Download JEE Chemistry Concept Summaries: JEE Chemistry The P Block Elements Notes Set 03
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Group 17: The Halogens
Fluorine is the strongest oxidant and shows only -1. Boiling points rise from F2 to I2 because of van der Waals forces. Chlorine, bromine and iodine show +1, +3, +5, +7 oxidation states. Hypohalites disproportionate to halide and halate, the rate being highest for IO-. Bleaching powder is CaOCl2. Interhalogens such as ClF3, BrF5 and IF7 are more reactive than the halogens. Bromine is manufactured from sea water by displacement by Cl2, absorption in Na2CO3 and acidification.
Group 18: Noble Gases
Noble gases have complete octets and are monatomic. Xenon forms XeF2 (linear), XeF4 (square planar), XeF6 (distorted octahedral), XeO3 (pyramidal) and XeOF4 (square pyramidal). The first compound of a noble gas was Xe+[PtF6]- (Neil Bartlett), made by analogy with O2+[PtF6]-. Helium has the lowest boiling point and is used in cryogenics.
Exam Tips
Learn each of the following as a set: the inert pair effect and the stability of oxidation states down each group, the structure and hybridisation of oxyanions and oxyacids, which reagent gives which oxidation product of nitrate and sulphate, and the order of properties such as acidity, basicity and thermal stability down groups.
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