JEE Physics Thermodynamics MCQs Set 05

Practice MCQs for JEE Physics Thermodynamics

Access targeted multiple-choice questions for Thermodynamics designed to align with the latest JEE academic syllabus for JEE Physics. These objective practice sets help students evaluate their conceptual understanding and improve exam readiness.

Access Thermodynamics Questions and Solutions

Access the complete set of multiple-choice questions for Thermodynamics below. This focused format allows students to isolate specific topics for thorough review and uninterrupted practice alongside official JEE textbooks.

Multiple Choice Questions

Question 1: A gas for which γ = 5/3 is heated at constant pressure. The percentage of the total heat given that will be used for external work is
(a) 40 %
(b) 60 %
(c) 30 %
(d) 20 %
Show Answer & Explanation

Answer: (a) 40 %

Explanation:
1. At constant pressure \( \dfrac{W}{Q} = \dfrac{R}{C_P} = 1 - \dfrac{1}{\gamma} \).
2. \( = 1 - \dfrac{3}{5} = \dfrac{2}{5} = 40\ \% \).

Teacher's Note:
1. The rest, 60 %, increases the internal energy.

Question 2: A vessel contains an ideal monoatomic gas which expands at constant pressure when heat Q is given to it. The work done in expansion is
(a) \( Q \)
(b) \( \dfrac{3}{5}Q \)
(c) \( \dfrac{2}{5}Q \)
(d) \( \dfrac{2}{3}Q \)
Show Answer & Explanation

Answer: (c) \( \dfrac{2}{5}Q \)

Explanation:
1. \( Q = nC_P\Delta T = \dfrac{5}{2}nR\Delta T \) and \( W = nR\Delta T \).
2. \( W = \dfrac{2}{5}Q \).

Teacher's Note:
1. Monatomic: C_P = 5R/2.

Question 3: One mole of an ideal gas at temperature \( T_1 \) expands according to the law \( P/V^2 = a \) (a constant). The work done by the gas till the temperature of the gas becomes \( T_2 \) is
(a) \( \dfrac{1}{2}R(T_2-T_1) \)
(b) \( \dfrac{1}{3}R(T_2-T_1) \)
(c) \( \dfrac{1}{4}R(T_2-T_1) \)
(d) \( \dfrac{1}{5}R(T_2-T_1) \)
Show Answer & Explanation

Answer: (b) \( \dfrac{1}{3}R(T_2-T_1) \)

Explanation:
1. \( P = aV^2 \), so \( W = \int PdV = \dfrac{a}{3}(V_2^3 - V_1^3) \).
2. With \( PV = RT \) we get \( aV^3 = RT \).
3. \( W = \dfrac{R}{3}(T_2 - T_1) \).

Teacher's Note:
1. Write P in terms of V and integrate.

Question 4: When an ideal diatomic gas is heated at constant pressure, the fraction of the heat energy supplied which increases the internal energy of the gas is
(a) \( \dfrac{2}{5} \)
(b) \( \dfrac{3}{5} \)
(c) \( \dfrac{3}{7} \)
(d) \( \dfrac{5}{7} \)
Show Answer & Explanation

Answer: (d) \( \dfrac{5}{7} \)

Explanation:
1. \( \dfrac{\Delta U}{Q} = \dfrac{nC_V\Delta T}{nC_P\Delta T} = \dfrac{1}{\gamma} = \dfrac{5}{7} \).

Teacher's Note:
1. The remaining 2/7 of the heat is the work done.

Question 5: The pressure–temperature relationship for an ideal gas undergoing an adiabatic change is (γ = C_P/C_V)
(a) \( PT^{\gamma} = \text{constant} \)
(b) \( PT^{-1+\gamma} = \text{constant} \)
(c) \( P^{\gamma-1}T^{\gamma} = \text{constant} \)
(d) \( P^{1-\gamma}T^{\gamma} = \text{constant} \)
Show Answer & Explanation

Answer: (d) \( P^{1-\gamma}T^{\gamma} = \text{constant} \)

Explanation:
1. Combine \( PV^\gamma = c \) with \( V = \dfrac{nRT}{P} \).
2. \( P\left(\dfrac{T}{P}\right)^\gamma = c \), so \( P^{1-\gamma}T^\gamma = \text{constant} \).

Teacher's Note:
1. Check with TV^(γ−1) = constant for consistency.

