Multiple Choice Questions (MCQs) for JEE Chemistry: General Principles and Processes Of Isolation Of Elements
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Multiple Choice Questions
(a) Zn
(b) Au
(c) Ag
(d) Hg
Show Answer & Explanation
Answer: (a) Zn
Explanation:
1. Zn is reactive and occurs as ZnS (zinc blende), ZnCO3 (calamine) and ZnO (zincite).
2. Au and Ag occur native, and Hg occurs native in traces.
Teacher's Note:
1. Native metals are the least reactive ones: Au, Ag, Pt, Cu (rare).
2. Reactive metals occur as compounds.
(a) the metal cannot be extracted economically from all minerals
(b) minerals are complex compounds
(c) minerals are obtained from mines
(d) all of these are correct
Show Answer & Explanation
Answer: (a) the metal cannot be extracted economically from all minerals
Explanation:
1. An ore is a mineral from which the metal can be extracted profitably.
2. Many minerals have too little metal or are too costly to process.
Teacher's Note:
1. Ore = economically viable mineral.
2. Clay is a mineral of Al but not an ore of Al.
(a) Zn
(b) Cr
(c) Ag
(d) Fe
Show Answer & Explanation
Answer: (b) Cr
Explanation:
1. Zn (blende), Ag (argentite) and Fe (pyrites) all occur as sulphides.
2. Chromium occurs as chromite FeCr2O4, an oxide ore.
Teacher's Note:
1. Chromite is the main ore of chromium.
2. Sulphide ores are concentrated by froth floatation.
(a) Cu
(b) Ca
(c) Fe
(d) Ag
Show Answer & Explanation
Answer: (b) Ca
Explanation:
1. Ca is highly electropositive and cannot be reduced by carbon; it is obtained by electrolysis of fused CaCl2.
Teacher's Note:
1. Highly electropositive metals (Na, K, Ca, Mg, Al) are extracted by fused salt electrolysis.
(a) Cu
(b) Ca
(c) Hg
(d) Zn
Show Answer & Explanation
Answer: (d) Zn
Explanation:
1. ZnO is reduced by coke at about 1673 K: ZnO + C → Zn + CO.
2. Ca needs electrolysis, Hg is obtained by roasting, and Cu is obtained by self-reduction.
Teacher's Note:
1. Check the Ellingham diagram for the oxide: carbon reduces ZnO above about 1200 K.
2. Zn vapour is collected and condensed.
(a) sodium alumino-silicate
(b) zinc cobaltate
(c) basic copper carbonate
(d) Prussian blue
Show Answer & Explanation
Answer: (a) sodium alumino-silicate
Explanation:
1. Lapis lazuli is a sodium alumino-silicate containing sulphur, Na8[Al6Si6O24]Sn.
Teacher's Note:
1. Do not confuse it with azurite (blue basic copper carbonate).
(a) its high density
(b) polished surface
(c) its chemical inertness
(d) presence of free electrons
Show Answer & Explanation
Answer: (d) presence of free electrons
Explanation:
1. Free electrons absorb and re-emit light, giving the metallic lustre.
Teacher's Note:
1. Free electrons also explain conductivity and malleability.
(a) Fused salt electrolysis
(b) Self reduction
(c) Aqueous solution electrolysis
(d) Thermite reduction
Show Answer & Explanation
Answer: (a) Fused salt electrolysis
Explanation:
1. Mg is highly electropositive.
2. It is obtained by electrolysis of fused anhydrous MgCl2 (or carnallite) mixed with NaCl and CaCl2.
Teacher's Note:
1. Aqueous electrolysis would liberate H2 instead of Mg.
(a) Mg
(b) Au
(c) Cu
(d) Zn
Show Answer & Explanation
Answer: (b) Au
Explanation:
1. Gold is leached with dilute NaCN in air to form [Au(CN)2]−, and then displaced with zinc dust.
Teacher's Note:
1. Cyanide leaching is used for Au and Ag.
(a) Copper
(b) Iron
(c) Silver
(d) Magnesium
Show Answer & Explanation
Answer: (a) Copper
Explanation:
1. In the extraction of copper, Cu2S reacts with Cu2O in the absence of air: 2Cu2O + Cu2S → 6Cu + SO2.
Teacher's Note:
1. Self-reduction is used for Cu, Pb and Hg.
(a) Au
(b) Ag
(c) Al
(d) both Au and Ag
Show Answer & Explanation
Answer: (d) both Au and Ag
Explanation:
1. Native Au and Ag, and Ag2S, dissolve in NaCN in the presence of air to give cyano complexes.
Teacher's Note:
1. The complexes are reduced by zinc dust.
(a) adsorption
(b) absorption
(c) coagulation
(d) sedimentation
Show Answer & Explanation
Answer: (a) adsorption
Explanation:
1. Sulphide ore particles are wetted by oil and adsorbed on air bubbles that rise to the surface.
Teacher's Note:
1. Preferential wetting: ore by oil, gangue by water.
(a) levigation
(b) leaching
(c) magnetic separation
(d) liquation
Show Answer & Explanation
Answer: (a) levigation
Explanation:
1. Levigation (hydraulic washing or gravity separation) washes away lighter gangue by flowing water.
Teacher's Note:
1. Used for heavy oxide ores such as haematite and cassiterite.
(a) SnO2 is paramagnetic
(b) SnO2 is diamagnetic
(c) FeWO4 and MnWO4 are paramagnetic
(d) both (b) and (c)
Show Answer & Explanation
Answer: (d) both (b) and (c)
Explanation:
1. Wolframite (FeWO4, MnWO4) is magnetic and SnO2 is non-magnetic.
2. A magnetic roller therefore separates them.
Teacher's Note:
1. The magnetic impurity is pulled off first.
(a) [Ag(CN)2]− is formed in a reversible reaction
(b) the Na2S formed is oxidised to Na2SO4 and sulphur
(c) both (a) and (b)
(d) none of the above
Show Answer & Explanation
Answer: (c) both (a) and (b)
Explanation:
1. Ag2S + 4NaCN ⇌ 2Na[Ag(CN)2] + Na2S is reversible.
2. Air oxidises Na2S to Na2SO4 and S, driving the reaction forward.
Teacher's Note:
1. Removal of a product shifts the equilibrium forward.
(a) activator
(b) frother
(c) collector
(d) agitator
Show Answer & Explanation
Answer: (b) frother
Explanation:
1. Pine oil stabilises the froth.
2. Collectors such as sodium ethyl xanthate make the sulphide particles water repellent.
Teacher's Note:
1. Frother: pine oil, cresols. Collector: xanthates. Depressant: NaCN.
(a) sodium ethyl xanthate
(b) sodium xenate
(c) sodium pyrophosphate
(d) sodium chloride
Show Answer & Explanation
Answer: (a) sodium ethyl xanthate
Explanation:
1. Sodium ethyl xanthate attaches to the sulphide surface and makes it water repellent so that it enters the froth.
Teacher's Note:
1. Collectors bind to the ore; frothers stabilise bubbles.
(a) Pb(CN)2 is precipitated while ZnS is unaffected
(b) ZnS forms a soluble complex Na2[Zn(CN)4] while PbS combines with the frother
(c) PbS forms a soluble complex while ZnS combines with the frother
(d) NaCN regenerates ZnS from its complex
Show Answer & Explanation
Answer: (b) ZnS forms a soluble complex Na2[Zn(CN)4] while PbS combines with the frother
Explanation:
1. NaCN forms a soluble complex with ZnS, stopping it from floating.
2. PbS does not form this complex and floats with the froth.
Teacher's Note:
1. Depressants separate two sulphides by selective wetting.
2. Pb and Zn sulphides are separated this way.
(a) Argentite
(b) Galena
(c) Copper pyrite
(d) Sphalerite
Show Answer & Explanation
Answer: (a) Argentite
Explanation:
1. Argentite (Ag2S) is leached with dilute NaCN solution.
2. Galena, copper pyrite and sphalerite are concentrated by froth floatation.
Teacher's Note:
1. Leaching = chemical concentration.
(a) horn silver
(b) gypsum
(c) chromite
(d) magnesite
Show Answer & Explanation
Answer: (c) chromite
Explanation:
1. Chromite (FeCr2O4) is magnetic.
2. The other ores are non-magnetic.
Teacher's Note:
1. Other magnetic ores: wolframite, haematite (weak), pyrolusite.
(a) froth floatation
(b) magnetic separation
(c) chemical leaching
(d) gravity separation
Show Answer & Explanation
Answer: (c) chemical leaching
Explanation:
1. Bauxite is leached with hot concentrated NaOH (Baeyer's process) to dissolve Al2O3 as NaAlO2.
Teacher's Note:
1. Impurities Fe2O3 and TiO2 remain as solids.
(a) froth floatation
(b) magnetic separation
(c) leaching
(d) roasting
Show Answer & Explanation
Answer: (a) froth floatation
Explanation:
1. Zinc blende (ZnS) is a sulphide ore and is concentrated by froth floatation.
Teacher's Note:
1. Roasting is not a concentration step; it is a chemical conversion.
(a) calamine
(b) haematite
(c) chalcopyrite
(d) bauxite
Show Answer & Explanation
Answer: (b) haematite
Explanation:
1. Haematite is a heavy oxide ore separated from light silica gangue by washing with water.
Teacher's Note:
1. Heavy oxides: haematite, cassiterite.
(a) Gravity separation
(b) Froth floatation
(c) Electromagnetic separation
(d) Bessemerisation
Show Answer & Explanation
Answer: (d) Bessemerisation
Explanation:
1. Bessemerisation is a converter process used to convert Cu2S into blister copper (and steel making), not a concentration step.
Teacher's Note:
1. Concentration means removing gangue physically or chemically.
(a) Azurite
(b) Siderite
(c) Clay
(d) Cerussite
Show Answer & Explanation
Answer: (c) Clay
Explanation:
1. Clay (Al2O3·2SiO2·2H2O) contains aluminium but extraction is uneconomical; it is a mineral, not an ore.
Teacher's Note:
1. Azurite (Cu), siderite (Fe) and cerussite (Pb) are ores.
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