JEE Chemistry Basic Inorganic Nomenclature MCQs Set 02

Download JEE MCQs for JEE Chemistry: Basic Inorganic Nomenclature

Review structured MCQ sets for JEE Chemistry Basic Inorganic Nomenclature. Built according to official JEE guidelines, these downloadable questions support daily revision and core concept reinforcement.

Chapter-wise Objective Questions: Basic Inorganic Nomenclature

Navigate directly to the 50 objective questions for Basic Inorganic Nomenclature using the digital viewer below. Each practice set includes verified answer keys, allowing students to instantly cross-check their work and identify areas requiring further revision.

Multiple Choice Questions

Question 1: Sodium chlorite is
(a) \( \ce{NaClO2} \)
(b) \( \ce{NaClO3} \)
(c) \( \ce{NaClO} \)
(d) \( \ce{NaClO4} \)
Show Answer & Explanation

Answer: (a) \( \ce{NaClO2} \)

Explanation:
1. Chlorous acid \( \ce{HClO2} \) gives chlorite \( \ce{ClO2^-} \) (-ous gives -ite).
2. Only this option agrees with the working above, so it is the correct choice.

Teacher's Note:
1. Learn the suffix pattern first: -ic acid gives -ate, -ous acid gives -ite, and hypo-/per- prefixes carry over to the anion.

Question 2: Aluminium phosphide is
(a) \( \ce{AlP3} \)
(b) \( \ce{AlP} \)
(c) \( \ce{Al2P3} \)
(d) \( \ce{Al3P2} \)
Show Answer & Explanation

Answer: (b) \( \ce{AlP} \)

Explanation:
1. Al is +3 and phosphide is \( \ce{P^3-} \), so the ratio is 1:1.
2. Only this option agrees with the working above, so it is the correct choice.

Teacher's Note:
1. Write the cation first, put the charges as subscripts crosswise, then cancel any common factor.

Question 3: Barium azide is
(a) \( \ce{Ba(N3)2} \)
(b) \( \ce{BaN} \)
(c) \( \ce{Ba2N3} \)
(d) \( \ce{Ba3N2} \)
Show Answer & Explanation

Answer: (a) \( \ce{Ba(N3)2} \)

Explanation:
1. Azide is \( \ce{N3^-} \) and barium is \( \ce{Ba^2+} \), so two azide ions are needed. (\( \ce{Ba3N2} \) would be barium nitride.)
2. Only this option agrees with the working above, so it is the correct choice.

Teacher's Note:
1. Write the cation first, put the charges as subscripts crosswise, then cancel any common factor.

Question 4: Silicon fluoride (silicon tetrafluoride) has the formula
(a) \( \ce{SiF} \)
(b) \( \ce{SiF3} \)
(c) \( \ce{SiF4} \)
(d) \( \ce{SiF6} \)
Show Answer & Explanation

Answer: (c) \( \ce{SiF4} \)

Explanation:
1. Silicon has valency 4 with fluorine -1, so \( \ce{SiF4} \).
2. Only this option agrees with the working above, so it is the correct choice.

Teacher's Note:
1. Write the cation first, put the charges as subscripts crosswise, then cancel any common factor.

Question 5: Aluminium carbide is
(a) \( \ce{Al2C} \)
(b) \( \ce{AlC3} \)
(c) \( \ce{AlC} \)
(d) \( \ce{Al4C3} \)
Show Answer & Explanation

Answer: (d) \( \ce{Al4C3} \)

Explanation:
1. Al is +3 and carbide is \( \ce{C^4-} \): cross-multiplying gives \( \ce{Al4C3} \).
2. Only this option agrees with the working above, so it is the correct choice.

Teacher's Note:
1. Write the cation first, put the charges as subscripts crosswise, then cancel any common factor.

