JEE Chemistry Surface Chemistry MCQs Set 04

Multiple Choice Questions (MCQs) for JEE Chemistry: Surface Chemistry

Access targeted multiple-choice questions for Surface Chemistry designed to align with the latest JEE academic syllabus for JEE Chemistry. These objective practice sets help students evaluate their conceptual understanding and improve exam readiness.

Practice Surface Chemistry MCQs for JEE Chemistry

View or download the dedicated Surface Chemistry MCQ resource below. Practicing these 50 objective questions regularly builds familiarity with standard exam patterns and helps secure higher marks in final Chemistry evaluations.

Multiple Choice Questions

Question 1: Physical adsorption is appreciable at
(a) Higher temperature
(b) Lower temperature
(c) Room temperature only
(d) \( 100^\circ \)C
Show Answer & Explanation

Answer: (b) Lower temperature

Explanation:
1. Physical adsorption is exothermic and is favoured at low temperature.
2. It decreases as temperature rises.

Teacher's Note:
1. Physisorption falls with temperature.
2. Chemisorption first rises, then falls.

Question 2: The rate of physical adsorption
(a) Decreases with increase of pressure
(b) Is independent of pressure at high pressure
(c) Is maximum at one atmosphere pressure
(d) Always increases with increase of pressure
Show Answer & Explanation

Answer: (b) Is independent of pressure at high pressure

Explanation:
1. Adsorption increases with pressure at first and then reaches saturation.
2. At high pressure the surface is full and the extent becomes independent of pressure.

Teacher's Note:
1. Adsorption isotherm levels off at high pressure.

Question 3: Which one of the following is NOT a correct statement?
(a) Physical adsorption is reversible in nature
(b) Physical adsorption involves van der Waals forces
(c) The rate of physical adsorption increases with increase of pressure on the adsorbate
(d) High activation energy is involved in physical adsorption
Show Answer & Explanation

Answer: (d) High activation energy is involved in physical adsorption

Explanation:
1. Physical adsorption needs almost no activation energy.
2. The other statements are correct.

Teacher's Note:
1. Chemisorption needs activation energy, physisorption does not.

Question 4: Which of the following is correct?
(a) Langmuir adsorption is highly specific
(b) van der Waals adsorption is reversible
(c) Both are exothermic
(d) All are correct
Show Answer & Explanation

Answer: (d) All are correct

Explanation:
1. Langmuir (chemical) adsorption is specific and van der Waals adsorption is reversible.
2. Both kinds of adsorption are exothermic, so all statements are correct.

Teacher's Note:
1. All adsorption is exothermic.

Question 5: Which characteristic of adsorption is wrong?
(a) Physical adsorption in general decreases with temperature
(b) Physical adsorption in general increases with temperature
(c) Physical adsorption is a reversible process
(d) Adsorption is limited to the surface only
Show Answer & Explanation

Answer: (b) Physical adsorption in general increases with temperature

Explanation:
1. Physical adsorption is exothermic, so it decreases as temperature increases.
2. Statement 2 says the opposite and is wrong.

Teacher's Note:
1. Rule: exothermic process is favoured by low temperature.

Question 6: Sorption is the term used when
(a) Adsorption takes place
(b) Absorption takes place
(c) Both adsorption and absorption take place
(d) Desorption takes place
Show Answer & Explanation

Answer: (c) Both adsorption and absorption take place

Explanation:
1. Sorption refers to adsorption and absorption occurring together.
2. Desorption is the reverse of adsorption.

Teacher's Note:
1. Sorption = adsorption + absorption.

Question 7: The extent of adsorption of a gas on a solid depends on
(a) The nature of the gas
(b) The pressure of the gas
(c) The temperature of the system
(d) All of these
Show Answer & Explanation

Answer: (d) All of these

Explanation:
1. Adsorption depends on the nature of the gas and solid, pressure, temperature and surface area.
2. All three listed factors matter.

Teacher's Note:
1. Freundlich isotherm links x/m with p and T.

Question 8: The number of phases present in a colloidal solution is
(a) 2
(b) 4
(c) 3
(d) 1
Show Answer & Explanation

Answer: (a) 2

Explanation:
1. A colloid has two phases, the dispersed phase and the dispersion medium.
2. Hence it is a heterogeneous system.

Teacher's Note:
1. Two phases: dispersed and medium.

Question 9: Lyophobic colloids are
(a) Reversible
(b) Irreversible
(c) Water loving
(d) Solvent loving
Show Answer & Explanation

Answer: (b) Irreversible

Explanation:
1. Lyophobic (solvent hating) sols are irreversible because once coagulated they do not form the sol again on adding the solvent.
2. Lyophilic sols are reversible.

Teacher's Note:
1. Lyophobic: needs stabilisers.
2. Lyophilic: self-stable.

Question 10: 'The greater the valency, the higher is the coagulating power of the ion.' This rule was introduced by
(a) Hardy and Schulze
(b) Graham
(c) Kossel and Lewis
(d) Faraday
Show Answer & Explanation

Answer: (a) Hardy and Schulze

Explanation:
1. The Hardy-Schulze rule relates the coagulating power of an ion to its charge.
2. It applies to the ion of charge opposite to that of the sol.

Teacher's Note:
1. Al3+ > Ba2+ > Na+ for negative sols.

Question 11: All colloidal solutions show
(a) Very high osmotic pressure
(b) High osmotic pressure
(c) Low osmotic pressure
(d) No osmotic pressure
Show Answer & Explanation

Answer: (c) Low osmotic pressure

Explanation:
1. Colloidal particles are big, so the number of particles per unit volume is small.
2. Hence the colligative properties and osmotic pressure are low.

