Download JEE MCQs for JEE Chemistry: Structure Of Atom
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Chapter-wise Objective Questions: Structure Of Atom
Navigate directly to the 50 objective questions for Structure Of Atom using the digital viewer below. Each practice set includes verified answer keys, allowing students to instantly cross-check their work and identify areas requiring further revision.
Multiple Choice Questions
(a) excited state of \( \ce{O2-} \)
(b) excited state of neon atom
(c) excited state of fluorine atom
(d) ground state of fluorine atom
Show Answer & Explanation
Answer: (b) excited state of neon atom
Explanation:
1. Count the electrons: 2 + 2 + 5 + 1 = 10, so the species has atomic number 10 if neutral, i.e. neon.
2. The ground state of neon is \( 1s^22s^22p^6 \); here one 2p electron has moved to 3s.
3. So it is an excited state of neon.
Teacher's Note:
1. F
2. i
3. r
4. s
5. t
6.
7. c
8. o
9. u
10. n
11. t
12.
13. t
14. h
15. e
16.
17. e
18. l
19. e
20. c
21. t
22. r
23. o
24. n
25. s
26.
27. t
28. o
29.
30. i
31. d
32. e
33. n
34. t
35. i
36. f
37. y
38.
39. t
40. h
41. e
42.
43. a
44. t
45. o
46. m
47. ,
48.
49. t
50. h
51. e
52. n
53.
54. c
55. o
56. m
57. p
58. a
59. r
60. e
61.
62. w
63. i
64. t
65. h
66.
67. t
68. h
69. e
70.
71. g
72. r
73. o
74. u
75. n
76. d
77.
78. s
79. t
80. a
81. t
82. e
83.
84. c
85. o
86. n
87. f
88. i
89. g
90. u
91. r
92. a
93. t
94. i
95. o
96. n
97. .
98.
99. A
100. n
101.
102. e
103. l
104. e
105. c
106. t
107. r
108. o
109. n
110.
111. i
112. n
113.
114. a
115.
116. h
117. i
118. g
119. h
120. e
121. r
122.
123. l
124. e
125. v
126. e
127. l
128.
129. t
130. h
131. a
132. n
133.
134. t
135. h
136. e
137.
138. g
139. r
140. o
141. u
142. n
143. d
144.
145. s
146. t
147. a
148. t
149. e
150.
151. m
152. e
153. a
154. n
155. s
156.
157. a
158. n
159.
160. e
161. x
162. c
163. i
164. t
165. e
166. d
167.
168. s
169. t
170. a
171. t
172. e
173. .
(a) \( n^2 \)
(b) \( n+1 \)
(c) \( 2n \)
(d) \( 2n^2 \)
Show Answer & Explanation
Answer: (a) \( n^2 \)
Explanation:
1. For each l from 0 to n−1 there are 2l + 1 orbitals.
2. The sum \( \sum_{l=0}^{n-1}(2l+1)=n^2 \).
Teacher's Note:
1. A
2.
3. s
4. h
5. e
6. l
7. l
8.
9. h
10. o
11. l
12. d
13. s
14.
15. n
16. ²
17.
18. o
19. r
20. b
21. i
22. t
23. a
24. l
25. s
26.
27. a
28. n
29. d
30.
31. s
32. o
33.
34. 2
35. n
36. ²
37.
38. e
39. l
40. e
41. c
42. t
43. r
44. o
45. n
46. s
47. .
48.
49. F
50. o
51. r
52.
53. n
54.
55. =
56.
57. 3
58.
59. t
60. h
61. e
62. r
63. e
64.
65. a
66. r
67. e
68.
69. 9
70.
71. o
72. r
73. b
74. i
75. t
76. a
77. l
78. s
79. .
(a) an electron with positive charge
(b) a nucleus with one neutron and one proton
(c) a nucleus with two protons
(d) a helium nucleus
Show Answer & Explanation
Answer: (a) an electron with positive charge
Explanation:
1. A positron is the antiparticle of the electron with the same mass and a charge of +1.
2. It is written \( {}_{+1}^{0}e \).
Teacher's Note:
1. T
2. h
3. e
4.
5. p
6. o
7. s
8. i
9. t
10. r
11. o
12. n
13.
14. w
15. a
16. s
17.
18. t
19. h
20. e
21.
