T=\dfrac{pV}{nR}=\dfrac{1}{nR}\left(3p_0V-\dfrac{p_0V^2}{V_0}\right) \).
2. \( \dfrac{dT}{dV}=0\Rightarrow V=1.5V_0,\ p=1.5p_0 \), giving \( T_{max}=\dfrac{2.25p_0V_0}{nR}=\dfrac{9p_0V_0}{4nR} \).

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 11: A gas is enclosed in a cylinder with a movable frictionless piston. Its initial thermodynamic state is at pressure \( p_i=10^5 \) Pa and volume \( V_i=10^{-3} \) m\(^3\), and it changes to a final state at \( p_f=\left(\dfrac1{32}\right)\times10^5 \) Pa and \( V_f=8\times10^{-3} \) m\(^3\) in an adiabatic quasi-static process, such that \( p^3V^5= \) constant. Consider another process that brings the system from the same initial state to the same final state in two steps: an isobaric expansion at \( p_i \) followed by an isochoric (isovolumetric) process at volume \( V_f \). The amount of heat supplied to the system in the two-step process is approximately
(a) 112 J
(b) 294 J
(c) 813 J
(d) 588 J
Show Answer & Explanation

Answer: (d) 588 J

Explanation:
1. \( p^3V^5= \) const means \( pV^{5/3}= \) const, a monoatomic gas: \( \Delta U=\tfrac32(p_fV_f-p_iV_i)=\tfrac32(25-100)=-112.5 \) J.
2. Isobaric step work \( =p_i(V_f-V_i)=10^5\times7\times10^{-3}=700 \) J, none in the isochoric step. \( Q=\Delta U+W=-112.5+700\approx588 \) J.

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 12: The p-V diagram represents the thermodynamic cycle of an engine operating with a monoatomic ideal gas: A \( (V_0,p_0) \) to B \( (V_0,2p_0) \) at constant volume, B to C \( (2V_0,2p_0) \) at constant pressure, C to D \( (2V_0,p_0) \) at constant volume, and D to A at constant pressure. The amount of heat extracted from the source in a single cycle is
(a) \( p_0V_0 \)
(b) \( \dfrac{13}{2}p_0V_0 \)
(c) \( \dfrac{11}{2}p_0V_0 \)
(d) \( 4p_0V_0 \)
Show Answer & Explanation

Answer: (b) \( \dfrac{13}{2}p_0V_0 \)

Explanation:
1. Heat is absorbed in AB (isochoric, temperature rises) and BC (isobaric expansion). AB: \( Q=\tfrac32(2p_0-p_0)V_0=\tfrac32p_0V_0 \).
2. BC: \( Q=\tfrac52(2p_0)(2V_0-V_0)=5p_0V_0 \). Total from the source \( =\dfrac{13}{2}p_0V_0 \) (CD and DA reject heat).

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 13: One mole of a monoatomic ideal gas is taken along two cyclic processes \( E\to F\to G\to E \) and \( E\to F\to H\to E \) on a p-V diagram. E is at \( (V_0,p_0) \), F is at \( (V_0,32p_0) \); the points G and H both lie on the line of pressure \( p_0 \), with F to G isothermal and F to H adiabatic. The processes are purely isochoric, isobaric, isothermal or adiabatic. The magnitudes of the work done: P is \( G\to E \), Q is \( G\to H \), R is \( F\to H \) and S is \( F\to G \). The correct matching with 1: \( 160p_0V_0\ln2 \), 2: \( 36p_0V_0 \), 3: \( 24p_0V_0 \), 4: \( 31p_0V_0 \) is
(a) P-4, Q-3, R-1, S-2
(b) P-3, Q-1, R-2, S-4
(c) P-4, Q-3, R-2, S-1
(d) P-1, Q-3, R-2, S-4
Show Answer & Explanation

Answer: (c) P-4, Q-3, R-2, S-1

Explanation:
1. G: isotherm through F gives \( 32p_0V_0=p_0V_G\Rightarrow V_G=32V_0 \). H: adiabat \( p V^{5/3}= \) const gives \( V_H=32^{3/5}V_0=8V_0 \).
2. P (isobaric \( 32V_0\to V_0 \)): \( 31p_0V_0 \). Q (isobaric \( 32V_0\to8V_0 \)): \( 24p_0V_0 \). R (adiabatic): \( \dfrac{32p_0V_0-8p_0V_0}{2/3}=36p_0V_0 \). S (isothermal): \( 32p_0V_0\ln32=160p_0V_0\ln2 \).