Question 6: The value of the internal energy of an ideal gas in an adiabatic process
(a) remains unchanged
(b) only increases
(c) only diminishes
(d) may diminish and may also increase
Show Answer & Explanation

Answer: (d) may diminish and may also increase

Explanation:
1. In an adiabatic process \( \Delta U = -W \).
2. During compression W is negative and U increases; during expansion U decreases.
3. So it may either increase or diminish.

Teacher's Note:
1. The direction depends on whether the gas is compressed or expanded.

Question 7: One mole of an ideal monoatomic gas is heated at a constant pressure of one atmosphere from 0°C to 100°C. The change in internal energy is (R = 8.31 J/mol K)
(a) \( 20.80\times10^2 \) J
(b) \( 12.48\times10^2 \) J
(c) \( 832\times10^2 \) J
(d) \( 6.25\times10^2 \) J
Show Answer & Explanation

Answer: (b) \( 12.48\times10^2 \) J

Explanation:
1. \( \Delta U = nC_V\Delta T = 1\times\dfrac{3}{2}\times8.31\times100 = 1246.5 \) J.
2. \( \approx 12.48\times10^2 \) J.

Teacher's Note:
1. ΔU depends only on ΔT for an ideal gas, whether at constant pressure or not.

Question 8: The specific heat of a gas at constant pressure is more than that at constant volume because
(a) work is done in the expansion of the gas at constant pressure
(b) work is done in the expansion of the gas at constant volume
(c) the molecular attraction increases under constant pressure
(d) the vibration of molecules increases under constant pressure
Show Answer & Explanation

Answer: (a) work is done in the expansion of the gas at constant pressure

Explanation:
1. At constant pressure the gas expands, so part of the heat supplied goes into external work.
2. The extra heat per degree is the work, \( C_P - C_V = R \).

Teacher's Note:
1. At constant volume no work is done.

Question 9: When a gas is adiabatically compressed, its temperature increases because
(a) work done is zero
(b) internal energy is increased
(c) heat is supplied to it
(d) there is no change in pressure
Show Answer & Explanation

Answer: (b) internal energy is increased

Explanation:
1. In adiabatic compression \( Q = 0 \), so \( \Delta U = -W > 0 \) (W is negative).
2. The work done on the gas raises its internal energy and hence its temperature.

Teacher's Note:
1. No heat is supplied, only work is done on the gas.

Question 10: Air is filled in a tube of the wheel of a car at 27°C and 2 atm pressure. If the tube suddenly bursts, the final temperature of the air will be (γ = 1.5, 2^{1/3} = 1.251)
(a) −33°C
(b) 21.6°C
(c) 0°C
(d) 240°C
Show Answer & Explanation

Answer: (a) −33°C

Explanation:
1. The sudden burst is adiabatic and the pressure falls to 1 atm.
2. \( T_2 = T_1\left(\dfrac{P_2}{P_1}\right)^{(\gamma-1)/\gamma} = 300\times\left(\dfrac{1}{2}\right)^{1/3} = \dfrac{300}{1.251} = 240 \) K.
3. \( 240 - 273 = -33 \)°C.

Teacher's Note:
1. Sudden expansion cools the gas.

Question 11: The specific heat of a gas undergoing an adiabatic change is
(a) zero
(b) infinite
(c) positive
(d) negative
Show Answer & Explanation

Answer: (a) zero

Explanation:
1. Specific heat \( = \dfrac{Q}{m\Delta T} \).
2. In an adiabatic change \( Q = 0 \) while ΔT is not zero, so the specific heat is zero.

Teacher's Note:
1. In an isothermal change it is infinite.

Question 12: A quantity of air (γ = 1.4) at 27°C is compressed suddenly. The temperature of the air will
(a) fall
(b) rise
(c) remain unchanged
(d) first rise and then fall
Show Answer & Explanation

Answer: (b) rise

Explanation:
1. A sudden compression is adiabatic and work is done on the gas.
2. Its internal energy and temperature rise.

Teacher's Note:
1. Fast compression leaves no time for heat to escape.

Question 13: A gas specimen in one vessel is expanded isothermally to double its volume, and a similar specimen in a second vessel is expanded adiabatically to the same extent. Then
(a) in the second vessel both pressure and work done are more
(b) in the second vessel the pressure is more but the work done is less
(c) in the first vessel both pressure and work done are more
(d) in the first vessel the pressure is more but the work done is less
Show Answer & Explanation

Answer: (c) in the first vessel both pressure and work done are more

Explanation:
1. For the isothermal expansion \( P_2 = \dfrac{P_1}{2} \). For the adiabatic expansion \( P_2 = \dfrac{P_1}{2^\gamma} \), which is smaller.
2. The adiabatic curve falls more steeply, so the area under it (work) is also smaller.
3. So the first vessel has both more pressure and more work.