22. f
23. i
24. r
25. s
26. t
27.
28. a
29. n
30. t
31. i
32. p
33. a
34. r
35. t
36. i
37. c
38. l
39. e
40.
41. d
42. i
43. s
44. c
45. o
46. v
47. e
48. r
49. e
50. d
51. .
52.
53. I
54. t
55.
56. i
57. s
58.
59. e
60. m
61. i
62. t
63. t
64. e
65. d
66.
67. i
68. n
69.
70. β
71. ⁺
72.
73. d
74. e
75. c
76. a
77. y
78. .
(a) 2000 Å – 3700 Å
(b) 7800 Å – 8900 Å
(c) 3800 Å – 7600 Å
(d) None of these
Show Answer & Explanation
Answer: (c) 3800 Å – 7600 Å
Explanation:
1. Visible light spans violet (about 3800 Å) to red (about 7600 Å).
2. Shorter wavelengths are ultraviolet and longer ones are infrared.
Teacher's Note:
1. R
2. e
3. m
4. e
5. m
6. b
7. e
8. r
9.
10. 3
11. 8
12. 0
13.
14. n
15. m
16.
17. t
18. o
19.
20. 7
21. 6
22. 0
23.
24. n
25. m
26. .
27.
28. 1
29.
30. Å
31.
32. =
33.
34. 1
35. 0
36. ⁻
37. ¹
38. ⁰
39.
40. m
41. .
(a) \( 3.43\times10^{-33} \) cm
(b) \( 5.86\times10^{-33} \) cm
(c) \( 7.77\times10^{-33} \) cm
(d) \( 8.83\times10^{-33} \) cm
Show Answer & Explanation
Answer: (d) \( 8.83\times10^{-33} \) cm
Explanation:
1. \( \lambda=h/mv \) with m = 0.150 kg and v = 50 m/s.
2. \( \lambda=\dfrac{6.626\times10^{-34}}{0.150\times50}=8.83\times10^{-35} \) m.
3. Converting, \( 8.83\times10^{-35} \) m = \( 8.83\times10^{-33} \) cm.
Teacher's Note:
1. W
2. a
3. v
4. e
5. l
6. e
7. n
8. g
9. t
10. h
11. s
12.
13. o
14. f
15.
16. m
17. a
18. c
19. r
20. o
21. s
22. c
23. o
24. p
25. i
26. c
27.
28. o
29. b
30. j
31. e
32. c
33. t
34. s
35.
36. a
37. r
38. e
39.
40. f
41. a
42. r
43.
44. t
45. o
46. o
47.
48. s
49. m
50. a
51. l
52. l
53.
54. t
55. o
56.
57. o
58. b
59. s
60. e
61. r
62. v
63. e
64. .
65.
66. K
67. e
68. e
69. p
70.
71. t
72. h
73. e
74.
75. u
76. n
77. i
78. t
79. s
80.
81. c
82. o
83. n
84. s
85. i
86. s
87. t
88. e
89. n
90. t
91.
92. (
93. k
94. g
95. ,
96.
97. m
98. /
99. s
100. )
101.
102. b
103. e
104. f
105. o
106. r
107. e
108.
109. c
110. o
111. n
112. v
113. e
114. r
115. t
116. i
117. n
118. g
119.
120. t
121. o
122.
123. c
124. m
125. .
(a) \( 7.5678\times10^{-31} \) kg
(b) \( 9.1091\times10^{-31} \) kg
(c) \( 11.2531\times10^{-31} \) kg
(d) \( 13.0513\times10^{-31} \) kg
Show Answer & Explanation
Answer: (b) \( 9.1091\times10^{-31} \) kg
Explanation:
1. \( m=\dfrac{e}{e/m}=\dfrac{1.60206\times10^{-19}}{1.75875\times10^{11}} \).
2. This equals \( 9.1091\times10^{-31} \) kg.
Teacher's Note:
1. T
2. h
3. o
4. m
5. s
6. o
7. n
8.
9. m
10. e
11. a
12. s
13. u
14. r
15. e
16. d
17.
18. e
19. /
20. m
21.
22. a
23. n
24. d
25.
26. M
27. i
28. l
29. l
30. i
31. k
32. a
33. n
34.
35. m
36. e
37. a
38. s
39. u
40. r
41. e
42. d
43.
