JEE Physics Thermodynamics MCQs Set 04

Physics Objective Questions and Answers: Thermodynamics

Explore reliable objective questions for Thermodynamics tailored for JEE learners. Utilizing these Physics multiple-choice formats ensures thorough preparation and strengthens problem-solving speed for upcoming school assessments.

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Multiple Choice Questions

Question 1: The first law of thermodynamics is based on
(a) none of the above
(b) the law of conservation of mechanical energy
(c) the law of conservation of gravitational potential energy
(d) the law of conservation of energy
Show Answer & Explanation

Answer: (d) the law of conservation of energy

Explanation:
1. The first law, \( Q = \Delta U + W \), states that heat supplied is accounted for by the rise in internal energy and the work done.
2. It is a statement of conservation of total energy, including heat.

Teacher's Note:
1. Mechanical energy alone is not conserved when heat is involved.

Question 2: In a process, 500 calories of heat is given to a system and at the same time 100 joules of work is done on the system. The increase in the internal energy of the system is (1 cal = 4.186 J)
(a) 40 calories
(b) 1993 joules
(c) 2193 joules
(d) 82 calories
Show Answer & Explanation

Answer: (c) 2193 joules

Explanation:
1. Heat absorbed \( Q = 500\times4.186 = 2093 \) J.
2. Work done on the system, so \( W_{by} = -100 \) J.
3. \( \Delta U = Q - W_{by} = 2093 + 100 = 2193 \) J.

Teacher's Note:
1. Work done on the system adds to its internal energy.
2. Convert calories to joules first.

Question 3: In a thermodynamic process, the pressure of a fixed mass of gas is changed in such a manner that the gas releases 20 joules of heat and 8 joules of work is done on the gas. If the initial internal energy of the gas was 30 joules, then the final internal energy will be
(a) 2 J
(b) 42 J
(c) 18 J
(d) 58 J
Show Answer & Explanation

Answer: (c) 18 J

Explanation:
1. Heat released: \( Q = -20 \) J. Work done by the gas: \( W = -8 \) J.
2. \( \Delta U = Q - W = -20 + 8 = -12 \) J.
3. \( U_f = 30 - 12 = 18 \) J.

Teacher's Note:
1. Heat given out has a negative sign.
2. Work done on the gas has a negative sign in Q = ΔU + W.

Question 4: When a system is taken from state a to state b along the path acb, 200 J of heat is absorbed by the system and 80 J of work is done by it. Along another path adb the system absorbs 144 J of heat. The work done by the system along the path adb is
(a) 6 J
(b) 12 J
(c) 18 J
(d) 24 J
Show Answer & Explanation

Answer: (d) 24 J

Explanation:
1. Along acb: \( \Delta U = Q - W = 200 - 80 = 120 \) J.
2. Internal energy is a state function, so \( \Delta U = 120 \) J along adb as well.
3. \( W = Q - \Delta U = 144 - 120 = 24 \) J.

Teacher's Note:
1. Change in internal energy depends only on the end states.
2. Use it to find the work on the second path.

Question 5: A system is taken from state a to state b along path acb, absorbing 200 J of heat while doing 80 J of work. Along the curved path ba (return) the work done ON the system is 52 J. The heat absorbed by the system along the path ba is
(a) −140 J
(b) −172 J
(c) 140 J
(d) 172 J
Show Answer & Explanation

Answer: (b) −172 J

Explanation:
1. \( \Delta U_{ab} = 200 - 80 = 120 \) J, so \( \Delta U_{ba} = -120 \) J.
2. Work done by the system on path ba is \( W = -52 \) J.
3. \( Q = \Delta U + W = -120 - 52 = -172 \) J, so 172 J of heat is released.

Teacher's Note:
1. Reversing the path reverses the change in internal energy.

Question 6: A system goes from state a to state b with \( \Delta U_{ab} = 120 \) J (as in the path acb of a previous question). If \( U_a = 40 \) J, the internal energy \( U_b \) of the system is
(a) −50 J
(b) 100 J
(c) −120 J
(d) 160 J
Show Answer & Explanation

Answer: (d) 160 J

Explanation:
1. \( U_b = U_a + \Delta U_{ab} = 40 + 120 = 160 \) J.

Teacher's Note:
1. Internal energy is a state function.

