JEE Physics Thermodynamics MCQs Set 23

Physics Objective Questions and Answers: Thermodynamics

Access targeted multiple-choice questions for Thermodynamics designed to align with the latest JEE academic syllabus for JEE Physics. These objective practice sets help students evaluate their conceptual understanding and improve exam readiness.

Download Thermodynamics MCQs with Answers

Navigate directly to the 50 objective questions for Thermodynamics using the digital viewer below. Each practice set includes verified answer keys, allowing students to instantly cross-check their work and identify areas requiring further revision.

Multiple Choice Questions

Question 1: For the same cycle (two moles of a monoatomic gas; AB isobaric with \( V_B=2V_A \); BC isothermal expansion to \( V_D=4V_A \); CD isochoric; DA isothermal compression; \( T_A=300 \) K), the net work done by the gas in the complete cycle is
(a) \( 600R \)
(b) \( 1200R\ln2 \)
(c) \( 300R \)
(d) \( 1500R \)
Show Answer & Explanation

Answer: (a) \( 600R \)

Explanation:
1. Heats: AB \( =nC_p\Delta T=2(2.5R)(300)=1500R \); BC \( =nRT_B\ln2=1200R\ln2 \); CD \( =nC_V\Delta T=2(1.5R)(-300)=-900R \); DA \( =nRT_A\ln\dfrac14=-1200R\ln2 \).
2. For a cycle \( W=Q_{net}=1500R-900R=600R \) (the logarithmic terms cancel).

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 2: Two moles of an ideal monoatomic gas are taken through the cycle ABCA on a p-T diagram. In the process AB, pressure and temperature vary such that \( pT= \) constant; at A the gas has pressure \( p_1 \) and temperature \( 2T_1 \), at B pressure \( 2p_1 \) and temperature \( T_1 \), at C pressure \( 2p_1 \) and temperature \( 2T_1 \) (BC is isobaric and CA isothermal). If \( T_1=300 \) K, the work done on the gas in the process AB is
(a) \( 600R \)
(b) \( 1200R \)
(c) \( 2400R \)
(d) \( 300R \)
Show Answer & Explanation

Answer: (b) \( 1200R \)

Explanation:
1. On AB \( p=\dfrac cT \) and \( V=\dfrac{nRT}{p}=\dfrac{nRT^2}{c} \), so \( dV=\dfrac{2nRT}{c}dT \).
2. Work by the gas \( =\int p\,dV=2nR\,\Delta T=2(2)R(T_1-2T_1)=-1200R \), so the work done on the gas is \( 1200R \).

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 3: For the same cycle (BC is isobaric at \( 2p_1 \) from \( T_1 \) to \( 2T_1 \), two moles of monoatomic gas, \( T_1=300 \) K), the heat absorbed by the gas in the process BC is
(a) \( 900R \)
(b) \( 600R \)
(c) \( 2100R \)
(d) \( 1500R \)
Show Answer & Explanation

Answer: (d) \( 1500R \)

Explanation:
1. Isobaric heating: \( Q=nC_p\Delta T \).
2. \( Q=2\times\tfrac52R\times300=1500R \).

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 4: Two moles of an ideal monoatomic gas, initially at pressure \( p_1 \) and volume \( V_1 \), undergo an adiabatic compression until its volume is \( V_2 \). Then the gas is given heat Q at constant volume \( V_2 \). The total work done by the gas in the complete process is
(a) \( \dfrac32p_1V_1\left[1-\left(\dfrac{V_1}{V_2}\right)^{2/3}\right] \)
(b) \( \dfrac32p_1V_1\left[\left(\dfrac{V_1}{V_2}\right)^{2/3}-1\right]+Q \)
(c) \( p_1V_1\ln\dfrac{V_2}{V_1} \)
(d) \( Q+\dfrac32p_1V_1 \)
Show Answer & Explanation

Answer: (a) \( \dfrac32p_1V_1\left[1-\left(\dfrac{V_1}{V_2}\right)^{2/3}\right] \)

Explanation:
1. Adiabatic compression: \( p_2=p_1\left(\dfrac{V_1}{V_2}\right)^{5/3} \), and the work done by the gas \( =\dfrac{p_1V_1-p_2V_2}{\gamma-1}=\dfrac32p_1V_1\left[1-\left(\dfrac{V_1}{V_2}\right)^{2/3}\right] \), which is negative since \( V_2\lt V_1 \).
2. No work is done in the constant volume heating, so this is the total work.

