JEE Physics Thermodynamics MCQs Set 21

Multiple Choice Questions (MCQs) for JEE Physics: Thermodynamics

Review structured MCQ sets for JEE Physics Thermodynamics. Built according to official JEE guidelines, these downloadable questions support daily revision and core concept reinforcement.

Practice Thermodynamics MCQs for JEE Physics

Access the complete set of multiple-choice questions for Thermodynamics below. This focused format allows students to isolate specific topics for thorough review and uninterrupted practice alongside official JEE textbooks.

Multiple Choice Questions

Question 1: Assertion (A): The efficiency of a reversible engine is maximum.
Reason (R): In such a device no dissipation of energy takes place.
(a) Both Assertion and Reason are true and the Reason is a correct explanation of the Assertion.
(b) Both Assertion and Reason are true but the Reason is not a correct explanation of the Assertion.
(c) Assertion is true but the Reason is false.
(d) Both Assertion and Reason are false.
Show Answer & Explanation

Answer: (a) Both Assertion and Reason are true and the Reason is a correct explanation of the Assertion.

Explanation:
1. A reversible engine has no dissipative losses, so it gives the greatest possible efficiency between two given temperatures.
2. The Reason explains the Assertion.

Teacher's Note:
1. Dissipation (friction, heat leaks) lowers efficiency.
2. A reversible engine has none.

Question 2: Assertion (A): In a cyclic process the initial and final states are the same, therefore the net work done is zero.
Reason (R): The initial and final temperatures are equal, therefore the change in internal energy is zero.
(a) Both Assertion and Reason are true and the Reason is a correct explanation of the Assertion.
(b) Both Assertion and Reason are true but the Reason is not a correct explanation of the Assertion.
(c) Assertion is true but the Reason is false.
(d) Both Assertion and Reason are false.
Show Answer & Explanation

Answer: (d) Both Assertion and Reason are false.

Explanation:
1. In a cyclic process \(\Delta U = 0\), so the Reason is true.
2. But the net work equals the net heat absorbed, which is not zero in general (it is the area of the loop): the Assertion is false.

Teacher's Note:
1. Net work in a cycle is the loop area.
2. Only the change in internal energy vanishes.

Question 3: Assertion (A): The efficiency of a Carnot engine increases on reducing the temperature of the sink.
Reason (R): The efficiency of a Carnot engine is the ratio of net mechanical work done per cycle by the gas to the amount of heat energy absorbed per cycle from the source.
(a) Both Assertion and Reason are true and the Reason is a correct explanation of the Assertion.
(b) Both Assertion and Reason are true but the Reason is not a correct explanation of the Assertion.
(c) Assertion is true but the Reason is false.
(d) Both Assertion and Reason are false.
Show Answer & Explanation

Answer: (b) Both Assertion and Reason are true but the Reason is not a correct explanation of the Assertion.

Explanation:
1. \(\eta = 1 - \frac{T_2}{T_1}\) increases when \(T_2\) falls: the Assertion is true.
2. The Reason is the definition of efficiency and is true, but it does not by itself explain the temperature dependence.

Teacher's Note:
1. The definition does not mention temperature.
2. The temperature dependence comes from \(\eta = 1 - T_2/T_1\).

Question 4: Assertion (A): The Carnot cycle is useful in understanding the performance of heat engines.
Reason (R): The Carnot cycle provides a way of determining the maximum possible efficiency achievable with reservoirs of given temperatures.
(a) Both Assertion and Reason are true and the Reason is a correct explanation of the Assertion.
(b) Both Assertion and Reason are true but the Reason is not a correct explanation of the Assertion.
(c) Assertion is true but the Reason is false.
(d) Both Assertion and Reason are false.
Show Answer & Explanation

Answer: (a) Both Assertion and Reason are true and the Reason is a correct explanation of the Assertion.

Explanation:
1. The Carnot efficiency is an upper limit that any engine can be compared with.
2. So the Reason explains the Assertion.

Teacher's Note:
1. Carnot efficiency is the benchmark.
2. Real engines are always below it.

Question 5: When the state of a gas is adiabatically changed from an equilibrium state A to another equilibrium state B, an amount of work of 35 J is done on the system. If the gas is taken from state A to B by a process in which the net heat absorbed by the system is 12 cal, then the net work done by the system is (1 cal = 4.2 J)
(a) 13.2 J
(b) 15.4 J
(c) 12.6 J
(d) 16.8 J
Show Answer & Explanation

Answer: (b) 15.4 J

Explanation:
1. Adiabatic A to B: \(Q = 0\), work done on the system is 35 J, so \(\Delta U = +35\ \text{J}\).
2. Other path: \(Q = 12\times4.2 = 50.4\ \text{J}\).
3. \(W = Q - \Delta U = 50.4 - 35 = 15.4\ \text{J}\).