Question 7: 1 kg of a gas does 20 kJ of work and receives 16 kJ of heat when it expands between two states. A second kind of expansion can be found between the same initial and final states which requires a heat input of 9 kJ. The work done by the gas in the second expansion is
(a) 32 kJ
(b) 5 kJ
(c) −4 kJ
(d) 13 kJ
Show Answer & Explanation

Answer: (d) 13 kJ

Explanation:
1. First path: \( \Delta U = Q - W = 16 - 20 = -4 \) kJ.
2. Second path has the same \( \Delta U \): \( W = Q - \Delta U = 9 + 4 = 13 \) kJ.

Teacher's Note:
1. State functions do not depend on the path.
2. Apply the first law to each path separately.

Question 8: A gas is taken from state A to state C along path ABC (an isochoric step AB followed by an isobaric expansion BC) and absorbs 90 J of heat while doing 30 J of work. Along the path ADC (an isobaric expansion AD at lower pressure followed by an isochoric step DC) the work done by the gas is 20 J. The heat absorbed along ADC is
(a) 90 J
(b) 110 J
(c) 80 J
(d) 120 J
Show Answer & Explanation

Answer: (c) 80 J

Explanation:
1. \( \Delta U_{AC} = 90 - 30 = 60 \) J.
2. Along ADC: \( Q = \Delta U + W = 60 + 20 = 80 \) J.

Teacher's Note:
1. Both paths connect the same end states, so ΔU is the same.

Question 9: For a gas \( C_V = 4.96 \) cal/mol K. The increase in the internal energy of 2 mole of the gas when heated from 340 K to 342 K is
(a) 27.80 cal
(b) 19.84 cal
(c) 13.90 cal
(d) 9.92 cal
Show Answer & Explanation

Answer: (b) 19.84 cal

Explanation:
1. \( \Delta U = nC_V\Delta T = 2\times4.96\times2 = 19.84 \) cal.

Teacher's Note:
1. For an ideal gas ΔU = nC_VΔT for any process.

Question 10: When a system changes from one state to another, the work done
(a) depends on the force acting on the system
(b) depends on the nature of the material present in the system
(c) does not depend on the path
(d) depends on the path
Show Answer & Explanation

Answer: (d) depends on the path

Explanation:
1. Work is the area under the P–V curve, which differs for different paths between the same two states.
2. So work is a path function.

Teacher's Note:
1. Internal energy is a state function; heat and work are path functions.

Question 11: If 110 J of heat is added to a gaseous system and the change in internal energy is 40 J, the amount of external work done is
(a) 180 J
(b) 70 J
(c) 110 J
(d) 30 J
Show Answer & Explanation

Answer: (b) 70 J

Explanation:
1. \( W = Q - \Delta U = 110 - 40 = 70 \) J.

Teacher's Note:
1. The remaining heat goes into work.

Question 12: If the amount of heat supplied is Q, the work done is W and the change in internal energy is \( mC_V\,dT \), the relation among them is (\( C_V \) = gram specific heat)
(a) \( mC_VdT = Q + W \)
(b) \( Q = W + mC_VdT \)
(c) \( Q + mC_VdT = W \)
(d) none of these
Show Answer & Explanation

Answer: (b) \( Q = W + mC_VdT \)

Explanation:
1. The first law states that heat supplied equals work done by the system plus the increase in internal energy.
2. \( Q = W + mC_VdT \).

Teacher's Note:
1. W is work done by the gas in this form of the law.

Question 13: A gas is taken around the cycle ABCA in a P–V diagram. The vertices are A (5V₀, 5P₀), B (5V₀, P₀) and C (2V₀, P₀). The path is A to B (volume constant), B to C (pressure constant) and C to A (straight line). The work done by the gas in the closed process is
(a) zero
(b) \( 6P_0V_0 \)
(c) \( 4P_0V_0 \)
(d) \( P_0V_0 \)
Show Answer & Explanation

Answer: (b) \( 6P_0V_0 \)

Explanation:
1. The work equals the area of the triangle.
2. Base \( = 5V_0 - 2V_0 = 3V_0 \), height \( = 5P_0 - P_0 = 4P_0 \).
3. Area \( = \dfrac{1}{2}\times3V_0\times4P_0 = 6P_0V_0 \).
4. The expansion C to A occurs at higher pressure than the compression B to C, so the net work is positive.

Teacher's Note:
1. The loop is traversed so that the expansion is on the upper path, giving positive work.

Question 14: The internal energy of a gas at state i is 10 J. For the path iaf from state i to state f, dQ = 50 J and dW = 20 J. For another path ibf between the same states, dQ = 36 J. The work done dW along ibf is
(a) 4 J
(b) 12 J
(c) 18 J
(d) 6 J
Show Answer & Explanation

Answer: (d) 6 J

Explanation:
1. Along iaf: \( \Delta U = 50 - 20 = 30 \) J.
2. The same \( \Delta U \) applies to ibf: \( W = 36 - 30 = 6 \) J.

