Practice MCQs for JEE Chemistry Some Basic Concepts Of Chemistry
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Multiple Choice Questions
(a) 18, 28 and 16
(b) 16, 44 and 18
(c) 18, 44 and 12
(d) 18, 44 and 16
Show Answer & Explanation
Answer: (d) 18, 44 and 16
Explanation:
1. \( \ce{H2O} \) = 2 + 16 = 18.
2. \( \ce{CO2} \) = 12 + 32 = 44.
3. \( \ce{CH4} \) = 12 + 4 = 16.
Teacher's Note:
1. Molecular mass is the sum of the atomic masses of all atoms in the molecule.
(a) 16.2%, 22.5% and 61.3%
(b) 32.4%, 22.5% and 45.1%
(c) 32.4%, 45.1% and 22.5%
(d) 23.0%, 32.0% and 45.0%
Show Answer & Explanation
Answer: (b) 32.4%, 22.5% and 45.1%
Explanation:
1. Molar mass = 46 + 32 + 64 = 142 g/mol.
2. Na = 46/142 = 32.4%, S = 32/142 = 22.5%, O = 64/142 = 45.1%.
Teacher's Note:
1. Percentage of an element = (mass of that element in one mole / molar mass) x 100.
(a) FeO
(b) \( \ce{Fe2O3} \)
(c) \( \ce{Fe3O4} \)
(d) \( \ce{Fe2O} \)
Show Answer & Explanation
Answer: (b) \( \ce{Fe2O3} \)
Explanation:
1. Moles: Fe = 69.9/56 = 1.248; O = 30.1/16 = 1.881.
2. Ratio Fe : O = 1 : 1.5 = 2 : 3.
3. Empirical formula = \( \ce{Fe2O3} \).
Teacher's Note:
1. Divide percentages by atomic masses, then divide by the smallest and clear fractions.
(a) 63.5 g
(b) 159.5 g
(c) 19.9 g
(d) 39.8 g
Show Answer & Explanation
Answer: (d) 39.8 g
Explanation:
1. Molar mass of \( \ce{CuSO4} \) = 159.5 g/mol.
2. Cu per 100 g = 63.5/159.5 x 100 = 39.8 g.
Teacher's Note:
1. Mass of an element from a compound = mass percentage x mass of compound.
(a) 34.2, 10.4, 0.0460 and 2810
(b) 34.2, 10.4, 0.046 and 2808
(c) 34.3, 10.5, 0.0459 and 2800
(d) 34.2, 10.4, 0.0459 and 2810
Show Answer & Explanation
Answer: (a) 34.2, 10.4, 0.0460 and 2810
Explanation:
1. 34.216 gives 34.2. 10.4107 gives 10.4.
2. 0.04597 gives 0.0460 (the last zero is significant). 2808 gives 2810.
Teacher's Note:
1. Look at the fourth significant digit to round and keep the trailing zero in 0.0460.
(a) 10.8 M
(b) 22.3 M
(c) 15.4 M
(d) 1.54 M
Show Answer & Explanation
Answer: (c) 15.4 M
Explanation:
1. 1 L of solution weighs 1410 g and holds 0.69 x 1410 = 972.9 g of \( \ce{HNO3} \).
2. Moles = 972.9/63 = 15.44.
3. Molarity = 15.4 M.
Teacher's Note:
1. Molarity = 10 x density x mass percent / molar mass.
(a) 0.0585
(b) 0.0292
(c) 0.292
(d) 0.0146
Show Answer & Explanation
Answer: (b) 0.0292
Explanation:
1. Moles = 20/342 = 0.0585 mol.
2. Molarity = 0.0585/2 = 0.0292 mol/L.
Teacher's Note:
1. Divide moles by the final volume of solution in litre.
(a) 52, 13 and 13
(b) \( 3.13\times10^{25} \), 52 and \( 3.13\times10^{25} \)
(c) \( 3.13\times10^{25} \), 13 and \( 3.13\times10^{25} \)
(d) \( 3.13\times10^{25} \), 13 and \( 7.83\times10^{24} \)
Show Answer & Explanation
Answer: (d) \( 3.13\times10^{25} \), 13 and \( 7.83\times10^{24} \)
Explanation:
1. Ar is monatomic: 52 mol = 52 x \( 6.022\times10^{23} = 3.13\times10^{25} \) atoms.
2. 52 u of He = 52/4 = 13 atoms (one atom weighs 4 u).
3. 52 g of He = 13 mol = \( 13\times6.022\times10^{23} = 7.83\times10^{24} \) atoms.