Teacher's Note:
1. Internal energy change is path independent.
2. Convert calories to joules before using the first law.

Question 6: The internal energy change in a system that has absorbed 2 kcal of heat and done 500 J of work is (1 cal = 4.2 J)
(a) 6400 J
(b) 5400 J
(c) 7900 J
(d) 8900 J
Show Answer & Explanation

Answer: (c) 7900 J

Explanation:
1. \(Q = 2000\times4.2 = 8400\ \text{J}\).
2. \(\Delta U = Q - W = 8400 - 500 = 7900\ \text{J}\).

Teacher's Note:
1. Work done by the system is subtracted from the heat absorbed.
2. Convert kcal to joules first.

Question 7: The specific heat at constant pressure of an ideal gas is \(C_p = \frac{5R}{2}\) per mole. The gas is kept in a closed vessel of volume \(0.0083\ \text{m}^3\) at 300 K and a pressure of \(1.6\times10^{6}\ \text{N/m}^2\). \(2.49\times10^{4}\ \text{J}\) of heat is supplied to the gas. The final temperature and pressure respectively are
(a) 567.2 K and \(6.3\times10^{6}\ \text{N/m}^2\)
(b) 675.2 K and \(3.6\times10^{6}\ \text{N/m}^2\)
(c) 275.2 K and \(2.3\times10^{6}\ \text{N/m}^2\)
(d) 465.6 K and \(4.2\times10^{6}\ \text{N/m}^2\)
Show Answer & Explanation

Answer: (b) 675.2 K and \(3.6\times10^{6}\ \text{N/m}^2\)

Explanation:
1. \(n = \frac{PV}{RT} = \frac{1.6\times10^6\times0.0083}{8.3\times300} = 5.33\ \text{mol}\).
2. Closed vessel means constant volume, \(C_V = C_P - R = \frac{3R}{2}\).
3. \(Q = nC_V\Delta T\) gives \(\Delta T = \frac{2.49\times10^4}{5.33\times1.5\times8.3} \approx 375\ \text{K}\), so \(T = 675\ \text{K}\).
4. \(P = 1.6\times10^6\times\frac{675}{300} = 3.6\times10^6\ \text{N/m}^2\).

Teacher's Note:
1. In a closed rigid vessel use \(C_V\), not \(C_P\).
2. Pressure scales with absolute temperature at constant volume.

Question 8: The amount of heat supplied to \(4\times10^{-2}\ \text{kg}\) of nitrogen at room temperature to raise its temperature by 50 C at constant pressure is (molecular mass of nitrogen = 28, \(R = 8.3\ \text{J mol}^{-1}\text{K}^{-1}\))
(a) 2.08 kJ
(b) 3.08 kJ
(c) 4.08 kJ
(d) 5.08 kJ
Show Answer & Explanation

Answer: (a) 2.08 kJ

Explanation:
1. \(n = \frac{40}{28} = 1.43\ \text{mol}\).
2. Nitrogen is diatomic: \(C_P = \frac{7}{2}R\).
3. \(Q = nC_P\Delta T = 1.43\times3.5\times8.3\times50 \approx 2075\ \text{J} \approx 2.08\ \text{kJ}\).

Teacher's Note:
1. Use \(C_P\) for constant pressure heating.
2. Nitrogen is diatomic, so \(C_P = 7R/2\).

Question 9: When 1 kg of ice at 0 C melts to water at 0 C, the change in its entropy, taking the latent heat of ice as 80 cal/g, is
(a) 273 cal/K
(b) \(8\times10^{4}\) cal/K
(c) 80 cal/K
(d) 293 cal/K
Show Answer & Explanation

Answer: (d) 293 cal/K

Explanation:
1. \(Q = mL = 1000\times80 = 8\times10^4\ \text{cal}\).
2. \(\Delta S = \frac{Q}{T} = \frac{8\times10^4}{273} \approx 293\ \text{cal/K}\).

Teacher's Note:
1. Latent heat per gram must be multiplied by the mass in grams.
2. Use absolute temperature.