Question 6: Which of the following oxyacids forms a pyro acid?
(a) \( \ce{H3PO4} \) only
(b) All of these
(c) \( \ce{H3BO3} \) only
(d) \( \ce{H2SO4} \) only
Show Answer & Explanation

Answer: (b) All of these

Explanation:
1. \( \ce{2H3PO4} \) - \( \ce{H2O} \) = \( \ce{H4P2O7} \), \( \ce{2H3BO3} \) - \( \ce{H2O} \) = \( \ce{H4B2O5} \) and \( \ce{2H2SO4} \) - \( \ce{H2O} \) = \( \ce{H2S2O7} \) all exist.
2. Only this option agrees with the working above, so it is the correct choice.

Teacher's Note:
1. Prefixes ortho, meta and pyro describe the water content of the acid; per/peroxo means an O-O link is present.

Question 7: Which set of elements does not form meta oxyacids?
(a) Cl, S, P
(b) Si, B, C
(c) Cl, S, N
(d) C, Si, P
Show Answer & Explanation

Answer: (c) Cl, S, N

Explanation:
1. Meta acids are formed by Si, P and B (e.g. \( \ce{H2SiO3} \), \( \ce{HPO3} \), \( \ce{HBO2} \)); Cl, S and N do not form them. In the options, only the set Cl, S, N contains no such element.
2. Only this option agrees with the working above, so it is the correct choice.

Teacher's Note:
1. Prefixes ortho, meta and pyro describe the water content of the acid; per/peroxo means an O-O link is present.

Question 8: Which of the following name-formula pairs are correct? (i) \( \ce{CrO4^2-} \) chromate (ii) \( \ce{MnO4^2-} \) manganate (iii) \( \ce{BO3^3-} \) borate (iv) \( \ce{XeO4^2-} \) xenate
(a) (i) and (ii) only
(b) All of these
(c) (ii) and (iii) only
(d) (iii) and (iv) only
Show Answer & Explanation

Answer: (b) All of these

Explanation:
1. All four names follow the -ate rule and are correct.
2. Only this option agrees with the working above, so it is the correct choice.

Teacher's Note:
1. Learn the suffix pattern first: -ic acid gives -ate, -ous acid gives -ite, and hypo-/per- prefixes carry over to the anion.

Question 9: The formula of sodium trisulphide is
(a) \( \ce{Na3S} \)
(b) \( \ce{Na3S2} \)
(c) \( \ce{Na2S} \)
(d) \( \ce{Na2S3} \)
Show Answer & Explanation

Answer: (d) \( \ce{Na2S3} \)

Explanation:
1. Trisulphide is \( \ce{S3^2-} \) and sodium is +1, so \( \ce{Na2S3} \).
2. Only this option agrees with the working above, so it is the correct choice.

Teacher's Note:
1. Write the cation first, put the charges as subscripts crosswise, then cancel any common factor.

Question 10: \( \ce{PO4^3-} \) is called
(a) phosphate ion
(b) phosphite ion
(c) hypophosphite ion
(d) pyrophosphite ion
Show Answer & Explanation

Answer: (a) phosphate ion

Explanation:
1. It comes from the -ic acid \( \ce{H3PO4} \) so it is a phosphate.
2. Only this option agrees with the working above, so it is the correct choice.

Teacher's Note:
1. Learn the suffix pattern first: -ic acid gives -ate, -ous acid gives -ite, and hypo-/per- prefixes carry over to the anion.

Question 11: Pyrophosphoric acid is
(a) \( \ce{H3PO4} \)
(b) \( \ce{H4P2O5} \)
(c) \( \ce{H4P2O7} \)
(d) \( \ce{H3PO3} \)
Show Answer & Explanation

Answer: (c) \( \ce{H4P2O7} \)

Explanation:
1. \( \ce{2H3PO4} \) - \( \ce{H2O} \) = \( \ce{H4P2O7} \).
2. Only this option agrees with the working above, so it is the correct choice.

Teacher's Note:
1. Prefixes ortho, meta and pyro describe the water content of the acid; per/peroxo means an O-O link is present.