44. e
45. .
46.
47. D
48. i
49. v
50. i
51. d
52. i
53. n
54. g
55.
56. t
57. h
58. e
59. m
60.
61. g
62. i
63. v
64. e
65. s
66.
67. t
68. h
69. e
70.
71. m
72. a
73. s
74. s
75.
76. o
77. f
78.
79. t
80. h
81. e
82.
83. e
84. l
85. e
86. c
87. t
88. r
89. o
90. n
91. .
(a) \( -54.47\times10^{-12} \) erg atom⁻¹
(b) \( -5.447\times10^{-12} \) erg atom⁻¹
(c) \( -0.5447\times10^{-12} \) erg atom⁻¹
(d) \( -0.05447\times10^{-12} \) erg atom⁻¹
Show Answer & Explanation
Answer: (b) \( -5.447\times10^{-12} \) erg atom⁻¹
Explanation:
1. \( E_n\propto 1/n^2 \) for a given atom.
2. \( E_2=E_1/4=-21.79\times10^{-12}/4 \).
3. So \( E_2=-5.447\times10^{-12} \) erg per atom.
Teacher's Note:
1. E
2. n
3. e
4. r
5. g
6. y
7.
8. o
9. f
10.
11. l
12. e
13. v
14. e
15. l
16.
17. n
18.
19. i
20. s
21.
22. E
23. ₁
24. /
25. n
26. ²
27. .
28.
29. L
30. e
31. v
32. e
33. l
34.
35. 2
36.
37. i
38. s
39.
40. o
41. n
42. e
43.
44. q
45. u
46. a
47. r
48. t
49. e
50. r
51.
52. o
53. f
54.
55. l
56. e
57. v
58. e
59. l
60.
61. 1
62. .
(a) 1 proton, 1 electron
(b) 1 proton, 1 neutron
(c) 2 protons, 1 electron
(d) 1 proton, 2 electrons
Show Answer & Explanation
Answer: (b) 1 proton, 1 neutron
Explanation:
1. Deuterium is the hydrogen isotope of mass number 2 and atomic number 1.
2. So its nucleus has 1 proton and 2 − 1 = 1 neutron. Electrons are outside the nucleus.
Teacher's Note:
1. I
2. s
3. o
4. t
5. o
6. p
7. e
8. s
9.
10. o
11. f
12.
13. h
14. y
15. d
16. r
17. o
18. g
19. e
20. n
21. :
22.
23. p
24. r
25. o
26. t
27. i
28. u
29. m
30.
31. (
32. 0
33.
34. n
35. e
36. u
37. t
38. r
39. o
40. n
41. )
42. ,
43.
44. d
45. e
46. u
47. t
48. e
49. r
50. i
51. u
52. m
53.
54. (
55. 1
56. )
57.
58. a
59. n
60. d
61.
62. t
63. r
64. i
65. t
66. i
67. u
68. m
69.
70. (
71. 2
72. )
73. .
74.
75. N
76. u
77. c
78. l
79. e
80. i
81.
82. n
83. e
84. v
85. e
86. r
87.
88. c
89. o
90. n
91. t
92. a
93. i
94. n
95.
96. e
97. l
98. e
99. c
100. t
101. r
102. o
103. n
104. s
105. .
(a) \( ns^2np^5 \)
(b) \( ns^2np^6 \)
(c) \( ns^2np^4 \)
(d) \( ns^2np^3 \)
Show Answer & Explanation
Answer: (a) \( ns^2np^5 \)
Explanation:
1. The most electronegative element is fluorine, a halogen.
2. Halogens have seven valence electrons, \( ns^2np^5 \).
Teacher's Note:
1. E
2. l
3. e
4. c
5. t
6. r
7. o
8. n
9. e
10. g
11. a
12. t
13. i
14. v
15. i
16. t
17. y
18.
19. i
20. n
21. c
22. r
23. e
24. a
25. s
26. e
27. s
28.
29. a
30. c
31. r
32. o
33. s
34. s
35.
36. a
37.
38. p
39. e
40. r
41. i
42. o
43. d
44.
45. a
46. n
47. d
48.
49. d
50. e
51. c
52. r
53. e
54. a
55. s
56. e
57. s
58.
59. d
60. o
61. w
62. n
63.
