JEE Chemistry Surface Chemistry MCQs Set 21

Multiple Choice Questions (MCQs) for JEE Chemistry: Surface Chemistry

Review structured MCQ sets for JEE Chemistry Surface Chemistry. Built according to official JEE guidelines, these downloadable questions support daily revision and core concept reinforcement.

Practice Surface Chemistry MCQs for JEE Chemistry

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Multiple Choice Questions

Question 1: Adsorption is the phenomenon in which a substance:
(a) Accumulates on the surface of another substance
(b) Goes into the body of another substance
(c) Remains close to another substance
(d) Oxidises or reduces another substance
Show Answer & Explanation

Answer: (a) Accumulates on the surface of another substance

Explanation:
1. Adsorption is the accumulation of molecules of a gas or liquid on the surface of a solid or liquid. Penetration into the bulk is absorption.

Teacher's Note:
1. Adsorption is a surface phenomenon.

Question 2: Adsorption is always:
(a) Endothermic
(b) Exothermic
(c) Accompanied by an increase in entropy
(d) Accompanied by an increase in enthalpy
Show Answer & Explanation

Answer: (b) Exothermic

Explanation:
1. Adsorption lowers the free energy of the surface and the freedom of the adsorbate, so both enthalpy and entropy decrease. As delta G is negative, delta H must be negative.

Teacher's Note:
1. Delta H is negative for adsorption.

Question 3: During adsorption, which statement is correct?
(a) \( T\Delta S \) is positive
(b) \( \Delta H - T\Delta S \) is negative
(c) \( \Delta H \) is positive
(d) \( T\Delta S \) and \( \Delta G \) become zero
Show Answer & Explanation

Answer: (b) \( \Delta H - T\Delta S \) is negative

Explanation:
1. Adsorption is spontaneous, so delta G = delta H - T delta S is negative. Delta H is negative and delta S is also negative.

Teacher's Note:
1. Spontaneous means delta G is negative.

Question 4: Valence forces (chemical bonds) between adsorbate and adsorbent cause:
(a) Chemisorption
(b) Physical adsorption
(c) Absorption
(d) Multilayer adsorption
Show Answer & Explanation

Answer: (a) Chemisorption

Explanation:
1. In chemisorption the adsorbate forms chemical bonds with the surface, so it is specific, irreversible and unilayered.

Teacher's Note:
1. Chemisorption is also called activated adsorption.

Question 5: Which of the following is NOT a characteristic of chemisorption?
(a) Adsorption is irreversible
(b) Enthalpy of adsorption is about 80 to 240 kJ/mol
(c) Adsorption is specific
(d) Adsorption is multilayered
Show Answer & Explanation

Answer: (d) Adsorption is multilayered

Explanation:
1. Chemisorption stops at one layer because the adsorbate bonds to surface atoms. Physical adsorption can be multilayered.

Teacher's Note:
1. Chemisorption is unimolecular.

Question 6: The plot of the extent of adsorption (x/m) against temperature at constant pressure is called:
(a) Adsorption isotherm
(b) Adsorption isobar
(c) Adsorption isochore
(d) Freundlich isotherm
Show Answer & Explanation

Answer: (b) Adsorption isobar

Explanation:
1. Constant pressure gives isobar, constant temperature gives isotherm.

Teacher's Note:
1. Iso-bar means constant pressure.

Question 7: The extent of adsorption from solution increases with:
(a) Increasing temperature
(b) Increasing surface area of the adsorbent
(c) Decreasing surface area of the adsorbent
(d) Decreasing concentration of solute
Show Answer & Explanation

Answer: (b) Increasing surface area of the adsorbent

Explanation:
1. More surface gives more sites for adsorption. Adsorption usually decreases with a rise in temperature.

Teacher's Note:
1. Powdered adsorbents are more effective.

Question 8: According to Freundlich adsorption isotherm, at high pressure the value of x/m is:
(a) Directly proportional to pressure
(b) Inversely proportional to pressure
(c) Proportional to the square of pressure
(d) Independent of pressure
Show Answer & Explanation

Answer: (d) Independent of pressure

Explanation:
1. \( x/m = k P^{1/n} \). At high pressure 1/n tends to 0, so x/m becomes constant.

Teacher's Note:
1. The surface becomes saturated.