Question 10: A mass of diatomic gas (\(\gamma = 1.4\)) at a pressure of 2 atmospheres is compressed adiabatically so that its temperature rises from 27 C to 927 C. The pressure of the gas in the final state is
(a) 28 atm
(b) 68.7 atm
(c) 256 atm
(d) 8 atm
Show Answer & Explanation

Answer: (c) 256 atm

Explanation:
1. \(T_1 = 300\ \text{K}\), \(T_2 = 1200\ \text{K}\).
2. Adiabatic: \(P \propto T^{\gamma/(\gamma-1)} = T^{3.5}\).
3. \(P_2 = 2\times4^{3.5} = 2\times128 = 256\ \text{atm}\).

Teacher's Note:
1. Use the form of the adiabatic law that links \(P\) and \(T\).
2. \(\frac{\gamma}{\gamma-1} = 3.5\) for a diatomic gas.

Question 11: A diatomic gas initially at 18 C is compressed adiabatically to one-eighth of its original volume. The temperature after compression will be
(a) 18 C
(b) 668.4 K
(c) 395.4 C
(d) 144 C
Show Answer & Explanation

Answer: (b) 668.4 K

Explanation:
1. \(T_1 = 291\ \text{K}\), \(\gamma = 1.4\).
2. \(T_2 = T_1\left(\frac{V_1}{V_2}\right)^{\gamma-1} = 291\times8^{0.4} = 291\times2.297 \approx 668.4\ \text{K}\).

Teacher's Note:
1. Convert Celsius to kelvin before using the adiabatic law.
2. \(8^{0.4} = 2^{1.2}\).

Question 12: What will be the final pressure if an ideal gas in a cylinder is compressed adiabatically to one-third of its volume?
(a) Final pressure will be three times less than the initial pressure
(b) Final pressure will be three times more than the initial pressure
(c) Change in pressure will be more than three times the initial pressure
(d) Change in pressure will be less than three times the initial pressure
Show Answer & Explanation

Answer: (c) Change in pressure will be more than three times the initial pressure

Explanation:
1. \(P_2 = P_1\left(\frac{V_1}{V_2}\right)^{\gamma} = 3^{\gamma}P_1\).
2. For \(\gamma \geq 1.4\), \(3^{\gamma} \geq 4.66\), so the change \(P_2 - P_1 = (3^\gamma - 1)P_1 > 3P_1\).

Teacher's Note:
1. In an adiabatic compression the pressure rises more than in an isothermal one.
2. Isothermal compression would give exactly three times.

Question 13: In a heat engine the temperatures of the source and sink are 500 K and 375 K. If the engine consumes \(25\times10^{5}\ \text{J}\) per cycle, the work done per cycle is
(a) \(6.25\times10^{5}\ \text{J}\)
(b) \(3\times10^{5}\ \text{J}\)
(c) \(2.19\times10^{5}\ \text{J}\)
(d) \(4\times10^{4}\ \text{J}\)
Show Answer & Explanation

Answer: (a) \(6.25\times10^{5}\ \text{J}\)

Explanation:
1. Assume a Carnot engine: \(\eta = 1 - \frac{375}{500} = 0.25\).
2. \(W = \eta Q = 0.25\times25\times10^5 = 6.25\times10^5\ \text{J}\).

Teacher's Note:
1. Heat consumed is the heat absorbed from the source.
2. Work = efficiency times heat absorbed.

Question 14: A refrigerator with coefficient of performance \(\frac{1}{3}\) releases 200 J of heat to a hot reservoir. The work done on the working substance is
(a) \(\frac{100}{3}\ \text{J}\)
(b) 100 J
(c) \(\frac{200}{3}\ \text{J}\)
(d) 150 J
Show Answer & Explanation

Answer: (d) 150 J

Explanation:
1. \(\beta = \frac{Q_2}{W} = \frac{1}{3}\) gives \(Q_2 = \frac{W}{3}\).
2. Heat released is \(Q_1 = Q_2 + W = \frac{4W}{3} = 200\ \text{J}\).
3. So \(W = 150\ \text{J}\).

Teacher's Note:
1. Heat released to the hot reservoir includes the work supplied.
2. \(Q_1 = Q_2 + W\).