64. a
65.
66. g
67. r
68. o
69. u
70. p
71. .
72.
73. F
74. l
75. u
76. o
77. r
78. i
79. n
80. e
81.
82. i
83. s
84.
85. a
86. t
87.
88. t
89. h
90. e
91.
92. t
93. o
94. p
95.
96. r
97. i
98. g
99. h
100. t
101. ,
102.
103. e
104. x
105. c
106. l
107. u
108. d
109. i
110. n
111. g
112.
113. n
114. o
115. b
116. l
117. e
118.
119. g
120. a
121. s
122. e
123. s
124. .
(a) H
(b) \( \ce{He+} \)
(c) \( \ce{Li^2+} \)
(d) \( \ce{H+} \)
Show Answer & Explanation
Answer: (d) \( \ce{H+} \)
Explanation:
1. Bohr's theory applies to one-electron species such as H, \( \ce{He+} \) and \( \ce{Li^2+} \).
2. H⁺ is a bare proton with no electron, so the theory cannot apply.
Teacher's Note:
1. B
2. o
3. h
4. r
5. '
6. s
7.
8. m
9. o
10. d
11. e
12. l
13.
14. w
15. o
16. r
17. k
18. s
19.
20. o
21. n
22. l
23. y
24.
25. f
26. o
27. r
28.
29. h
30. y
31. d
32. r
33. o
34. g
35. e
36. n
37. -
38. l
39. i
40. k
41. e
42.
43. s
44. p
45. e
46. c
47. i
48. e
49. s
50.
51. w
52. i
53. t
54. h
55.
56. o
57. n
58. e
59.
60. e
61. l
62. e
63. c
64. t
65. r
66. o
67. n
68. .
69.
70. I
71. t
72.
73. f
74. a
75. i
76. l
77. s
78.
79. f
80. o
81. r
82.
83. m
84. u
85. l
86. t
87. i
88. -
89. e
90. l
91. e
92. c
93. t
94. r
95. o
96. n
97.
98. a
99. t
100. o
101. m
102. s
103. .
(a) 33.28 nm
(b) 3.328 nm
(c) 0.3328 nm
(d) 0.0332 nm
Show Answer & Explanation
Answer: (c) 0.3328 nm
Explanation:
1. \( \lambda=\dfrac{h}{\sqrt{2m\,\mathrm{KE}}} \).
2. KE = 13.6 × 1.602×10⁻¹⁹ = 2.18×10⁻¹⁸ J.
3. \( \lambda=\dfrac{6.626\times10^{-34}}{\sqrt{2\times9.1\times10^{-31}\times2.18\times10^{-18}}}\approx3.33\times10^{-10} \) m = 0.3328 nm.
Teacher's Note:
1. T
2. h
3. e
4.
5. w
6. a
7. v
8. e
9. l
10. e
11. n
12. g
13. t
14. h
15.
16. e
17. q
18. u
19. a
20. l
21. s
22.
23. t
24. h
25. e
26.
27. c
28. i
29. r
30. c
31. u
32. m
33. f
34. e
35. r
36. e
37. n
38. c
39. e
40.
41. o
42. f
43.
44. t
45. h
46. e
47.
48. f
49. i
50. r
51. s
52. t
53.
54. B
55. o
56. h
57. r
58.
59. o
60. r
61. b
62. i
63. t
64. ,
65.
66. 2
67. π
68.
69. ×
70.
71. 0
72. .
73. 5
74. 2
75. 9
76.
77. Å
78.
79. =
80.
81. 3
82. .
83. 3
84. 2
85.
86. Å
87. .
88.
89. T
90. h
91. i
92. s
93.
94. a
95. g
96. r
97. e
98. e
99. s
100.
101. w
102. i
103. t
104. h
105.
106. t
107. h
108. e
109.
110. c
111. a
112. l
113. c
114. u
115. l
116. a
117. t
118. i
119. o
120. n
121. .
(a) \( 6.63\times10^{-7} \) m
(b) \( 6.63\times10^{-16} \) m
(c) \( 6.63\times10^{-21} \) m
(d) \( 6.63\times10^{-29} \) m
Show Answer & Explanation
Answer: (d) \( 6.63\times10^{-29} \) m
Explanation:
1. \( \lambda=\dfrac{h}{mv}=\dfrac{6.63\times10^{-34}}{10^{-6}\times10} \).