Teacher's Note:
1. The initial internal energy value of 10 J is not needed for ΔU.

Question 15: The temperature of 5 moles of a gas held at constant volume was changed from 100°C to 120°C. The change in internal energy was found to be 80 J. The total heat capacity of the gas at constant volume is
(a) 8 J/K
(b) 0.8 J/K
(c) 4.0 J/K
(d) 0.4 J/K
Show Answer & Explanation

Answer: (c) 4.0 J/K

Explanation:
1. At constant volume \( \Delta U = Q = C_V^{total}\Delta T \).
2. \( C_V^{total} = \dfrac{80}{20} = 4 \) J/K.

Teacher's Note:
1. The question asks for total heat capacity, not molar.

Question 16: The adiabatic bulk modulus of a diatomic gas at atmospheric pressure (1.013×10⁵ N/m²) is
(a) 0 N/m²
(b) 1 N/m²
(c) 1.4×10⁴ N/m²
(d) 1.4×10⁵ N/m²
Show Answer & Explanation

Answer: (d) 1.4×10⁵ N/m²

Explanation:
1. Adiabatic bulk modulus \( = \gamma P \).
2. For a diatomic gas \( \gamma = 1.4 \): \( 1.4\times1.013\times10^5 \approx 1.4\times10^5 \) N/m².

Teacher's Note:
1. Isothermal bulk modulus equals P; adiabatic equals γP.

Question 17: A given quantity of an ideal gas is at pressure P and absolute temperature T. The isothermal bulk modulus of the gas is
(a) \( \dfrac{2P}{3} \)
(b) \( P \)
(c) \( \dfrac{3P}{2} \)
(d) \( 2P \)
Show Answer & Explanation

Answer: (b) \( P \)

Explanation:
1. \( B = -V\dfrac{dP}{dV} \).
2. For isothermal change \( PV = c \), so \( \dfrac{dP}{dV} = -\dfrac{P}{V} \) and \( B = P \).

Teacher's Note:
1. The isothermal bulk modulus is simply the pressure.

Question 18: For an adiabatic expansion of a perfect gas, the value of \( \Delta P/P \) is equal to
(a) \( -\sqrt{\gamma}\,\dfrac{\Delta V}{V} \)
(b) \( -\dfrac{\Delta V}{V} \)
(c) \( -\gamma\,\dfrac{\Delta V}{V} \)
(d) \( -\gamma^2\dfrac{\Delta V}{V} \)
Show Answer & Explanation

Answer: (c) \( -\gamma\,\dfrac{\Delta V}{V} \)

Explanation:
1. \( PV^\gamma = \text{constant} \).
2. Differentiating, \( V^\gamma\,dP + \gamma PV^{\gamma-1}dV = 0 \).
3. \( \dfrac{dP}{P} = -\gamma\dfrac{dV}{V} \).

Teacher's Note:
1. For an isothermal change the factor γ is absent.

Question 19: An ideal gas at 27°C is compressed adiabatically to 8/27 of its original volume. If γ = 5/3, the rise in temperature is
(a) 450 K
(b) 375 K
(c) 675 K
(d) 405 K
Show Answer & Explanation

Answer: (b) 375 K

Explanation:
1. \( TV^{\gamma-1} = \text{constant} \).
2. \( T_2 = 300\times\left(\dfrac{27}{8}\right)^{2/3} = 300\times\dfrac{9}{4} = 675 \) K.
3. Rise \( = 675 - 300 = 375 \) K.

Teacher's Note:
1. The question asks for the rise, not the final temperature.

Question 20: For a monoatomic gas the relation between pressure P and temperature T in an adiabatic process is \( P \propto T^C \). The value of C is
(a) \( \dfrac{5}{3} \)
(b) \( \dfrac{2}{5} \)
(c) \( \dfrac{3}{5} \)
(d) \( \dfrac{5}{2} \)
Show Answer & Explanation

Answer: (d) \( \dfrac{5}{2} \)

Explanation:
1. Adiabatic: \( P^{1-\gamma}T^{\gamma} = \text{constant} \), so \( P \propto T^{\gamma/(\gamma-1)} \).
2. For \( \gamma = \dfrac{5}{3} \): \( C = \dfrac{5/3}{2/3} = \dfrac{5}{2} \).

Teacher's Note:
1. Use γ = 5/3 for a monoatomic gas.

Thermodynamics Objective Questions & Solutions for JEE Physics

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