JEE Physics Kinetic Theory of Gases Notes Set 03

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Ideal Gas Equation

1. \(PV = nRT = NkT\). So \(PV/kT\) is the number of molecules.
2. For a given mass, \(PV = (m/M)RT\), so at equal mass the slope of PV against T is inversely proportional to the molar mass.
3. Gases in a closed ring separated by a free stopper have equal pressure and temperature, so their volumes are in the ratio of their moles.

Kinetic Theory

QuantityExpression
rms speed\(v = \sqrt{3kT/m} = \sqrt{3RT/M}\), proportional to \(\sqrt{T}\)
Mean translational energy per molecule\(\tfrac{3}{2}kT\)
Energy per degree of freedom\(\tfrac{1}{2}kT\)
Rigid diatomic molecule3 translational and 2 rotational, so total \(\tfrac{5}{2}kT\) and rotational \(kT\)

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