2. This is \( 6.63\times10^{-29} \) m.
Teacher's Note:
1. A
2. p
3. p
4. l
5. y
6.
7. λ
8.
9. =
10.
11. h
12. /
13. m
14. v
15.
16. d
17. i
18. r
19. e
20. c
21. t
22. l
23. y
24.
25. w
26. i
27. t
28. h
29.
30. S
31. I
32.
33. u
34. n
35. i
36. t
37. s
38. .
39.
40. A
41.
42. s
43. m
44. a
45. l
46. l
47.
48. m
49. a
50. s
51. s
52.
53. o
54. f
55.
56. 1
57.
58. m
59. g
60.
61. s
62. t
63. i
64. l
65. l
66.
67. g
68. i
69. v
70. e
71. s
72.
73. a
74. n
75.
76. u
77. n
78. o
79. b
80. s
81. e
82. r
83. v
84. a
85. b
86. l
87. e
88.
89. w
90. a
91. v
92. e
93. l
94. e
95. n
96. g
97. t
98. h
99. .
(a) \( 10.94\times10^{6} \) m s⁻¹
(b) \( 18.88\times10^{6} \) m s⁻¹
(c) \( 1.888\times10^{6} \) m s⁻¹
(d) \( 1.094\times10^{6} \) m s⁻¹
Show Answer & Explanation
Answer: (d) \( 1.094\times10^{6} \) m s⁻¹
Explanation:
1. Bohr velocity: \( v=2.188\times10^6\,\dfrac{Z}{n} \) m/s.
2. For hydrogen Z = 1 and n = 2, so \( v=\dfrac{2.188\times10^6}{2}=1.094\times10^6 \) m/s.
Teacher's Note:
1. V
2. e
3. l
4. o
5. c
6. i
7. t
8. y
9.
10. f
11. a
12. l
13. l
14. s
15.
16. a
17. s
18.
19. 1
20. /
21. n
22. ,
23.
24. s
25. o
26.
27. t
28. h
29. e
30.
31. e
32. l
33. e
34. c
35. t
36. r
37. o
38. n
39.
40. i
41. n
42.
43. h
44. i
45. g
46. h
47. e
48. r
49.
50. o
51. r
52. b
53. i
54. t
55. s
56.
57. m
58. o
59. v
60. e
61. s
62.
63. m
64. o
65. r
66. e
67.
68. s
69. l
70. o
71. w
72. l
73. y
74. .
75.
76. R
77. a
78. d
79. i
80. u
81. s
82.
83. g
84. r
85. o
86. w
87. s
88.
89. a
90. s
91.
92. n
93. ²
94. .
(a) nitrogen
(b) oxygen
(c) fluorine
(d) sulphur
Show Answer & Explanation
Answer: (a) nitrogen
Explanation:
1. Total electrons = 2 + 2 + 3 = 7.
2. Atomic number 7 is nitrogen.
Teacher's Note:
1. H
2. u
3. n
4. d
5. '
6. s
7.
8. r
9. u
10. l
11. e
12.
13. p
14. l
15. a
16. c
17. e
18. s
19.
20. o
21. n
22. e
23.
24. e
25. l
26. e
27. c
28. t
29. r
30. o
31. n
32.
33. i
34. n
35.
36. e
37. a
38. c
39. h
40.
41. 2
42. p
43.
44. o
45. r
46. b
47. i
48. t
49. a
50. l
51.
52. b
53. e
54. f
55. o
56. r
57. e
58.
59. p
60. a
61. i
62. r
63. i
64. n
65. g
66. .
67.
68. T
69. h
70. i
71. s
72.
73. i
74. s
75.
76. t
77. h
78. e
79.
80. g
81. r
82. o
83. u
84. n
85. d
86.
87. s
88. t
89. a
90. t
91. e
92.
93. o
94. f
95.
96. n
97. i
98. t
99. r
100. o
101. g
102. e
103. n
104. .
(a) Hund's rule
(b) Pauli's exclusion principle
(c) Aufbau principle
(d) Heisenberg's uncertainty principle
Show Answer & Explanation
Answer: (b) Pauli's exclusion principle
Explanation:
1. Pauli's principle states that no two electrons in an atom can have the same set of all four quantum numbers.
2. The four quantum numbers are therefore used to specify an electron uniquely.
Teacher's Note:
1. P
2. a
3. u
4. l
5. i
6. '
7. s
8.