Teacher's Note:
1. Distinguish u (mass of a few atoms) from g (mass of a mole-scale sample).
(a) 16 g
(b) 32 g
(c) 48 g
(d) 24 g
Show Answer & Explanation
Answer: (b) 32 g
Explanation:
1. Initial = 64/32 = 2 mol of \( \ce{O2} \).
2. 11.2 L at STP = 0.5 mol of \( \ce{O2} \) removed. \( 6.02\times10^{23} \) atoms = 1 mol atoms = 0.5 mol of \( \ce{O2} \) removed.
3. Left = 2 - 0.5 - 0.5 = 1 mol = 32 g.
Teacher's Note:
1. Convert each removed quantity to moles of \( \ce{O2} \) before subtracting.
(a) 2.31 mol/kg
(b) 0.040 mol/kg
(c) 2.22 mol/kg
(d) 1.11 mol/kg
Show Answer & Explanation
Answer: (a) 2.31 mol/kg
Explanation:
1. Take 1 mol of solution: ethanol = 0.04 mol, water = 0.96 mol = 17.28 g.
2. Molality = 0.04/0.01728 kg = 2.31 mol/kg.
Teacher's Note:
1. Pick a convenient total of 1 mole of solution and convert water moles to kilogram.
(a) 39.95 g/mol
(b) 39.96 g/mol
(c) 37.96 g/mol
(d) 38.99 g/mol
Show Answer & Explanation
Answer: (a) 39.95 g/mol
Explanation:
1. Average = 0.00337 x 35.96755 + 0.00063 x 37.96272 + 0.99600 x 39.9624.
2. = 0.1212 + 0.0239 + 39.8026 = 39.95 g/mol.
Teacher's Note:
1. Weight each isotopic mass by its fractional abundance.
(a) 44 g, 22 g and 22 g
(b) 44 g, 44 g and 44 g
(c) 44 g, 22 g and 44 g
(d) 22 g, 22 g and 44 g
Show Answer & Explanation
Answer: (a) 44 g, 22 g and 22 g
Explanation:
1. \( \ce{C + O2 -> CO2} \). (i) Air has excess oxygen, so 1 mol \( \ce{CO2} \) = 44 g.
2. (ii) 16 g \( \ce{O2} \) = 0.5 mol limiting, so \( \ce{CO2} \) = 0.5 mol = 22 g.
3. (iii) Again \( \ce{O2} \) is limiting (0.5 mol), so 22 g.
Teacher's Note:
1. Find the limiting reagent each time. Excess carbon does not make more product.
(a) \( 1.5\times10^{-3} \)% and \( 1.26\times10^{-4} \) m
(b) \( 1.5\times10^{-5} \)% and \( 1.26\times10^{-4} \) m
(c) \( 1.5\times10^{-3} \)% and \( 1.26\times10^{-2} \) m
(d) 15% and \( 1.26\times10^{-4} \) m
Show Answer & Explanation
Answer: (a) \( 1.5\times10^{-3} \)% and \( 1.26\times10^{-4} \) m
Explanation:
1. 15 ppm = 15 g in \( 10^6 \) g of solution = \( 15/10^6\times100 = 1.5\times10^{-3} \)%.
2. Moles of \( \ce{CHCl3} \) = 15/119.5 = 0.1255 mol in about 1000 kg of water.
3. Molality = \( 0.1255/1000 = 1.26\times10^{-4} \) mol/kg.
Teacher's Note:
1. ppm is mass per million parts of solution. Convert to percent by multiplying by \( 10^{-4} \).
(a) 2429 g of \( \ce{NH3} \); 1000 g of \( \ce{N2} \) left
(b) 3000 g of \( \ce{NH3} \); none left
(c) 1214 g of \( \ce{NH3} \); 571 g of \( \ce{H2} \) left
(d) 2429 g of \( \ce{NH3} \); 571 g of \( \ce{H2} \) left
Show Answer & Explanation
Answer: (d) 2429 g of \( \ce{NH3} \); 571 g of \( \ce{H2} \) left
Explanation:
1. Moles: \( \ce{N2} \) = 2000/28 = 71.4; \( \ce{H2} \) = 1000/2 = 500.
2. \( \ce{H2} \) needed for all the nitrogen = 3 x 71.4 = 214.3 mol, so \( \ce{N2} \) is limiting.
3. \( \ce{NH3} \) = 2 x 71.4 = 142.9 mol = 2429 g.