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 14: An ideal gas expands isothermally from a volume \( V_1 \) to \( V_2 \) and then is compressed to the original volume \( V_1 \) adiabatically. The initial pressure is \( p_1 \) and the final pressure is \( p_3 \). The total work done is W. Then
(a) \( p_3\gt p_1,\ W\lt 0 \)
(b) \( p_3\gt p_1,\ W\gt 0 \)
(c) \( p_3\lt p_1,\ W\lt 0 \)
(d) \( p_3=p_1,\ W=0 \)
Show Answer & Explanation

Answer: (a) \( p_3\gt p_1,\ W\lt 0 \)

Explanation:
1. After the isothermal expansion the pressure is \( p_2\lt p_1 \). The adiabatic compression back to \( V_1 \) raises the temperature, so the gas ends hotter than it started and \( p_3\gt p_1 \).
2. On the p-V diagram the adiabat is steeper than the isotherm, so the compression curve lies above the expansion curve; the work done on the gas exceeds the work done by it and \( W\lt 0 \).

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 15: An ideal gas is taken through the cycle \( A\to B\to C\to A \). In the process A to B the pressure is constant at 10 N/m\(^2\) and the volume increases from 1 m\(^3\) to 2 m\(^3\); B to C is at constant volume, and C to A is a straight line. If the net heat supplied to the gas in the cycle is 5 J, the work done by the gas in the process \( C\to A \) is
(a) \(-10\) J
(b) \(-5\) J
(c) \(-15\) J
(d) \(-20\) J
Show Answer & Explanation

Answer: (b) \(-5\) J

Explanation:
1. Work in AB \( =p\Delta V=10\times1=10 \) J and work in BC (constant volume) \( =0 \).
2. Over the cycle \( W_{net}=Q_{net}=5 \) J, so \( W_{CA}=5-10-0=-5 \) J.

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 16: The p-V plots of two gases during adiabatic processes are drawn on the same diagram; plot 2 falls more steeply than plot 1. Plots 1 and 2 should correspond respectively to
(a) \( \text{He and O}_2 \)
(b) \( \text{He and Ar} \)
(c) \( \text{O}_2\text{ and He} \)
(d) \( \text{O}_2\text{ and N}_2 \)
Show Answer & Explanation

Answer: (c) \( \text{O}_2\text{ and He} \)

Explanation:
1. For an adiabatic process \( \dfrac{dp}{dV}=-\gamma\dfrac pV \): the larger the \( \gamma \), the steeper the curve.
2. Plot 2 has the larger \( \gamma \). Helium is monoatomic (\( \gamma=\tfrac53 \)) and oxygen is diatomic (\( \gamma=\tfrac75 \)), so plot 1 is O\(_2\) and plot 2 is He (O\(_2\) and N\(_2\) have the same \( \gamma \); He and Ar too).

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 17: A monoatomic ideal gas, initially at temperature \( T_1 \), is enclosed in a cylinder fitted with a frictionless piston. The gas is allowed to expand adiabatically to a temperature \( T_2 \) by releasing the piston. If \( L_1 \) and \( L_2 \) are the lengths of the gas column before and after expansion respectively, then \( T_1/T_2 \) is given by
(a) \( \left(\dfrac{L_2}{L_1}\right)^{2/3} \)
(b) \( \left(\dfrac{L_1}{L_2}\right)^{2/3} \)
(c) \( \dfrac{L_1}{L_2} \)
(d) \( \dfrac{L_2}{L_1} \)
Show Answer & Explanation

Answer: (a) \( \left(\dfrac{L_2}{L_1}\right)^{2/3} \)

Explanation:
1. Adiabatic process for a monoatomic gas: \( TV^{\gamma-1}= \) const with \( \gamma=\tfrac53 \), so \( TV^{2/3}= \) const.
2. With V proportional to L: \( T_1L_1^{2/3}=T_2L_2^{2/3}\Rightarrow\dfrac{T_1}{T_2}=\left(\dfrac{L_2}{L_1}\right)^{2/3} \).

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 18: Two cylinders A and B fitted with pistons contain equal amounts of an ideal diatomic gas at 300 K. The piston of A is free to move, while that of B is held fixed. The same amount of heat is given to the gas in each cylinder. If the rise in temperature of the gas in A is 30 K, then the rise in temperature of the gas in B is
(a) 30 K
(b) 42 K
(c) 18 K
(d) 50 K
Show Answer & Explanation

Answer: (b) 42 K

Explanation:
1. A: constant pressure, \( Q=nC_p\Delta T_A \). B: constant volume, \( Q=nC_V\Delta T_B \).
2. \( \Delta T_B=\dfrac{C_p}{C_V}\Delta T_A=1.4\times30=42 \) K.