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 5: For the same process (2 moles of monoatomic gas, adiabatic compression from \( (p_1,V_1) \) to volume \( V_2 \), then heat Q at constant volume), the final temperature of the gas is
(a) \( \dfrac{p_1V_1}{2R}+\dfrac{Q}{3R} \)
(b) \( \dfrac{p_1V_1^{5/3}V_2^{-2/3}}{2R}+\dfrac{Q}{3R} \)
(c) \( \dfrac{p_1V_1^{5/3}V_2^{-2/3}}{2R}+\dfrac{Q}{2R} \)
(d) \( \dfrac{p_1V_1^{5/3}V_2^{-2/3}}{2R}-\dfrac{Q}{3R} \)
Show Answer & Explanation

Answer: (b) \( \dfrac{p_1V_1^{5/3}V_2^{-2/3}}{2R}+\dfrac{Q}{3R} \)

Explanation:
1. After the adiabatic compression \( p_2V_2=p_1V_1^{5/3}V_2^{-2/3} \), so \( T_2=\dfrac{p_2V_2}{nR}=\dfrac{p_1V_1^{5/3}V_2^{-2/3}}{2R} \).
2. At constant volume \( Q=nC_V\Delta T=2(1.5R)\Delta T\Rightarrow\Delta T=\dfrac{Q}{3R} \), so \( T_f=T_2+\dfrac{Q}{3R} \).

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 6: For the same cycle (A \( (V_0,p_0) \), B \( (V_0,3p_0) \), C \( (2V_0,p_0) \), one mole of a monoatomic gas), the heat rejected by the gas in the path CA and the heat absorbed by the gas in the path AB are respectively
(a) \( 3p_0V_0\text{ and }\dfrac52p_0V_0 \)
(b) \( \dfrac32p_0V_0\text{ and }3p_0V_0 \)
(c) \( \dfrac52p_0V_0\text{ and }\dfrac92p_0V_0 \)
(d) \( \dfrac52p_0V_0\text{ and }3p_0V_0 \)
Show Answer & Explanation

Answer: (d) \( \dfrac52p_0V_0\text{ and }3p_0V_0 \)

Explanation:
1. CA is isobaric compression: \( Q=nC_p\Delta T=\tfrac52p_0(V_0-2V_0)=-\tfrac52p_0V_0 \), i.e. \( \tfrac52p_0V_0 \) is rejected.
2. AB is isochoric: \( Q=\tfrac32(3p_0V_0-p_0V_0)=3p_0V_0 \), absorbed.

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 7: For the same cycle (A \( (V_0,p_0) \), B \( (V_0,3p_0) \), C \( (2V_0,p_0) \), one mole of a monoatomic gas), the net heat absorbed by the gas in the path BC is
(a) \( \dfrac12p_0V_0 \)
(b) \( p_0V_0 \)
(c) \( \dfrac52p_0V_0 \)
(d) \( 3p_0V_0 \)
Show Answer & Explanation

Answer: (a) \( \dfrac12p_0V_0 \)

Explanation:
1. Net heat in the cycle \( =W=p_0V_0=Q_{AB}+Q_{BC}+Q_{CA}=3p_0V_0+Q_{BC}-\tfrac52p_0V_0 \).
2. \( Q_{BC}=p_0V_0-\tfrac12p_0V_0=\tfrac12p_0V_0 \).

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 8: A sample of 2 kg monoatomic helium (assumed ideal, molecular mass 4) is taken through the process ABC, where A is at \( (V=10\ \text{m}^3,\ p=5\times10^4\ \text{N/m}^2) \), B at \( (10\ \text{m}^3,\ 10\times10^4\ \text{N/m}^2) \) and C at \( (20\ \text{m}^3,\ 10\times10^4\ \text{N/m}^2) \); AB is isochoric and BC is isobaric. The temperature of helium in state C is close to (R = 8.31 J/mol-K)
(a) 120 K
(b) 241 K
(c) 481 K
(d) 963 K
Show Answer & Explanation

Answer: (c) 481 K

Explanation:
1. \( n=\dfrac{2000}{4}=500 \) mol.
2. \( T_C=\dfrac{p_CV_C}{nR}=\dfrac{10\times10^4\times20}{500\times8.31}\approx481 \) K (and \( T_A\approx120 \) K, \( T_B\approx241 \) K).