Question 12: Match the acids: (1) \( \ce{H3PO4} \) (2) \( \ce{HPO3} \) (3) \( \ce{H2SO4} \) (4) \( \ce{H2S2O3} \) with (p) metaphosphoric (q) thiosulphuric (r) phosphoric (s) sulphuric acid. The correct pairing is
(a) 1-s, 2-q, 3-r, 4-s
(b) 1-q, 2-r, 3-p, 4-q
(c) 1-s, 2-r, 3-q, 4-p
(d) 1-r, 2-p, 3-s, 4-q
Show Answer & Explanation

Answer: (d) 1-r, 2-p, 3-s, 4-q

Explanation:
1. \( \ce{H3PO4} \) is (ortho)phosphoric, \( \ce{HPO3} \) metaphosphoric, \( \ce{H2SO4} \) sulphuric and \( \ce{H2S2O3} \) thiosulphuric (one O replaced by S).
2. Only this option agrees with the working above, so it is the correct choice.

Teacher's Note:
1. Prefixes ortho, meta and pyro describe the water content of the acid; per/peroxo means an O-O link is present.

Question 13: Pyrosulphuric acid has the formula
(a) \( \ce{H2S2O8} \)
(b) \( \ce{H2S2O3} \)
(c) \( \ce{H2S2O7} \)
(d) \( \ce{H2SO3} \)
Show Answer & Explanation

Answer: (c) \( \ce{H2S2O7} \)

Explanation:
1. \( \ce{2H2SO4} \) - \( \ce{H2O} \) = \( \ce{H2S2O7} \).
2. Only this option agrees with the working above, so it is the correct choice.

Teacher's Note:
1. Prefixes ortho, meta and pyro describe the water content of the acid; per/peroxo means an O-O link is present.

Question 14: Sulphurous acid is
(a) \( \ce{H2SO3} \)
(b) \( \ce{H2S2O7} \)
(c) \( \ce{H2S2O8} \)
(d) \( \ce{H2S2O3} \)
Show Answer & Explanation

Answer: (a) \( \ce{H2SO3} \)

Explanation:
1. The -ous acid has fewer oxygens than sulphuric acid: \( \ce{H2SO3} \).
2. Only this option agrees with the working above, so it is the correct choice.

Teacher's Note:
1. Learn the suffix pattern first: -ic acid gives -ate, -ous acid gives -ite, and hypo-/per- prefixes carry over to the anion.

Question 15: Peroxomonosulphuric acid is
(a) \( \ce{H2S2O7} \)
(b) \( \ce{H2SO5} \)
(c) \( \ce{H2SO4} \)
(d) \( \ce{H2S2O8} \)
Show Answer & Explanation

Answer: (b) \( \ce{H2SO5} \)

Explanation:
1. One -O- of sulphuric acid is replaced by -O-O-, giving \( \ce{H2SO5} \).
2. Only this option agrees with the working above, so it is the correct choice.

Teacher's Note:
1. Prefixes ortho, meta and pyro describe the water content of the acid; per/peroxo means an O-O link is present.

Question 16: \( \ce{HIO2} \) is called
(a) hypoiodous acid
(b) iodic acid
(c) periodic acid
(d) iodous acid
Show Answer & Explanation

Answer: (d) iodous acid

Explanation:
1. HIO is hypoiodous, \( \ce{HIO2} \) iodous, \( \ce{HIO3} \) iodic, \( \ce{HIO4} \) periodic acid.
2. Only this option agrees with the working above, so it is the correct choice.

Teacher's Note:
1. Learn the suffix pattern first: -ic acid gives -ate, -ous acid gives -ite, and hypo-/per- prefixes carry over to the anion.

Question 17: \( \ce{Mg(IO)2} \) is called
(a) magnesium hypoiodite
(b) magnesium iodite
(c) magnesium iodate
(d) magnesium periodate
Show Answer & Explanation

Answer: (a) magnesium hypoiodite

Explanation:
1. IO^- comes from hypoiodous acid, so it is hypoiodite.
2. Only this option agrees with the working above, so it is the correct choice.