Question 9: Which of the following is used as a good adsorbent for removing moisture?
(a) Silica gel
(b) Alumina gel
(c) Charcoal
(d) Both silica gel and alumina gel
Show Answer & Explanation

Answer: (d) Both silica gel and alumina gel

Explanation:
1. Silica gel and aluminium oxide gel adsorb water vapour strongly and are used as drying agents.

Teacher's Note:
1. Gels have a large surface area.

Question 10: The heat evolved during chemisorption lies in the range of:
(a) 4 to 20 kJ/mol
(b) 80 to 240 kJ/mol
(c) 20 to 40 kJ/mol
(d) 500 to 1000 kJ/mol
Show Answer & Explanation

Answer: (b) 80 to 240 kJ/mol

Explanation:
1. Chemisorption involves bond formation and has enthalpy changes similar to those of chemical reactions. Physical adsorption is about 20 to 40 kJ/mol.

Teacher's Note:
1. Chemisorption is much stronger than physisorption.

Question 11: Which metal can adsorb (occlude) a large volume of hydrogen gas?
(a) Palladium
(b) Nickel
(c) \( \ce{Fe(OH)3} \)
(d) Platinum
Show Answer & Explanation

Answer: (a) Palladium

Explanation:
1. Palladium absorbs up to about 900 times its own volume of hydrogen.

Teacher's Note:
1. Palladium forms non-stoichiometric hydrides.

Question 12: The temperature at which the catalytic activity of a catalyst is maximum is called the:
(a) Critical temperature
(b) Room temperature
(c) Optimum temperature
(d) Absolute temperature
Show Answer & Explanation

Answer: (c) Optimum temperature

Explanation:
1. Catalysts, and especially enzymes, work best at an optimum temperature.

Teacher's Note:
1. Too high a temperature can destroy an enzyme.

Question 13: The decomposition of \( \ce{KClO3} \) is catalysed by:
(a) HCl
(b) \( \ce{MnO2} \)
(c) \( \ce{C2H5OH} \)
(d) \( \ce{Cl2} \)
Show Answer & Explanation

Answer: (b) \( \ce{MnO2} \)

Explanation:
1. \( \ce{2KClO3 ->[MnO2] 2KCl + 3O2} \). Manganese dioxide lowers the decomposition temperature.

Teacher's Note:
1. MnO2 is a heterogeneous catalyst.

Question 14: The efficiency of a catalyst depends upon:
(a) Molecular weight
(b) Physical state
(c) Number of free valencies on the surface
(d) Amount of catalyst used
Show Answer & Explanation

Answer: (c) Number of free valencies on the surface

Explanation:
1. Free valencies on the surface give strong adsorption of the reactants.

Teacher's Note:
1. Active sites matter most.

Question 15: In the reactions \( \ce{CO + H2 -> CH4 + H2O} \) (X), \( \ce{CO + H2 -> CH3OH} \) (Y) and \( \ce{CO + H2 -> HCHO} \) (Z), the catalysts X, Y and Z are respectively:
(a) Cu; ZnO-Cr2O3; Ni
(b) Cu; Ni; Cu
(c) Ni; Cu; ZnO-Cr2O3
(d) Ni; ZnO-Cr2O3; Cu
Show Answer & Explanation

Answer: (d) Ni; ZnO-Cr2O3; Cu

Explanation:
1. Ni gives methane, ZnO with \( \ce{Cr2O3} \) gives methanol, and copper gives methanal. This shows the selectivity of catalysts.

Teacher's Note:
1. Same reactants but different catalysts give different products.

Question 16: Which of the following catalysts is the most sensitive to temperature changes?
(a) Fe
(b) Pt
(c) Ni
(d) Enzyme
Show Answer & Explanation

Answer: (d) Enzyme

Explanation:
1. Enzymes are proteins that denature when heated beyond their optimum temperature.

Teacher's Note:
1. Enzymes work around 298 to 310 K.

Question 17: The autocatalyst in the decomposition of arsine to arsenic and hydrogen is:
(a) \( \ce{As2O3} \)
(b) As
(c) \( \ce{H2} \)
(d) Ar
Show Answer & Explanation

Answer: (b) As

Explanation:
1. \( \ce{2AsH3 -> 2As + 3H2} \). The arsenic that forms catalyses the decomposition.

Teacher's Note:
1. An autocatalyst is a product that speeds up its own formation.