9. e
10. x
11. c
12. l
13. u
14. s
15. i
16. o
17. n
18.
19. p
20. r
21. i
22. n
23. c
24. i
25. p
26. l
27. e
28.
29. l
30. i
31. m
32. i
33. t
34. s
35.
36. a
37. n
38.
39. o
40. r
41. b
42. i
43. t
44. a
45. l
46.
47. t
48. o
49.
50. t
51. w
52. o
53.
54. e
55. l
56. e
57. c
58. t
59. r
60. o
61. n
62. s
63.
64. o
65. f
66.
67. o
68. p
69. p
70. o
71. s
72. i
73. t
74. e
75.
76. s
77. p
78. i
79. n
80. .
81.
82. A
83. u
84. f
85. b
86. a
87. u
88.
89. a
90. n
91. d
92.
93. H
94. u
95. n
96. d
97. '
98. s
99.
100. r
101. u
102. l
103. e
104.
105. d
106. e
107. c
108. i
109. d
110. e
111.
112. t
113. h
114. e
115.
116. o
117. r
118. d
119. e
120. r
121.
122. o
123. f
124.
125. f
126. i
127. l
128. l
129. i
130. n
131. g
132. .
(a) H
(b) Be
(c) He
(d) Ne
Show Answer & Explanation
Answer: (a) H
Explanation:
1. \( \ce{Li^2+} \) has only one electron, so it is a hydrogen-like species.
2. Its spectrum resembles that of hydrogen, with lines scaled by \( Z^2 \).
Teacher's Note:
1. H
2. y
3. d
4. r
5. o
6. g
7. e
8. n
9. -
10. l
11. i
12. k
13. e
14.
15. i
16. o
17. n
18. s
19.
20. (
21. H
22. e
23. ⁺
24. ,
25.
26. L
27. i
28. ²
29. ⁺
30. ,
31.
32. B
33. e
34. ³
35. ⁺
36. )
37.
38. h
39. a
40. v
41. e
42.
43. s
44. i
45. n
46. g
47. l
48. e
49. -
50. e
51. l
52. e
53. c
54. t
55. r
56. o
57. n
58.
59. s
60. p
61. e
62. c
63. t
64. r
65. a
66. .
67.
68. O
69. n
70. l
71. y
72.
73. t
74. h
75. e
76.
77. s
78. c
79. a
80. l
81. e
82.
83. f
84. a
85. c
86. t
87. o
88. r
89.
90. Z
91. ²
92.
93. c
94. h
95. a
96. n
97. g
98. e
99. s
100. .
(a) \( e/m \) ratio of electron
(b) angular momentum of electron
(c) spin of electron
(d) magnetic moment of electron
Show Answer & Explanation
Answer: (b) angular momentum of electron
Explanation:
1. The azimuthal (subsidiary) quantum number l determines the shape of the orbital and the orbital angular momentum, \( \sqrt{l(l+1)}\,\hbar \).
Teacher's Note:
1. l
2.
3. =
4.
5. 0
6. ,
7.
8. 1
9. ,
10.
11. 2
12. ,
13.
14. 3
15.
16. c
17. o
18. r
19. r
20. e
21. s
22. p
23. o
24. n
25. d
26.
27. t
28. o
29.
30. s
31. ,
32.
33. p
34. ,
35.
36. d
37. ,
38.
39. f
40. .
41.
42. T
43. h
44. e
45.
46. m
47. a
48. g
49. n
50. e
51. t
52. i
53. c
54.
55. q
56. u
57. a
58. n
59. t
60. u
61. m
62.
63. n
64. u
65. m
66. b
67. e
68. r
69.
70. g
71. i
72. v
73. e
74. s
75.
76. o
77. r
78. i
79. e
80. n
81. t
82. a
83. t
84. i
85. o
86. n
87.
88. a
89. n
90. d
91.
92. m
93. s
94.
95. g
96. i
97. v
98. e
99. s
100.
101. s
102. p
103. i
104. n
105. .