Teacher's Note:
1. Large particle size gives low colligative effects.

Question 12: Brownian motion shown by colloidal particles is its ........ property
(a) Optical
(b) Electrical
(c) Kinetic
(d) Chemical
Show Answer & Explanation

Answer: (c) Kinetic

Explanation:
1. Brownian motion arises from collisions of the particles with the molecules of the medium.
2. It is a kinetic property.

Teacher's Note:
1. Tyndall effect is optical.
2. Electrophoresis is electrical.

Question 13: In both dialysis and osmosis, which particles do NOT pass through the semipermeable membrane?
(a) Water
(b) Small molecules
(c) Colloids
(d) All
Show Answer & Explanation

Answer: (c) Colloids

Explanation:
1. A semipermeable membrane lets water and small molecules pass but not colloidal particles.
2. That is the basis of dialysis.

Teacher's Note:
1. Colloidal particles are too big.

Question 14: A colloidal system involves
(a) A state of dissolution
(b) A state of dispersion
(c) A state of suspension
(d) None
Show Answer & Explanation

Answer: (b) A state of dispersion

Explanation:
1. A colloid is a dispersion of one phase in another, not a true solution or a suspension.
2. The particle size is 1 to 1000 nm.

Teacher's Note:
1. Colloidal state is a state of dispersion.

Question 15: Which of the following is NOT shown by sols?
(a) Adsorption
(b) Tyndall effect
(c) Flocculation
(d) Paramagnetism
Show Answer & Explanation

Answer: (d) Paramagnetism

Explanation:
1. Sols show adsorption, Tyndall scattering and coagulation (flocculation).
2. Paramagnetism is a magnetic property that is not characteristic of colloids.

Teacher's Note:
1. Colloidal properties: optical, kinetic, electrical.

Question 16: Emulsifiers are generally
(a) Soaps
(b) Synthetic detergents
(c) Lyophilic sols
(d) All of the above
Show Answer & Explanation

Answer: (d) All of the above

Explanation:
1. Soaps, detergents and lyophilic sols (gelatin, gum) can all stabilise emulsions.
2. So all three are emulsifiers.

Teacher's Note:
1. Lyophilic sols act as protective colloids.

Question 17: On adding AgNO\(_3\) solution to KI solution, a negatively charged colloidal sol is obtained when they are mixed as
(a) 100 mL of 0.1 M AgNO3 + 100 mL of 0.1 M KI
(b) 100 mL of 0.1 M AgNO3 + 50 mL of 0.2 M KI
(c) 200 mL of 0.1 M AgNO3 + 200 mL of 0.1 M KI
(d) 100 mL of 0.1 M AgNO3 + 100 mL of 0.15 M KI
Show Answer & Explanation

Answer: (d) 100 mL of 0.1 M AgNO3 + 100 mL of 0.15 M KI

Explanation:
1. A negative AgI sol needs excess iodide so that I- is adsorbed.
2. Option 4 has 10 mmol Ag+ and 15 mmol I-, an excess of iodide; the others have equal amounts.

Teacher's Note:
1. Excess KI gives a negative sol.
2. Excess AgNO3 gives a positive sol.

Question 18: Which of the following ions has the minimum flocculation value for a positively charged sol?
(a) \( \ce{Cl-} \)
(b) \( \ce{SO4^{2-}} \)
(c) \( \ce{PO4^{3-}} \)
(d) \( \ce{[Fe(CN)6]^{4-}} \)
Show Answer & Explanation

Answer: (d) \( \ce{[Fe(CN)6]^{4-}} \)

Explanation:
1. The ion with the highest charge of opposite sign, [Fe(CN)6]4-, coagulates the sol at the lowest concentration.
2. A smaller flocculation value means higher coagulating power.

Teacher's Note:
1. Flocculation value is the minimum concentration needed.

Question 19: Which of the following is NOT a colloidal solution?
(a) Smoke
(b) Ink
(c) Air
(d) Blood
Show Answer & Explanation

Answer: (c) Air

Explanation:
1. Air is a homogeneous mixture of gases.
2. Smoke, ink and blood are colloids.

Teacher's Note:
1. Smoke is a solid in gas colloid.

Question 20: Medicines are more effective if they are used in
(a) Colloidal state
(b) Solid state
(c) Granular state
(d) All of the above
Show Answer & Explanation

Answer: (a) Colloidal state

Explanation:
1. The colloidal state has a large surface area, so medicines are assimilated quickly.
2. Examples are colloidal silver and colloidal sulphur.

Teacher's Note:
1. Large surface area increases effectiveness.

Question 21: Gelatin protects
(a) Gold sol
(b) As2S3 sol
(c) Fe(OH)3 sol
(d) All of these
Show Answer & Explanation

Answer: (d) All of these

Explanation:
1. Gelatin is a protective colloid that stabilises lyophobic sols.
2. It protects all three sols.

Teacher's Note:
1. Gold number measures this protection.

Multiple Choice Questions (MCQs) for JEE Chemistry Surface Chemistry

JEE Chemistry Surface Chemistry Objective Test Questions

Test your conceptual understanding of Surface Chemistry with these targeted multiple-choice questions. Designed in alignment with the latest JEE curriculum for JEE Chemistry, these problem sets build accuracy and prepare students for objective exams.

NCERT-Aligned Objective Questions and Solutions

Each question includes structured solution keys mapped directly to standard JEE textbooks, helping students evaluate their reasoning and correct mistakes early in their revision.

Next Steps in Your Exam Preparation

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FAQs

Where can I access latest JEE Chemistry Surface Chemistry MCQs Set 04?

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