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 9: Two samples of 2 kg helium go from the state A \( (10\ \text{m}^3,\,5\times10^4\ \text{N/m}^2) \) to the state C \( (20\ \text{m}^3,\,10\times10^4\ \text{N/m}^2) \), one through ABC (B at \( 10\ \text{m}^3,\,10\times10^4 \)) and the other through ADC (D at \( 20\ \text{m}^3,\,5\times10^4 \)). After the processes, can we tell which sample went through ABC and which through ADC?
(a) Yes, because the heat absorbed differs
(b) Yes, because the work done differs
(c) Yes, because the internal energy differs
(d) No, because both samples end in the same state and the internal energy is a state function
Show Answer & Explanation

Answer: (d) No, because both samples end in the same state and the internal energy is a state function

Explanation:
1. Heat and work are path functions, but the final state (pressure, volume, temperature, internal energy) of the gas depends only on the end point C.
2. Nothing in the final state records the path, so the two samples cannot be told apart.

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 10: For the helium sample (2 kg, molecular mass 4) taken from A \( (10\ \text{m}^3,\,5\times10^4\ \text{N/m}^2) \) to C \( (20\ \text{m}^3,\,10\times10^4\ \text{N/m}^2) \) through B \( (10\ \text{m}^3,\,10\times10^4) \) by the process ABC, the heat involved is
(a) \( 3.25\times10^6\ \text{J} \)
(b) \( 2.75\times10^6\ \text{J} \)
(c) \( 2.5\times10^6\ \text{J} \)
(d) \( 4.0\times10^6\ \text{J} \)
Show Answer & Explanation

Answer: (a) \( 3.25\times10^6\ \text{J} \)

Explanation:
1. AB (isochoric): \( Q=\tfrac32(p_BV-p_AV)=1.5(10^6-5\times10^5)=7.5\times10^5 \) J.
2. BC (isobaric): \( Q=\tfrac52p\Delta V=2.5\times10^5\times10=2.5\times10^6 \) J. Total \( =3.25\times10^6 \) J.

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 11: One mole of a diatomic ideal gas (\( \gamma=1.4 \)) is taken through a cyclic process starting from point A. The process \( A\to B \) is an adiabatic compression, \( B\to C \) is isobaric expansion, \( C\to D \) is an adiabatic expansion and \( D\to A \) is isochoric. The volume ratios are \( V_A/V_B=16 \) and \( V_C/V_B=2 \) and the temperature at A is \( T_A=300 \) K. The temperatures of the gas at the points B and D are respectively close to
(a) 600 K and 791 K
(b) 909 K and 450 K
(c) 909 K and 791 K
(d) 300 K and 909 K
Show Answer & Explanation

Answer: (c) 909 K and 791 K

Explanation:
1. \( T_B=T_A\left(\dfrac{V_A}{V_B}\right)^{0.4}=300\times16^{0.4}\approx909 \) K. Isobaric BC: \( T_C=2T_B=1818 \) K.
2. \( V_D=V_A=8V_C \) (since \( V_C=2V_B \) and \( V_A=16V_B \)): \( T_D=T_C\left(\dfrac{V_C}{V_D}\right)^{0.4}=1818\times8^{-0.4}\approx791 \) K.

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 12: For the same cycle (diatomic gas, \( \gamma=1.4 \); AB adiabatic compression with \( V_A/V_B=16 \); BC isobaric expansion with \( V_C/V_B=2 \); CD adiabatic expansion; DA isochoric; \( T_A=300 \) K, so \( T_B=909 \) K, \( T_C=1818 \) K, \( T_D=791 \) K), the efficiency of the cycle is close to
(a) 39%
(b) 75%
(c) 50%
(d) 61%
Show Answer & Explanation

Answer: (d) 61%

Explanation:
1. Heat absorbed in BC: \( Q_1=C_p(T_C-T_B)=\tfrac72R(909)=3181R \). Heat rejected in DA: \( Q_2=C_V(T_D-T_A)=\tfrac52R(491)=1228R \).
2. \( \eta=1-\dfrac{Q_2}{Q_1}=1-\dfrac{1228}{3181}\approx0.61 \).