Teacher's Note:
1. The adiabatic curve is steeper than the isothermal one.

Question 14: If an ideal gas is compressed during an isothermal process, then
(a) no work is done against it
(b) heat is rejected by the gas
(c) its internal energy will increase
(d) its pressure does not change
Show Answer & Explanation

Answer: (b) heat is rejected by the gas

Explanation:
1. In an isothermal process \( \Delta U = 0 \).
2. Work is done on the gas, so \( Q = W < 0 \): the gas gives out heat.

Teacher's Note:
1. Pressure rises on isothermal compression.

Question 15: The graphs between P and V for isothermal and adiabatic processes are drawn through the same point. The relation between their slopes is
(a) slope of adiabatic curve = γ × (slope of isothermal curve)
(b) slope of isothermal curve = γ × (slope of adiabatic curve)
(c) slope of isothermal curve = slope of adiabatic curve
(d) slope of adiabatic curve = γ² × (slope of isothermal curve)
Show Answer & Explanation

Answer: (a) slope of adiabatic curve = γ × (slope of isothermal curve)

Explanation:
1. Isothermal: \( \dfrac{dP}{dV} = -\dfrac{P}{V} \). Adiabatic: \( \dfrac{dP}{dV} = -\gamma\dfrac{P}{V} \).
2. So the adiabatic slope is γ times the isothermal slope.

Teacher's Note:
1. γ is greater than 1, so the adiabatic curve is steeper.

Question 16: An ideal gas is taken round the cycle ABCA on a P–V diagram. The vertices are A (V₁, 4P₁), B (3V₁, P₁) and C (V₁, P₁). The path is A to B (straight line), B to C (isobaric) and C to A (isochoric). The work done in the cycle is
(a) \( 12P_1V_1 \)
(b) \( 6P_1V_1 \)
(c) \( 3P_1V_1 \)
(d) \( P_1V_1 \)
Show Answer & Explanation

Answer: (c) \( 3P_1V_1 \)

Explanation:
1. Work equals the area of the triangle.
2. Base \( = 3V_1 - V_1 = 2V_1 \), height \( = 4P_1 - P_1 = 3P_1 \).
3. Area \( = \dfrac{1}{2}\times2V_1\times3P_1 = 3P_1V_1 \).
4. The expansion A to B is at higher pressure than the compression B to C, so W is positive.

Teacher's Note:
1. Area of a triangle is half base times height.

Question 17: One mole of an ideal gas is compressed adiabatically at 27°C and its temperature becomes 102°C. The work done by the gas in this process is (γ = 1.5, R = 8.3 J/mol K)
(a) −625 J
(b) 625 J
(c) 1245 J
(d) −1245 J
Show Answer & Explanation

Answer: (d) −1245 J

Explanation:
1. \( W = \dfrac{nR(T_1 - T_2)}{\gamma - 1} = \dfrac{8.3\times(300 - 375)}{0.5} = -1245 \) J.

Teacher's Note:
1. The negative sign means work is done on the gas.

Question 18: In an isometric (isochoric) change
(a) \( \delta Q = dU \)
(b) \( \delta W = dU \)
(c) \( \delta Q + \delta W = dU \)
(d) none of these
Show Answer & Explanation

Answer: (a) \( \delta Q = dU \)

Explanation:
1. At constant volume \( \delta W = P\,dV = 0 \).
2. The first law \( \delta Q = dU + \delta W \) becomes \( \delta Q = dU \).

Teacher's Note:
1. All heat goes into internal energy.

Question 19: The volume of a gas expands by 0.25 m³ at a constant pressure of 10³ N/m². The work done is equal to
(a) 2.5 erg
(b) 250 J
(c) 250 W
(d) 250 N
Show Answer & Explanation

Answer: (b) 250 J

Explanation:
1. \( W = P\Delta V = 10^3\times0.25 = 250 \) J.

Teacher's Note:
1. Work is measured in joules.

Question 20: The process in which the heat given to a system is completely transformed into work, for an ideal gas, is
(a) isobaric
(b) isometric
(c) isothermal
(d) adiabatic
Show Answer & Explanation

Answer: (c) isothermal

Explanation:
1. In an isothermal change the internal energy of an ideal gas is constant, so \( Q = W \).
2. All the heat supplied becomes work.

Teacher's Note:
1. This does not violate the second law because the gas ends up in a different state.

Multiple Choice Questions (MCQs) for JEE Physics Thermodynamics

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