JEE Physics Atoms MCQs Set 03

Physics Objective Questions and Answers: Atoms

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Multiple Choice Questions

Question 1: If in the first orbit of a hydrogen atom the total energy of the electron is \( -21.76\times10^{-19} \) J, then its potential energy will be:
(a) \( -43.52\times10^{-19} \) J
(b) \( -21.76\times10^{-19} \) J
(c) \( -10.88\times10^{-19} \) J
(d) \( -13.6\times10^{-19} \) J
Show Answer & Explanation

Answer: (a) \( -43.52\times10^{-19} \) J

Explanation:
1. For an electron in a Bohr orbit, \( U = 2E \) (since \( K = -E \) and \( U = -2K \))
2. \( U = 2\times(-21.76\times10^{-19}) = -43.52\times10^{-19} \) J. Answer: (a)

Teacher's Note:
1. Potential energy is twice the total energy and kinetic energy equals minus the total energy.
2. All three energies are in the ratio K : U : E = 1 : -2 : -1.

Question 2: The longest wavelength of a photon in the Balmer series of hydrogen is:
(a) 0.66 nm
(b) 6.56 nm
(c) 65.6 nm
(d) 656 nm
Show Answer & Explanation

Answer: (d) 656 nm

Explanation:
1. Longest wavelength corresponds to the transition \( n = 3 \to 2 \)
2. \( \frac1\lambda = R\left(\frac14 - \frac19\right) = \frac{5R}{36} \)
3. \( \lambda = \frac{36}{5R} = \frac{36}{5\times1.097\times10^7} \approx 656 \) nm. Answer: (d)

Teacher's Note:
1. The longest wavelength is the lowest energy transition in the series.
2. Balmer lines end on n = 2.

Question 3: An electron in a hydrogen atom is excited from the ground state to the first excited level. Select the incorrect statement:
(a) Kinetic energy of the electron is decreased.
(b) Potential energy is increased.
(c) Time period of rotation is increased while angular momentum is decreased.
(d) Total energy is increased while angular speed is decreased.
Show Answer & Explanation

Answer: (c) Time period of rotation is increased while angular momentum is decreased.

Explanation:
1. Going from n = 1 to n = 2, the radius increases, kinetic energy decreases, potential energy increases and total energy increases
2. Angular momentum \( L = \frac{nh}{2\pi} \) increases, not decreases
3. The time period increases and the angular speed decreases. So the statement in (c) is incorrect. Answer: (c)

Teacher's Note:
1. Angular momentum in the Bohr model is proportional to n.
2. Higher orbits have longer time periods and smaller angular speeds.

Question 4: A force of attraction between the positively charged nucleus and the negatively charged electron in a hydrogen atom is given by \( F = \frac{ke^2}{r^2} \), where k is a constant. The electron, initially moving in a circle of radius \( R_1 \) about the nucleus, jumps suddenly into a circular orbit of radius \( R_2 \). The total energy of the atom decreased in this process is:
(a) \( \frac{ke^2}{2}\left[\frac{1}{R_1}+\frac{1}{R_2}\right] \)
(b) \( \frac{ke^2}{2}\left[\frac{1}{R_2}-\frac{1}{R_1}\right] \)
(c) \( \frac{ke^2}{2}\left[\frac{R_1R_2}{R_2-R_1}\right] \)
(d) \( \frac{ke^2}{2}\left[\frac{R_1R_2}{R_1+R_2}\right] \)
Show Answer & Explanation

Answer: (b) \( \frac{ke^2}{2}\left[\frac{1}{R_2}-\frac{1}{R_1}\right] \)

Explanation:
1. Total energy in a circular orbit \( E = -\frac{ke^2}{2r} \)
2. Decrease \( = E_1 - E_2 = -\frac{ke^2}{2R_1} + \frac{ke^2}{2R_2} = \frac{ke^2}{2}\left[\frac{1}{R_2} - \frac{1}{R_1}\right] \)
3. This is positive when \( R_2 < R_1 \), as the electron drops to an inner orbit. Answer: (b)

Teacher's Note:
1. Total energy equals minus half the potential-energy magnitude for a circular orbit.
2. The decrease is the initial energy minus the final energy.

Question 5: A sample of hydrogen atoms (in the ground state) is made to absorb ultraviolet light of a single energy by shining radiation on it. The most probable value of the energy absorbed is:
(a) 4.6 eV
(b) 5.2 eV
(c) 10.2 eV
(d) 7.8 eV
Show Answer & Explanation

Answer: (c) 10.2 eV

Explanation:
1. Ground-state atoms can absorb only energies equal to level differences \( 13.6\left(1-\frac{1}{n^2}\right) \) eV
2. The smallest is \( n = 1 \to 2 \): \( 13.6\times\frac34 = 10.2 \) eV
3. Only 10.2 eV matches the options. Answer: (c)

Teacher's Note:
1. Absorption by an atom needs the photon energy to equal an energy-level gap.
2. The first gap from n = 1 is 10.2 eV.

Atoms Objective Questions & Solutions for JEE Physics

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FAQs

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