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 13: At 27 \(^\circ\)C two moles of an ideal monoatomic gas occupy a volume V. The gas expands adiabatically to a volume 2V. The work done by the gas during this process is close to (R = 8.31 J/mol-K)
(a) 2.77 kJ
(b) 1.38 kJ
(c) 5.5 kJ
(d) 0.77 kJ
Show Answer & Explanation

Answer: (a) 2.77 kJ

Explanation:
1. \( T_2=300\left(\dfrac12\right)^{2/3}\approx189 \) K.
2. \( W=-\Delta U=nC_V(T_1-T_2)=2(1.5)(8.31)(111)\approx2.77 \) kJ.

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 14: For the same cyclic process (heat in the four steps 5960 J, -5585 J, -2980 J and 3645 J; net work 1040 J), the efficiency of the cycle is close to
(a) 5.4%
(b) 21.6%
(c) 10.8%
(d) 35%
Show Answer & Explanation

Answer: (c) 10.8%

Explanation:
1. Heat absorbed \( =5960+3645=9605 \) J; net work \( =1040 \) J.
2. \( \eta=\dfrac{1040}{9605}\approx10.8\% \).

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 15: One mole of a monoatomic ideal gas is taken through the cycle: \( A\to B \) adiabatic expansion; \( B\to C \) cooling at constant volume; \( C\to D \) adiabatic compression; \( D\to A \) heating at constant volume. The pressure and temperature at A, B etc. are denoted by \( p_A \), \( T_A \), \( p_B \), \( T_B \) etc. Given that \( T_A=1000 \) K, \( p_B=\tfrac23p_A \) and \( p_C=\tfrac13p_A \), the work done by the gas in the process \( A\to B \) is close to (R = 8.31 J/mol-K, \( (2/3)^{2/5}=0.85 \))
(a) 0.93 kJ
(b) 3.7 kJ
(c) 1.25 kJ
(d) 1.87 kJ
Show Answer & Explanation

Answer: (d) 1.87 kJ

Explanation:
1. Adiabatic: \( p^{1-\gamma}T^{\gamma}= \) const gives \( \dfrac{T_B}{T_A}=\left(\dfrac{p_B}{p_A}\right)^{(\gamma-1)/\gamma}=\left(\dfrac23\right)^{2/5}=0.85 \), so \( T_B=850 \) K.
2. \( W_{AB}=nC_V(T_A-T_B)=1.5\times8.31\times150\approx1870 \) J.

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 16: For the same cycle (monoatomic gas; AB adiabatic, BC cooling at constant volume, CD adiabatic, DA heating at constant volume; \( T_A=1000 \) K, \( p_B=\tfrac23p_A \), \( p_C=\tfrac13p_A \), \( T_B=850 \) K), the heat lost by the gas in the process \( B\to C \) is close to (R = 8.31 J/mol-K)
(a) 5.3 kJ
(b) 2.6 kJ
(c) 10.6 kJ
(d) 1.9 kJ
Show Answer & Explanation

Answer: (a) 5.3 kJ

Explanation:
1. BC is at constant volume: \( \dfrac{T_C}{T_B}=\dfrac{p_C}{p_B}=\dfrac12\Rightarrow T_C=425 \) K.
2. \( Q=nC_V(T_B-T_C)=1.5\times8.31\times425\approx5.3 \) kJ lost.

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 17: Two moles of helium gas undergo a cyclic process ABCDA on a p-T diagram: A at \( (300\ \text{K},\,2\ \text{atm}) \), B at \( (400\ \text{K},\,2\ \text{atm}) \), C at \( (400\ \text{K},\,1\ \text{atm}) \), D at \( (300\ \text{K},\,1\ \text{atm}) \) (AB and CD isobaric, BC and DA isothermal). Assuming the gas to be ideal, the net work done in the cycle is close to (R = 8.31 J/mol-K)
(a) 576 J
(b) 2300 J
(c) 1152 J
(d) 0 J
Show Answer & Explanation

Answer: (c) 1152 J

Explanation:
1. Work: AB \( =nR(100)=200R \); BC (isothermal, volume doubles) \( =nR(400)\ln2=800R\ln2 \); CD \( =-200R \); DA \( =nR(300)\ln\dfrac12=-600R\ln2 \).
2. Net \( W=200R\ln2=200\times8.31\times0.693\approx1152 \) J (equal to the net heat, and \( \Delta U=0 \)).