Question 15: If the coefficient of performance of a refrigerator is 5 and it operates at a room temperature of 27 C, the temperature inside the refrigerator is
(a) 240 K
(b) 250 K
(c) 230 K
(d) 260 K
Show Answer & Explanation

Answer: (b) 250 K

Explanation:
1. \(\beta = \frac{T_2}{T_1 - T_2} = 5\) with \(T_1 = 300\ \text{K}\).
2. \(T_2 = 5(300 - T_2)\), so \(6T_2 = 1500\) and \(T_2 = 250\ \text{K}\).

Teacher's Note:
1. Take room temperature as the hot reservoir.
2. Solve the linear equation in \(T_2\).

Question 16: By running a refrigerator with its door open in a room
(a) the temperature of the room will reduce a little
(b) the room can be cooled considerably but this will take a long time
(c) the room will get a little hotter
(d) None of these
Show Answer & Explanation

Answer: (c) the room will get a little hotter

Explanation:
1. The refrigerator rejects heat \(Q_1 = Q_2 + W\) to the room, which is more than the heat \(Q_2\) it removes from the room.
2. So the room gets a little hotter.

Teacher's Note:
1. The work supplied by the compressor ends up as heat in the room.
2. A refrigerator cannot cool a closed room.

Question 17: A monatomic gas at pressure \(P\) and volume \(V\) expands isothermally to a volume \(2V\) and then adiabatically to a volume \(16V\). The final pressure of the gas is (take \(\gamma = \frac{5}{3}\))
(a) 64P
(b) 32P
(c) \(\frac{P}{64}\)
(d) 16P
Show Answer & Explanation

Answer: (c) \(\frac{P}{64}\)

Explanation:
1. Isothermal: \(P_1 = \frac{P}{2}\) at volume \(2V\).
2. Adiabatic from \(2V\) to \(16V\): ratio 8, so \(P_2 = \frac{P}{2}\times8^{-5/3} = \frac{P}{2}\times\frac{1}{32} = \frac{P}{64}\).

Teacher's Note:
1. Apply the isothermal law first and then the adiabatic law.
2. \(8^{5/3} = 2^5 = 32\).

Question 18: A spring stores 1 J of energy for a compression of 1 mm. The additional work to be done to compress it further by 1 mm is
(a) 1 J
(b) 2 J
(c) 3 J
(d) 4 J
Show Answer & Explanation

Answer: (c) 3 J

Explanation:
1. Stored energy is \(\frac{1}{2}kx^2 \propto x^2\).
2. At 1 mm: 1 J. At 2 mm: 4 J.
3. Additional work \(= 4 - 1 = 3\ \text{J}\).

Teacher's Note:
1. Energy grows with the square of the compression.
2. Subtract the energy already stored.

Question 19: The change in internal energy of a thermodynamic system which has absorbed 2 kcal of heat and done 400 J of work is (1 cal = 4.2 J)
(a) 2 kJ
(b) 8 kJ
(c) 3.5 kJ
(d) 5.5 kJ
Show Answer & Explanation

Answer: (b) 8 kJ

Explanation:
1. \(Q = 2000\times4.2 = 8400\ \text{J}\).
2. \(\Delta U = Q - W = 8400 - 400 = 8000\ \text{J} = 8\ \text{kJ}\).

Teacher's Note:
1. Convert kcal to J before subtracting.
2. Work done by the system is subtracted.

Question 20: If the internal energy of a box is \(U\) and the box is moving with some velocity, then which of the following is not to be included in \(U\)?
(a) Kinetic energy of the box
(b) Translational kinetic energy of molecules of the gas
(c) Rotational kinetic energy of molecules of the gas
(d) Vibrational kinetic energy of the molecules of the gas
Show Answer & Explanation

Answer: (a) Kinetic energy of the box

Explanation:
1. Internal energy is the energy of the molecular motions and interactions in the frame of the gas.
2. The bulk kinetic energy of the moving box is mechanical energy and is not included.

Teacher's Note:
1. Internal energy is measured relative to the centre of mass.
2. Bulk motion is excluded.

Question 21: If the temperatures of the source and sink of a Carnot engine having efficiency \(\eta\) are each decreased by 100 K, then the efficiency
(a) remains constant
(b) becomes 1
(c) decreases
(d) increases
Show Answer & Explanation

Answer: (d) increases

Explanation:
1. \(\eta = \frac{T_1 - T_2}{T_1}\).
2. After the change \(\eta' = \frac{T_1 - T_2}{T_1 - 100}\) has the same numerator and a smaller denominator.
3. So the efficiency increases.

Teacher's Note:
1. The difference stays the same while the source temperature falls.
2. Hence the ratio increases.