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 19: When an ideal diatomic gas is heated at constant pressure, the fraction of the heat energy supplied which increases the internal energy of the gas is
(a) \( \dfrac25 \)
(b) \( \dfrac35 \)
(c) \( \dfrac57 \)
(d) \( \dfrac37 \)
Show Answer & Explanation

Answer: (c) \( \dfrac57 \)

Explanation:
1. Heat at constant pressure \( Q=nC_p\Delta T=\tfrac72nR\Delta T \); the part that raises the internal energy is \( \Delta U=nC_V\Delta T=\tfrac52nR\Delta T \).
2. Fraction \( =\dfrac{C_V}{C_p}=\dfrac57 \).

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 20: One mole of a monoatomic ideal gas is heated in a cylinder with a spring-loaded piston (spring initially relaxed; the pressure outside is equal to the initial gas pressure \( p_1 \); no friction). The gas goes from \( (p_1,V_1,T_1) \) to \( (p_2,V_2,T_2) \) while the piston moves out through a distance x. Which of the following statements are correct? (a) If \( V_2=2V_1 \) and \( T_2=3T_1 \), the energy stored in the spring is \( \tfrac14p_1V_1 \). (b) If \( V_2=2V_1 \) and \( T_2=3T_1 \), the change in internal energy is \( 3p_1V_1 \). (c) If \( V_2=3V_1 \) and \( T_2=4T_1 \), the work done by the gas is \( \tfrac73p_1V_1 \).
(a) (a), (b) and (c) are all correct
(b) (a) and (b) only
(c) (b) and (c) only
(d) (a) and (c) only
Show Answer & Explanation

Answer: (a) (a), (b) and (c) are all correct

Explanation:
1. Case 1: \( p_2=p_1\dfrac{T_2V_1}{T_1V_2}=1.5p_1 \). Spring force \( =(p_2-p_1)A \) over a displacement with \( Ax=V_1 \): energy \( =\tfrac12(0.5p_1)V_1=\tfrac14p_1V_1 \): (a) true. \( \Delta U=\tfrac32(p_2V_2-p_1V_1)=\tfrac32(3-1)p_1V_1=3p_1V_1 \): (b) true.
2. Case 2: \( p_2=\tfrac43p_1 \), \( Ax=2V_1 \). Work done by the gas \( =p_1(2V_1)+\tfrac12\left(\tfrac13p_1\right)(2V_1)=\tfrac73p_1V_1 \): (c) true.

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 21: During the melting of a slab of ice at 273 K at atmospheric pressure, which statements are correct? (a) Positive work is done by the ice-water system on the atmosphere. (b) Positive work is done on the ice-water system by the atmosphere. (c) The internal energy of the ice-water system increases. (d) The internal energy of the ice-water system decreases.
(a) (a) and (c) only
(b) (b) and (c) only
(c) (a) and (d) only
(d) (b) and (d) only
Show Answer & Explanation

Answer: (b) (b) and (c) only

Explanation:
1. Ice has a larger volume than the water formed from it, so the system shrinks and the atmosphere does positive work on it: (b) true, (a) false.
2. Heat is absorbed at constant temperature (latent heat) and the work done on the system is positive, so \( \Delta U=Q+W_{on}\gt 0 \): (c) true.

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 22: For an ideal gas, which statements are correct? (a) The change in internal energy in a constant pressure process from temperature \( T_1 \) to \( T_2 \) is equal to \( nC_V(T_2-T_1) \), where \( C_V \) is the molar heat capacity at constant volume and n the number of moles. (b) The change in internal energy of the gas and the work done by the gas are equal in magnitude in an adiabatic process. (c) The internal energy does not change in an isothermal process. (d) No heat is added or removed in an adiabatic process.
(a) (a), (b) and (c) only
(b) (b), (c) and (d) only
(c) (a), (b), (c) and (d)
(d) (a), (c) and (d) only
Show Answer & Explanation

Answer: (c) (a), (b), (c) and (d)

Explanation:
1. For an ideal gas U depends only on T, so \( \Delta U=nC_V\Delta T \) for any process: (a) true; \( \Delta U=0 \) when T is constant: (c) true.
2. Adiabatic means \( Q=0 \): (d) true, and then \( \Delta U=-W \): (b) true.