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 18: Three moles of an ideal gas (\( C_p=\tfrac72R \)) at pressure \( p_A \) and temperature \( T_A \) is isothermally expanded to twice its initial volume. It is then compressed at constant pressure to its original volume. Finally the gas is compressed at constant volume to its original pressure \( p_A \). The net work done by the gas in the complete process (and the net heat supplied) is
(a) \( 3RT_A\ln2 \)
(b) \( 3RT_A\left(\ln2+\dfrac12\right) \)
(c) \( -3RT_A\left(\ln2-\dfrac12\right) \)
(d) \( 3RT_A\left(\ln2-\dfrac12\right) \)
Show Answer & Explanation

Answer: (d) \( 3RT_A\left(\ln2-\dfrac12\right) \)

Explanation:
1. Isothermal expansion: \( W_1=3RT_A\ln2 \). Isobaric compression at pressure \( \dfrac{p_A}{2} \) from 2V to V: \( W_2=-\dfrac{p_A}{2}V_A=-\dfrac{3RT_A}2 \). Isochoric step: \( W_3=0 \).
2. Net work \( =3RT_A\ln2-\dfrac32RT_A \). Since \( \Delta U=0 \) over a cycle, the net heat supplied equals this.

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 19: An ideal gas having initial pressure p, volume V and temperature T is allowed to expand adiabatically until its volume becomes 5.66V while its temperature falls to T/2. The number of degrees of freedom of the gas molecules is
(a) 5
(b) 3
(c) 6
(d) 7
Show Answer & Explanation

Answer: (a) 5

Explanation:
1. \( TV^{\gamma-1}= \) const: \( 5.66^{\gamma-1}=2 \). Since \( 5.66=4\sqrt2=2^{5/2} \), \( \tfrac52(\gamma-1)=1\Rightarrow\gamma=1.4 \).
2. \( \gamma=1+\dfrac2f=1.4\Rightarrow f=5 \).

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 20: An ideal gas has a specific heat at constant pressure \( C_p=\dfrac{5R}2 \). The gas is kept in a closed vessel of volume 0.0083 m\(^3\), at a temperature of 300 K and a pressure of \( 1.6\times10^6 \) N/m\(^2\). An amount of \( 2.49\times10^4 \) J of heat energy is supplied to the gas. The final temperature and pressure of the gas are (R = 8.3 J/mol-K)
(a) 600 K and \( 3.2\times10^6 \) N/m\(^2\)
(b) 675 K and \( 1.6\times10^6 \) N/m\(^2\)
(c) 675 K and \( 3.6\times10^6 \) N/m\(^2\)
(d) 750 K and \( 4.0\times10^6 \) N/m\(^2\)
Show Answer & Explanation

Answer: (c) 675 K and \( 3.6\times10^6 \) N/m\(^2\)

Explanation:
1. \( n=\dfrac{pV}{RT}=\dfrac{1.6\times10^6\times0.0083}{8.3\times300}=5.33 \) mol. \( C_p=\tfrac52R \) means a monoatomic gas, so \( C_V=\tfrac32R \).
2. Closed vessel: \( Q=nC_V\Delta T\Rightarrow\Delta T=\dfrac{2.49\times10^4}{5.33\times12.45}=375 \) K, so \( T=675 \) K and \( p'=p\dfrac{675}{300}=3.6\times10^6 \) N/m\(^2\).

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 21: Calculate the work done when one mole of a perfect gas is compressed adiabatically. The initial pressure and volume of the gas are \( 10^5 \) N/m\(^2\) and 6 L respectively. The final volume of the gas is 2 L. The molar specific heat of the gas at constant volume is 3R/2. The work done on the gas is close to
(a) 600 J
(b) 1248 J
(c) 648 J
(d) 972 J
Show Answer & Explanation

Answer: (d) 972 J

Explanation:
1. \( C_V=\tfrac32R\Rightarrow\gamma=\tfrac53 \). \( p_2=10^5\left(\dfrac62\right)^{5/3}=6.24\times10^5 \) N/m\(^2\).
2. Work done on the gas \( =\dfrac{p_2V_2-p_1V_1}{\gamma-1}=\dfrac{1248-600}{2/3}\approx972 \) J.

Teacher's Note:
1. First write the first law, Q = delta U + W, and recall that delta U depends only on the temperature change (n Cv delta T) for an ideal gas, whatever the path.
2. Work is the area under the p-V curve (positive for expansion); for a cycle the net work equals the net heat absorbed.