Teacher's Note:
1. Learn the suffix pattern first: -ic acid gives -ate, -ous acid gives -ite, and hypo-/per- prefixes carry over to the anion.

Question 18: Which of the following is a correct statement?
(a) \( \ce{CdF3} \) is a correct formula
(b) Zn can show only the +3 state
(c) The element of atomic number 29 lies in the p-block
(d) The name of \( \ce{SeO3^2-} \) is selenite
Show Answer & Explanation

Answer: (d) The name of \( \ce{SeO3^2-} \) is selenite

Explanation:
1. Selenium(IV) oxoanion is selenite. Cd is +2 so \( \ce{CdF2} \) is right, Zn is only +2 and Z = 29 (Cu) is a d-block element.
2. Only this option agrees with the working above, so it is the correct choice.

Teacher's Note:
1. Learn the suffix pattern first: -ic acid gives -ate, -ous acid gives -ite, and hypo-/per- prefixes carry over to the anion.

Question 19: Which of the following formulae is correct?
(a) \( \ce{SiI2} \)
(b) \( \ce{Na2C8H4O4} \)
(c) \( \ce{Cr2O7} \)
(d) \( \ce{Ti2O5} \)
Show Answer & Explanation

Answer: (b) \( \ce{Na2C8H4O4} \)

Explanation:
1. Sodium phthalate \( \ce{Na2C8H4O4} \) is a real salt; \( \ce{CrO3} \) or \( \ce{Cr2O3} \) (not \( \ce{Cr2O7} \)) and \( \ce{TiO2} \) are the common oxides.
2. Only this option agrees with the working above, so it is the correct choice.

Teacher's Note:
1. Write the cation first, put the charges as subscripts crosswise, then cancel any common factor.

Question 20: The prefix peroxo is used in the name of
(a) \( \ce{H2SnO3} \)
(b) \( \ce{Sb2O5} \)
(c) \( \ce{H3PO5} \)
(d) \( \ce{HNO2} \)
Show Answer & Explanation

Answer: (c) \( \ce{H3PO5} \)

Explanation:
1. \( \ce{H3PO5} \) has one O-O link and is peroxomonophosphoric acid; the others have no peroxide link.
2. Only this option agrees with the working above, so it is the correct choice.

Teacher's Note:
1. Prefixes ortho, meta and pyro describe the water content of the acid; per/peroxo means an O-O link is present.

Question 21: Match \( \ce{CO3^2-} \), \( \ce{N3^-} \), \( \ce{O2^2-} \), \( \ce{CH3COO^-} \) in that order with names
(a) carbonate, azide, peroxide, acetate
(b) carbonate, azide, acetate, peroxide
(c) azide, carbonate, peroxide, acetate
(d) carbonate, nitride, peroxide, acetate
Show Answer & Explanation

Answer: (a) carbonate, azide, peroxide, acetate

Explanation:
1. The names are the standard ones: \( \ce{N3^-} \) is azide (nitride is \( \ce{N^3-} \)).
2. Only this option agrees with the working above, so it is the correct choice.

Teacher's Note:
1. Learn the suffix pattern first: -ic acid gives -ate, -ous acid gives -ite, and hypo-/per- prefixes carry over to the anion.

Question 22: The dichromate ion is
(a) \( \ce{CrO4^2-} \)
(b) \( \ce{Cr2O7^2-} \)
(c) \( \ce{CrO3} \)
(d) \( \ce{Cr2O4} \)
Show Answer & Explanation

Answer: (b) \( \ce{Cr2O7^2-} \)

Explanation:
1. Two chromate ions condense with loss of one oxide to give \( \ce{Cr2O7^2-} \).
2. Only this option agrees with the working above, so it is the correct choice.

Teacher's Note:
1. Learn the suffix pattern first: -ic acid gives -ate, -ous acid gives -ite, and hypo-/per- prefixes carry over to the anion.