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 23: A thermodynamic system is taken from an initial state i with internal energy \( U_i=100 \) J to the final state f along two different paths iaf and ibf. The work done by the system along the paths af, ib and bf are \( W_{af}=200 \) J, \( W_{ib}=50 \) J and \( W_{bf}=100 \) J respectively. The heat supplied to the system along the path iaf, ib and bf are \( Q_{iaf} \), \( Q_{ib} \) and \( Q_{bf} \) respectively. If the internal energy of the system in the state b is \( U_b=200 \) J and \( Q_{iaf}=500 \) J, the ratio \( Q_{bf}/Q_{ib} \) is
(a) 2
(b) 1
(c) 3
(d) 0.5
Show Answer & Explanation

Answer: (a) 2

Explanation:
1. Path iaf: \( 500=U_f-100+200\Rightarrow U_f=400 \) J (no work in the leg ia).
2. \( Q_{ib}=(200-100)+50=150 \) J and \( Q_{bf}=(400-200)+100=300 \) J, so the ratio is 2.

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 24: A diatomic ideal gas is compressed adiabatically to \( \dfrac1{32} \) of its initial volume. If the initial temperature of the gas is \( T_i \) (in kelvin) and the final temperature is \( aT_i \), the value of a is
(a) 2
(b) 4
(c) 8
(d) 32
Show Answer & Explanation

Answer: (b) 4

Explanation:
1. \( T_fV_f^{\gamma-1}=T_iV_i^{\gamma-1} \) with \( \gamma=\tfrac75 \).
2. \( a=\left(\dfrac{V_i}{V_f}\right)^{2/5}=32^{2/5}=4 \).

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 25: On a p-V diagram an isothermal expansion and an adiabatic expansion of an ideal gas start from the same point. Compared with the isothermal curve, the adiabatic curve
(a) falls less steeply
(b) coincides with it
(c) rises with volume
(d) falls more steeply
Show Answer & Explanation

Answer: (d) falls more steeply

Explanation:
1. Isothermal slope \( =-\dfrac pV \); adiabatic slope \( =-\gamma\dfrac pV \).
2. Since \( \gamma\gt 1 \), the adiabat is steeper than the isotherm.

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 26: A metal of mass 1 kg at constant atmospheric pressure and at initial temperature 20 \(^\circ\)C is given a heat of 20000 J. (Specific heat = 400 J/kg/\(^\circ\)C, coefficient of cubical expansion \( \gamma=9\times10^{-5} \)/\(^\circ\)C, density \( \rho=9000 \) kg/m\(^3\), atmospheric pressure = \( 10^5 \) N/m\(^2\).) The change in temperature is
(a) \( 50^\circ\text{C} \)
(b) \( 20^\circ\text{C} \)
(c) \( 100^\circ\text{C} \)
(d) \( 500^\circ\text{C} \)
Show Answer & Explanation

Answer: (a) \( 50^\circ\text{C} \)

Explanation:
1. \( Q=mc\Delta T \).
2. \( \Delta T=\dfrac{20000}{1\times400}=50^\circ \)C.

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 27: For the same metal (mass 1 kg, density 9000 kg/m\(^3\), \( \gamma=9\times10^{-5} \)/\(^\circ\)C, heated through 50 \(^\circ\)C at atmospheric pressure \( 10^5 \) N/m\(^2\)), the work done by the metal against the atmosphere is
(a) 5 J
(b) 0.05 J
(c) 0.5 J
(d) 50 J
Show Answer & Explanation

Answer: (b) 0.05 J

Explanation:
1. \( V=\dfrac1{9000}=1.11\times10^{-4} \) m\(^3\) and \( \Delta V=V\gamma\Delta T=1.11\times10^{-4}\times9\times10^{-5}\times50=5\times10^{-7} \) m\(^3\).
2. \( W=p\Delta V=10^5\times5\times10^{-7}=0.05 \) J.

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 28: Two moles of a monoatomic ideal gas are taken through a cycle: A to B along a line through the origin of a V-T diagram (constant pressure) with \( V_B/V_A=2 \), B to C isothermal expansion up to \( V_D \), C to D at constant volume, and D to A isothermal compression, with \( V_D/V_A=4 \). If the temperature \( T_A \) at A is 27 \(^\circ\)C, the temperature of the gas at B is
(a) 300 K
(b) 450 K
(c) 900 K
(d) 600 K
Show Answer & Explanation

Answer: (d) 600 K

Explanation:
1. A to B is isobaric, so \( V\propto T \).
2. \( T_B=T_A\dfrac{V_B}{V_A}=300\times2=600 \) K.

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

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