Question 22: If \( 10^{22} \) gas molecules each of mass \( 10^{-26} \) kg collide with a surface (perpendicular to it) elastically per second per area 1 m\(^2\) with a speed \( 10^4 \) m/s, the pressure exerted by the gas molecules will be of the order of
(a) \( 10^4 \) N/m\(^2\)
(b) 1 N/m\(^2\)
(c) \( 10^8 \) N/m\(^2\)
(d) \( 10^3 \) N/m\(^2\)
Show Answer & Explanation

Answer: (b) 1 N/m\(^2\)

Explanation:
1. Each elastic collision reverses the momentum: change \( =2mv=2\times10^{-26}\times10^4=2\times10^{-22} \) kg m/s.
2. Force on 1 m\(^2\) \( =10^{22}\times2\times10^{-22}=2 \) N, so the pressure is 2 N/m\(^2\), of the order of 1 N/m\(^2\).

Teacher's Note:
1. Break the problem into the simplest physical law that applies (kinetic theory, linear scale of a thermometer, conduction or radiation) and write it before substituting numbers.
2. Check orders of magnitude and units at the end; most mistakes in these problems come from a missing factor of 2 or of 4 pi.

Question 23: A thermometer graduated according to a linear scale reads a value \( x_0 \) when in contact with boiling water, and \( x_0/3 \) when in contact with ice. What is the temperature of an object in \(^\circ\)C, if this thermometer reads \( x_0/2 \) in the contact with the object?
(a) 35
(b) 60
(c) 25
(d) 40
Show Answer & Explanation

Answer: (c) 25

Explanation:
1. Linear scale: \( \dfrac{x-x_0/3}{x_0-x_0/3}=\dfrac{T-0}{100-0} \).
2. \( \dfrac{x_0/2-x_0/3}{2x_0/3}=\dfrac14=\dfrac T{100}\Rightarrow T=25^\circ \)C.

Teacher's Note:
1. Break the problem into the simplest physical law that applies (kinetic theory, linear scale of a thermometer, conduction or radiation) and write it before substituting numbers.
2. Check orders of magnitude and units at the end; most mistakes in these problems come from a missing factor of 2 or of 4 pi.

Question 24: A heat source at \( T=10^3 \) K is connected to another heat reservoir at \( T=10^2 \) K by a copper slab which is 1 m thick. Given that the thermal conductivity of copper is 0.1 W K\(^{-1}\)m\(^{-1}\), the energy flux through it in the steady state is
(a) 65 W m\(^{-2}\)
(b) 120 W m\(^{-2}\)
(c) 200 W m\(^{-2}\)
(d) 90 W m\(^{-2}\)
Show Answer & Explanation

Answer: (d) 90 W m\(^{-2}\)

Explanation:
1. Energy flux \( =K\dfrac{\Delta T}{L} \).
2. \( =0.1\times\dfrac{1000-100}{1}=90 \) W m\(^{-2}\).

Teacher's Note:
1. Break the problem into the simplest physical law that applies (kinetic theory, linear scale of a thermometer, conduction or radiation) and write it before substituting numbers.
2. Check orders of magnitude and units at the end; most mistakes in these problems come from a missing factor of 2 or of 4 pi.

Question 25: Consider an ideal gas confined in an isolated closed chamber. As the gas undergoes an adiabatic expansion, the average time of collision between molecules increases as \( V^q \), where V is the volume of the gas. The value of q is \( \left(\gamma=\dfrac{C_p}{C_V}\right) \)
(a) \( \dfrac{3\gamma+5}{6} \)
(b) \( \dfrac{\gamma+1}{2} \)
(c) \( \dfrac{3\gamma-5}{6} \)
(d) \( \dfrac{\gamma-1}{2} \)
Show Answer & Explanation

Answer: (b) \( \dfrac{\gamma+1}{2} \)

Explanation:
1. Mean time \( \tau=\dfrac\lambda{v_{rms}} \) with \( \lambda\propto V \) (fixed number of molecules) and \( v_{rms}\propto\sqrt T \).
2. Adiabatic: \( T\propto V^{1-\gamma} \), so \( v_{rms}\propto V^{(1-\gamma)/2} \) and \( \tau\propto V^{1-(1-\gamma)/2}=V^{(\gamma+1)/2} \).

