JEE Chemistry The P Block Elements Notes Set 05

Revision Notes for JEE Chemistry: P-Block Elements

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Boron and Aluminium

1. Borax gives a basic solution because it is the salt of a strong base and weak boric acid.
2. Borazine is a ring with alternating B and N. Its disubstituted derivatives have four isomers.
3. Anhydrous \(\ce{AlCl3}\) is prepared from \(\ce{Al2O3}\), carbon and dry \(\ce{Cl2}\), because moisture hydrolyses the chloride.

Carbon Family

1. Inert pair effect makes Pb(IV) strongly oxidising, so \(\ce{PbBr4}\) and \(\ce{PbI4}\) cannot exist, while \(\ce{PbCl4}\) does.
2. \(\ce{CCl4}\) is not hydrolysed because carbon has no d orbitals, but \(\ce{SiCl4}\) is hydrolysed readily.
3. Carbides: \(\ce{Al4C3}\) has \(\ce{C^{4-}}\) (gives methane), \(\ce{CaC2}\) has \(\ce{C2^{2-}}\) (gives ethyne), \(\ce{Mg2C3}\) has \(\ce{C3^{4-}}\) (gives propyne).
4. Hydrolysis and condensation of \(\ce{Me2SiCl2}\) gives both linear chain and cyclic silicones.

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P-Block Elements Concepts and Summary for JEE Chemistry

Quick Revision Notes: P-Block Elements (JEE)

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