Question 23: How many of these are pyro acids: \( \ce{H4P2O7} \), \( \ce{H4P2O5} \), \( \ce{H2S2O3} \), \( \ce{HNO2} \), \( \ce{H3PO4} \), \( \ce{HNO3} \), \( \ce{H6Si2O7} \)?
(a) 3
(b) 2
(c) 4
(d) 5
Show Answer & Explanation

Answer: (a) 3

Explanation:
1. \( \ce{H4P2O7} \) (pyrophosphoric), \( \ce{H4P2O5} \) (pyrophosphorous) and \( \ce{H6Si2O7} \) (pyrosilicic) are pyro acids; \( \ce{H2S2O3} \) is thiosulphuric.
2. Only this option agrees with the working above, so it is the correct choice.

Teacher's Note:
1. Prefixes ortho, meta and pyro describe the water content of the acid; per/peroxo means an O-O link is present.

Question 24: How many of these names are correct? \( \ce{N^3-} \) nitride; \( \ce{O^2-} \) peroxide; \( \ce{ZnO2^2-} \) zincate; \( \ce{SO4^2-} \) sulphite; \( \ce{NO2^-} \) nitrate; \( \ce{PbO2^2-} \) plumbite; \( \ce{Fe^2+} \) ferric.
(a) 2
(b) 4
(c) 3
(d) 5
Show Answer & Explanation

Answer: (c) 3

Explanation:
1. Correct: nitride, zincate and plumbite. Wrong: \( \ce{O^2-} \) is oxide, \( \ce{SO4^2-} \) sulphate, \( \ce{NO2^-} \) nitrite, \( \ce{Fe^2+} \) ferrous.
2. Only this option agrees with the working above, so it is the correct choice.

Teacher's Note:
1. Learn the suffix pattern first: -ic acid gives -ate, -ous acid gives -ite, and hypo-/per- prefixes carry over to the anion.

Question 25: How many of these are correct? (i) N shows +5, +4, +3, +1, -3, 0 (ii) alkaline earth metals are +1 (iii) HClO3 is perchloric acid (iv) \( \ce{(NH4)2SO4} \) is ammonium sulphate (v) \( \ce{Al(H2PO3)3} \) is aluminium hydrogen phosphite (vi) O is +2 in \( \ce{OF2} \) and +1 in \( \ce{O2F2} \) (vii) \( \ce{Cu^+, Sn^2+, Fe^3+, Sn^4+} \) are cuprous, stannous, ferric, stannic
(a) 3
(b) 4
(c) 6
(d) 5
Show Answer & Explanation

Answer: (d) 5

Explanation:
1. True: (i), (iv), (v), (vi), (vii). False: alkaline earth metals are +2, and \( \ce{HClO3} \) is chloric (not perchloric) acid.
2. Only this option agrees with the working above, so it is the correct choice.

Teacher's Note:
1. Learn the suffix pattern first: -ic acid gives -ate, -ous acid gives -ite, and hypo-/per- prefixes carry over to the anion.

Question 26: In how many of these does nitrogen show a positive oxidation state? \( \ce{NH3} \), \( \ce{Na3N} \), AlN, \( \ce{N2O} \), \( \ce{NF3} \), \( \ce{HNO2} \), \( \ce{NH4^+} \), \( \ce{N2O3} \), \( \ce{Ca(N3)2} \), \( \ce{Mg3N2} \), \( \ce{NaNO3} \)
(a) 4
(b) 5
(c) 6
(d) 7
Show Answer & Explanation

Answer: (b) 5

Explanation:
1. \( \ce{N2O} \) (+1), \( \ce{NF3} \) (+3), \( \ce{HNO2} \) (+3), \( \ce{N2O3} \) (+3), \( \ce{NaNO3} \) (+5) are positive; the rest are -3 or -1/3.
2. Only this option agrees with the working above, so it is the correct choice.

Teacher's Note:
1. Oxidation number is a bookkeeping charge: fix F = -1, O = -2 (exceptions in peroxides, superoxides, OF2), H = +1 and then make the total equal the charge on the species.

Multiple Choice Questions (MCQs) for JEE Chemistry Basic Inorganic Nomenclature

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FAQs

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