Teacher's Note:
1. Break the problem into the simplest physical law that applies (kinetic theory, linear scale of a thermometer, conduction or radiation) and write it before substituting numbers.
2. Check orders of magnitude and units at the end; most mistakes in these problems come from a missing factor of 2 or of 4 pi.

Question 26: A solid body of constant heat capacity 1 J/K is being heated by keeping it in contact with reservoirs in two ways: (i) sequentially keeping in contact with 2 reservoirs such that each reservoir supplies the same amount of heat; (ii) sequentially keeping in contact with 8 reservoirs such that each reservoir supplies the same amount of heat. In both cases the body is brought from the initial temperature 100 K to the final temperature 200 K. The entropy change of the body in the two cases respectively is
(a) \( \ln2,\ 2\ln2 \)
(b) \( 2\ln2,\ 8\ln2 \)
(c) \( \ln2,\ \ln2 \)
(d) \( \ln2,\ 4\ln2 \)
Show Answer & Explanation

Answer: (c) \( \ln2,\ \ln2 \)

Explanation:
1. Entropy is a state function: the change in the body depends only on the initial and final temperatures, not on the number of reservoirs used.
2. \( \Delta S=\int_{100}^{200}\dfrac{C\,dT}{T}=1\times\ln\dfrac{200}{100}=\ln2 \) in both cases.

Teacher's Note:
1. Break the problem into the simplest physical law that applies (kinetic theory, linear scale of a thermometer, conduction or radiation) and write it before substituting numbers.
2. Check orders of magnitude and units at the end; most mistakes in these problems come from a missing factor of 2 or of 4 pi.

Question 27: An ideal gas enclosed in a vertical cylindrical container supports a freely moving piston of mass M. The piston and the cylinder have equal cross-sectional area A. When the piston is in equilibrium, the volume of the gas is \( V_0 \) and its pressure is \( p_0 \). The piston is slightly displaced from the equilibrium position and released. Assuming that the system is completely isolated from its surroundings, the piston executes a simple harmonic motion with frequency
(a) \( \dfrac1{2\pi}\dfrac{A\gamma p_0}{V_0M} \)
(b) \( \dfrac1{2\pi}\dfrac{V_0Mp_0}{A^2\gamma} \)
(c) \( \dfrac1{2\pi}\sqrt{\dfrac{MV_0}{A\gamma p_0}} \)
(d) \( \dfrac1{2\pi}\sqrt{\dfrac{A^2\gamma p_0}{MV_0}} \)
Show Answer & Explanation

Answer: (d) \( \dfrac1{2\pi}\sqrt{\dfrac{A^2\gamma p_0}{MV_0}} \)

Explanation:
1. Isolated gas, so the change is adiabatic: \( pV^\gamma= \) const gives \( dp=-\gamma\dfrac{p_0}{V_0}dV \) with \( dV=A\,x \).
2. Restoring force \( F=-A\,dp=-\dfrac{\gamma p_0A^2}{V_0}x \), so \( \omega=\sqrt{\dfrac{\gamma p_0A^2}{MV_0}} \) and \( f=\dfrac{1}{2\pi}\sqrt{\dfrac{A^2\gamma p_0}{MV_0}} \).

Teacher's Note:
1. Break the problem into the simplest physical law that applies (kinetic theory, linear scale of a thermometer, conduction or radiation) and write it before substituting numbers.
2. Check orders of magnitude and units at the end; most mistakes in these problems come from a missing factor of 2 or of 4 pi.

Question 28: An ideal gas is expanding such that \( pT^2= \) constant. The coefficient of volume expansion of the gas is
(a) \( \dfrac1T \)
(b) \( \dfrac3T \)
(c) \( \dfrac2T \)
(d) \( \dfrac4T \)
Show Answer & Explanation

Answer: (b) \( \dfrac3T \)

Explanation:
1. \( p=\dfrac{c}{T^2} \) and \( V=\dfrac{nRT}{p}=\dfrac{nRT^3}{c}\propto T^3 \).
2. \( \gamma_V=\dfrac1V\dfrac{dV}{dT}=\dfrac3T \).

Teacher's Note:
1. Break the problem into the simplest physical law that applies (kinetic theory, linear scale of a thermometer, conduction or radiation) and write it before substituting numbers.
2. Check orders of magnitude and units at the end; most mistakes in these problems come from a missing factor of 2 or of 4 pi.

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