(a) the effective volume of the orbital
(b) the shape of the orbital
(c) the spatial orientation of the orbital
(d) the energy of the orbital in the absence of a magnetic field
Show Answer & Explanation
Answer: (c) the spatial orientation of the orbital
Explanation:
1. The magnetic quantum number m has values from −l to +l.
2. It gives the orientation of the orbital in space; in the absence of a field the orientations have equal energy.
Teacher's Note:
1. F
2. o
3. r
4.
5. l
6.
7. =
8.
9. 1
10.
11. t
12. h
13. e
14. r
15. e
16.
17. a
18. r
19. e
20.
21. t
22. h
23. r
24. e
25. e
26.
27. p
28.
29. o
30. r
31. b
32. i
33. t
34. a
35. l
36. s
37.
38. w
39. i
40. t
41. h
42.
43. m
44.
45. =
46.
47. −
48. 1
49. ,
50.
51. 0
52. ,
53.
54. +
55. 1
56. .
57.
58. T
59. h
60. e
61. y
62.
63. d
64. i
65. f
66. f
67. e
68. r
69.
70. i
71. n
72.
73. d
74. i
75. r
76. e
77. c
78. t
79. i
80. o
81. n
82. ,
83.
84. n
85. o
86. t
87.
88. i
89. n
90.
91. s
92. i
93. z
94. e
95.
96. o
97. r
98.
99. s
100. h
101. a
102. p
103. e
104. .
(a) 3
(b) 7
(c) 5
(d) 9
Show Answer & Explanation
Answer: (b) 7
Explanation:
1. For n = 4 and l = 3 the subshell is 4f.
2. The number of orbitals is 2l + 1 = 7.
Teacher's Note:
1. E
2. a
3. c
4. h
5.
6. s
7. u
8. b
9. s
10. h
11. e
12. l
13. l
14.
15. l
16.
17. h
18. a
19. s
20.
21. 2
22. l
23.
24. +
25.
26. 1
27.
28. o
29. r
30. b
31. i
32. t
33. a
34. l
35. s
36. :
37.
38. s
39.
40. 1
41. ,
42.
43. p
44.
45. 3
46. ,
47.
48. d
49.
50. 5
51. ,
52.
53. f
54.
55. 7
56. .
57.
58. S
59. o
60.
61. 4
62. f
63.
64. h
65. a
66. s
67.
68. s
69. e
70. v
71. e
72. n
73.
74. o
75. r
76. b
77. i
78. t
79. a
80. l
81. s
82. .
(a) \( \ce{Cl2O} \) and \( \ce{ICl2-} \)
(b) \( \ce{ICl2-} \) and \( \ce{ClO2} \)
(c) \( \ce{IF2+} \) and \( \ce{I3-} \)
(d) \( \ce{ClO2-} \) and \( \ce{ClF2+} \)
Show Answer & Explanation
Answer: (d) \( \ce{ClO2-} \) and \( \ce{ClF2+} \)
Explanation:
1. \( \ce{ClO2-} \): 17 + 2×8 + 1 = 34 electrons.
2. \( \ce{ClF2+} \): 17 + 2×9 − 1 = 34 electrons.
3. The other pairs have different numbers of electrons, so the pair in (d) is isoelectronic.
Teacher's Note:
1. I
2. s
3. o
4. e
5. l
6. e
7. c
8. t
9. r
10. o
11. n
12. i
13. c
14.
15. s
16. p
17. e
18. c
19. i
20. e
21. s
22.
23. h
24. a
25. v
26. e
27.
28. t
29. h
30. e
31.
32. s
33. a
34. m
35. e
36.
37. t
38. o
39. t
40. a
41. l
42.
43. n
44. u
45. m
46. b
47. e
48. r
49.
50. o
51. f
52.
53. e
54. l
55. e
56. c
57. t
58. r
59. o
60. n
61. s
62. .
63.
64. A
65. d
66. d
67.
68. a
69. t
70. o
71. m
72. i
73. c
74.
75. n
76. u
77. m
78. b
79. e
80. r
81. s
82.
83. a
84. n
85. d
86.
87. a
88. d
89. j
90. u
91. s
92. t
93.
94. f
95. o
96. r
97.
98. c
99. h
100. a
101. r
102. g
103. e
104. .