Question 22: A diatomic ideal gas is used in a car engine as the working substance. During the adiabatic expansion part of the cycle, the volume of the gas increases from \(V\) to \(32V\). The efficiency of the engine is
(a) 0.5
(b) 0.75
(c) 0.99
(d) 0.25
Show Answer & Explanation

Answer: (b) 0.75

Explanation:
1. \(TV^{\gamma-1}\) is constant with \(\gamma = 1.4\): \(\frac{T_2}{T_1} = \left(\frac{1}{32}\right)^{0.4} = 2^{-2} = \frac{1}{4}\).
2. Efficiency of the cycle \(\eta = 1 - \frac{T_2}{T_1} = 1 - \frac{1}{4} = 0.75\).

Teacher's Note:
1. \(32^{0.4} = 2^{2} = 4\).
2. Efficiency of an Otto-type cycle depends on the expansion ratio.

Question 23: A Carnot engine operating between temperatures \(T_1\) and \(T_2\) has efficiency \(\frac{1}{6}\). When \(T_2\) is lowered by 62 K its efficiency increases to \(\frac{1}{3}\). Then \(T_1\) and \(T_2\) are respectively
(a) 372 K and 330 K
(b) 330 K and 268 K
(c) 310 K and 248 K
(d) 372 K and 310 K
Show Answer & Explanation

Answer: (d) 372 K and 310 K

Explanation:
1. \(\frac{T_2}{T_1} = \frac{5}{6}\) and \(\frac{T_2 - 62}{T_1} = \frac{2}{3}\).
2. Subtracting: \(\frac{62}{T_1} = \frac{1}{6}\), so \(T_1 = 372\ \text{K}\).
3. \(T_2 = \frac{5}{6}\times372 = 310\ \text{K}\).

Teacher's Note:
1. Write both efficiencies as temperature ratios.
2. Subtract to eliminate \(T_2\).

Question 24: In a Carnot engine the temperature of the reservoir is 927 C and that of the sink is 27 C. If the work done by the engine when it transfers heat from reservoir to sink is \(12.6\times10^{6}\ \text{J}\), the quantity of heat absorbed by the engine from the reservoir is
(a) \(16.8\times10^{6}\ \text{J}\)
(b) \(4\times10^{6}\ \text{J}\)
(c) \(7.6\times10^{6}\ \text{J}\)
(d) \(4.2\times10^{6}\ \text{J}\)
Show Answer & Explanation

Answer: (a) \(16.8\times10^{6}\ \text{J}\)

Explanation:
1. \(\eta = 1 - \frac{300}{1200} = 0.75\).
2. \(Q_1 = \frac{W}{\eta} = \frac{12.6\times10^6}{0.75} = 16.8\times10^6\ \text{J}\).

Teacher's Note:
1. Efficiency links work output with heat absorbed.
2. Convert Celsius to kelvin.

Question 25: A Carnot engine operating between temperatures \(T_1\) and \(T_2\) has efficiency 0.2. When \(T_2\) is reduced by 50 K, its efficiency increases to 0.4. Then \(T_1\) and \(T_2\) are respectively
(a) 200 K, 150 K
(b) 250 K, 200 K
(c) 300 K, 250 K
(d) 300 K, 200 K
Show Answer & Explanation

Answer: (b) 250 K, 200 K

Explanation:
1. \(T_2 = 0.8T_1\) and \(T_2 - 50 = 0.6T_1\).
2. Subtracting: \(50 = 0.2T_1\), so \(T_1 = 250\ \text{K}\).
3. \(T_2 = 200\ \text{K}\).

Teacher's Note:
1. Write efficiency as \(1 - T_2/T_1\) twice.
2. Subtract the two equations.

Question 26: If the energy input to a Carnot engine is thrice the work it performs, then the fraction of the energy rejected to the sink is
(a) \(\frac{1}{3}\)
(b) \(\frac{1}{4}\)
(c) \(\frac{2}{5}\)
(d) \(\frac{2}{3}\)
Show Answer & Explanation

Answer: (d) \(\frac{2}{3}\)

Explanation:
1. \(Q_1 = 3W\), so \(Q_2 = Q_1 - W = 2W\).
2. Fraction rejected \(= \frac{Q_2}{Q_1} = \frac{2}{3}\).

Teacher's Note:
1. Energy in equals work plus energy rejected.
2. The fraction is taken with respect to input.

Multiple Choice Questions (MCQs) for JEE Physics Thermodynamics

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