Question 18: Which one of the following is NOT an example of homogeneous catalysis?
(a) Formation of \( \ce{SO3} \) in the lead chamber process
(b) Formation of \( \ce{SO3} \) in the contact process
(c) Hydrolysis of ester with an acid
(d) Hydrolysis of sugar in the presence of sulphuric acid
Show Answer & Explanation

Answer: (b) Formation of \( \ce{SO3} \) in the contact process

Explanation:
1. In the contact process, solid \( \ce{Pt} \) or \( \ce{V2O5} \) acts on gases, so it is heterogeneous. In the lead chamber process, NO gas catalyses gaseous reactants.

Teacher's Note:
1. Same phase for catalyst and reactants means homogeneous.

Question 19: Which of the following is NOT involved in heterogeneous catalysis?
(a) Adsorption of reactants
(b) Diffusion of reactants along the surface
(c) Reaction at the active site to form adsorbed products
(d) Decomposition of the catalyst
Show Answer & Explanation

Answer: (d) Decomposition of the catalyst

Explanation:
1. A catalyst is not consumed during the reaction. Adsorption, surface diffusion, reaction at the active site and desorption are the steps.

Teacher's Note:
1. Catalysts remain unchanged chemically.

Question 20: Which statement is WRONG for enzyme catalysis?
(a) Enzymes work best at an optimum temperature
(b) Enzymes work at an optimum pH
(c) Enzymes are highly specific for a substrate
(d) An enzyme raises the activation energy
Show Answer & Explanation

Answer: (d) An enzyme raises the activation energy

Explanation:
1. Enzymes lower the activation energy of the reaction.

Teacher's Note:
1. All catalysts lower activation energy.

Question 21: An example of a zeolite catalyst is:
(a) ZSM-5
(b) \( \ce{AgNO3} \)
(c) \( \ce{Mg(OH)2} \)
(d) \( \ce{Co(OH)3} \)
Show Answer & Explanation

Answer: (a) ZSM-5

Explanation:
1. ZSM-5 is an aluminosilicate zeolite that converts alcohols to gasoline range hydrocarbons.

Teacher's Note:
1. Zeolites are shape-selective.

Question 22: A catalytic reaction that depends on the pore structure of the catalyst and the size of the reactant and product molecules is called:
(a) Size-selective catalysis
(b) Shape-selective catalysis
(c) Metal oxide catalysis
(d) Transition metal catalysis
Show Answer & Explanation

Answer: (b) Shape-selective catalysis

Explanation:
1. In shape-selective catalysis only molecules that fit the pores of the zeolite can react.

Teacher's Note:
1. Zeolites are used in petroleum cracking.

Question 23: In the reaction \( \ce{2KMnO4 + 3H2SO4 + 5H2C2O4 -> K2SO4 + 2MnSO4 + 10CO2 + 8H2O} \), \( \ce{Mn^{2+}} \) acts as:
(a) Positive catalyst
(b) Negative catalyst
(c) Autocatalyst
(d) Induced catalyst
Show Answer & Explanation

Answer: (c) Autocatalyst

Explanation:
1. Mn2+ is a product that accelerates the reaction, so it is an autocatalyst (the reaction speeds up after a while).

Teacher's Note:
1. Autocatalysis shows a slow start.

Question 24: A methylene blue sol is:
(a) Negatively charged
(b) Neutral
(c) Positively charged
(d) Both positively and negatively charged
Show Answer & Explanation

Answer: (c) Positively charged

Explanation:
1. Basic dyes such as methylene blue form positively charged sols. Acid dyes such as eosin form negatively charged sols.

Teacher's Note:
1. Basic dye gives a positive sol.

Question 25: Sulphur sol is a:
(a) Macromolecular colloid
(b) Multimolecular colloid
(c) Associated colloid
(d) Micelle
Show Answer & Explanation

Answer: (b) Multimolecular colloid

Explanation:
1. Aggregates of thousands of \( \ce{S8} \) molecules form the colloidal particles, so the sol is multimolecular.

Teacher's Note:
1. Gold and sulphur sols are multimolecular.

Practice MCQs for JEE Chemistry Surface Chemistry

JEE Chemistry Surface Chemistry Objective Test Questions

Review structured objective questions for JEE Chemistry Surface Chemistry. Built according to official JEE guidelines, these MCQ sets support daily revision and core concept reinforcement.

NCERT-Aligned Objective Questions and Solutions

Each question includes structured solution keys mapped directly to standard JEE textbooks, helping students evaluate their reasoning and correct mistakes early in their revision.

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FAQs

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