(a) 0.0
(b) 52.9
(c) 26.5
(d) 105.8
Show Answer & Explanation
Answer: (c) 26.5
Explanation:
1. The most probable radius for the 1s electron is the Bohr radius for the species: \( r=\dfrac{52.9\,n^2}{Z} \) pm.
2. With n = 1 and Z = 2, \( r=52.9/2=26.45 \) pm.
Teacher's Note:
1. A
2.
3. h
4. y
5. d
6. r
7. o
8. g
9. e
10. n
11. -
12. l
13. i
14. k
15. e
16.
17. i
18. o
19. n
20.
21. w
22. i
23. t
24. h
25.
26. l
27. a
28. r
29. g
30. e
31. r
32.
33. Z
34.
35. h
36. a
37. s
38.
39. a
40.
41. s
42. m
43. a
44. l
45. l
46. e
47. r
48.
49. o
50. r
51. b
52. i
53. t
54. .
55.
56. H
57. e
58. ⁺
59.
60. r
61. a
62. d
63. i
64. u
65. s
66.
67. i
68. s
69.
70. h
71. a
72. l
73. f
74.
75. t
76. h
77. a
78. t
79.
80. o
81. f
82.
83. h
84. y
85. d
86. r
87. o
88. g
89. e
90. n
91. .
(a) \( 6.626\times10^{-34} \) m
(b) \( 13.20\times10^{-34} \) m
(c) \( 10.38\times10^{-21} \) m
(d) \( 6.626\times10^{-34} \) Å
Show Answer & Explanation
Answer: (a) \( 6.626\times10^{-34} \) m
Explanation:
1. \( \lambda=\dfrac{h}{mv}=\dfrac{h}{\sqrt{2m\,\mathrm{KE}}} \).
2. \( \sqrt{2\times1\times0.5}=1 \) kg m/s (so v = 1 m/s).
3. So \( \lambda=6.626\times10^{-34} \) m.
Teacher's Note:
1. M
2. o
3. m
4. e
5. n
6. t
7. u
8. m
9.
10. c
11. a
12. n
13.
14. b
15. e
16.
17. o
18. b
19. t
20. a
21. i
22. n
23. e
24. d
25.
26. f
27. r
28. o
29. m
30.
31. k
32. i
33. n
34. e
35. t
36. i
37. c
38.
39. e
40. n
41. e
42. r
43. g
44. y
45.
46. a
47. s
48.
49. p
50.
51. =
52.
53. √
54. (
55. 2
56. m
57. K
58. E
59. )
60. .
61.
62. H
63. e
64. r
65. e
66.
67. p
68.
69. =
70.
71. 1
72.
73. k
74. g
75.
76. m
77. /
78. s
79. .
(a) 2
(b) 0.25
(c) 4
(d) 1
Show Answer & Explanation
Answer: (a) 2
Explanation:
1. Heisenberg: \( \Delta x\cdot m\Delta v=\dfrac{h}{4\pi} \), so \( \Delta x\propto\dfrac{1}{m\,\Delta v} \).
2. \( \dfrac{\Delta x_A}{\Delta x_B}=\dfrac{m_B\Delta v_B}{m_A\Delta v_A}=\dfrac{5\times0.02}{1\times0.05}=2 \).
Teacher's Note:
1. T
2. h
3. e
4.
5. p
6. r
7. o
8. d
9. u
10. c
11. t
12.
13. o
14. f
15.
16. u
17. n
18. c
19. e
20. r
21. t
22. a
23. i
24. n
25. t
26. y
27.
28. i
29. n
30.
31. p
32. o
33. s
34. i
35. t
36. i
37. o
38. n
39.
40. a
41. n
42. d
43.
44. i
45. n
46.
47. m
48. o
49. m
50. e
51. n
52. t
53. u
54. m
55.
56. i
57. s
58.
59. f
60. i
61. x
62. e
63. d
64. .
65.
66. A
67.
68. h
69. e
70. a
71. v
72. i
73. e
74. r
75.
76. o
77. r
78.
79. b
80. e
81. t
82. t
83. e
84. r
85. -
86. d
87. e
88. f
89. i
90. n
91. e
92. d
93.
94. p
95. a
96. r
97. t
98. i
99. c
100. l
101. e
102.
103. h
104. a
105. s
106.
107. a
108.
109. s
110. m
111. a
112. l
113. l
114. e
115. r
116.
117. Δ
118. x
119. .
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