4. \( \ce{H2} \) left = 500 - 214.3 = 285.7 mol = 571 g.
Teacher's Note:
1. Compare moles divided by coefficients. The leftover is the excess reagent minus what is used.
(a) \( 2.87\times10^{-9} \) m, \( 1.515\times10^{-3} \) s and 25.365 kg
(b) \( 2.87\times10^{-11} \) m, \( 1.515\times10^{-5} \) s and 0.025365 kg
(c) \( 2.87\times10^{-11} \) m, \( 1.515\times10^{-5} \) s and 25.365 g
(d) \( 2.87\times10^{-8} \) m, \( 1.515\times10^{-6} \) s and 0.25365 kg
Show Answer & Explanation
Answer: (b) \( 2.87\times10^{-11} \) m, \( 1.515\times10^{-5} \) s and 0.025365 kg
Explanation:
1. pico = \( 10^{-12} \): 28.7 pm = \( 2.87\times10^{-11} \) m.
2. micro = \( 10^{-6} \): 15.15 us = \( 1.515\times10^{-5} \) s.
3. 25365 mg = 25.365 g = 0.025365 kg (the SI unit of mass is kg).
Teacher's Note:
1. Mass in SI is kilogram, not gram. Multiply by the prefix power of ten.
(a) \( \ce{CH2} \), 28 g/mol and \( \ce{C2H4} \)
(b) CH, 26 g/mol and \( \ce{C2H2} \)
(c) CH, 78 g/mol and \( \ce{C6H6} \)
(d) \( \ce{CH3} \), 30 g/mol and \( \ce{C2H6} \)
Show Answer & Explanation
Answer: (b) CH, 26 g/mol and \( \ce{C2H2} \)
Explanation:
1. C = 3.38/44 = 0.0768 mol. H = 2 x 0.690/18 = 0.0767 mol. Ratio 1 : 1, so empirical formula CH.
2. Molar mass = 11.6/10.0 x 22.4 = 26 g/mol.
3. 26/13 = 2, so molecular formula = \( \ce{C2H2} \).
Teacher's Note:
1. Moles of C and H come from \( \ce{CO2} \) and \( \ce{H2O} \). Molar mass from the STP data gives the multiplier.
(a) 10 \( N_A \), 10 \( N_A \) and 40 \( N_A \)
(b) 5 \( N_A \), 5 \( N_A \) and 20 \( N_A \)
(c) 10 \( N_A \), 10 \( N_A \) and 8 \( N_A \)
(d) 2 \( N_A \), 2 \( N_A \) and 8 \( N_A \)
Show Answer & Explanation
Answer: (a) 10 \( N_A \), 10 \( N_A \) and 40 \( N_A \)
Explanation:
1. Each formula unit has 2 H, 2 S and 8 O.
2. For 5 mol: H = 10, S = 10, O = 40 mol of atoms, that is 10 \( N_A \), 10 \( N_A \) and 40 \( N_A \) atoms.
Teacher's Note:
1. Number of atoms = moles x atoms per formula unit x \( N_A \).
(a) \( 6\times10^{24} \)
(b) \( 2.4\times10^{25} \)
(c) \( 3.6\times10^{25} \)
(d) \( 1.2\times10^{25} \)
Show Answer & Explanation
Answer: (d) \( 1.2\times10^{25} \)
Explanation:
1. H atoms = 10 x 3 + 5 x 2 = 40 mol.
2. \( \ce{H2} \) = 40/2 = 20 mol.
3. Molecules = \( 20\times6\times10^{23} = 1.2\times10^{25} \).
Teacher's Note:
1. Two H atoms make one \( \ce{H2} \) molecule, so halve the number of hydrogen atoms.
(a) 1 : 2
(b) 3 : 2
(c) 4 : 3
(d) 2 : 1
Show Answer & Explanation
Answer: (d) 2 : 1
Explanation:
1. Oxygen per g of Sn: A = 21.23/78.77 = 0.2695; B = 11.88/88.12 = 0.1348.
2. Ratio = 0.2695 : 0.1348 = 2 : 1, a simple ratio (law of multiple proportions).
Teacher's Note:
1. Divide the oxygen mass by the tin mass in each compound and compare.
(a) 26.9 g
(b) 22.4 g
(c) 18.7 g
(d) 1.20 g
Show Answer & Explanation
Answer: (a) 26.9 g
Explanation:
1. Mass of 22.4 L = 1.20 x 22.4 = 26.88 g.
2. So the molar mass is about 26.9 g/mol.
Teacher's Note:
1. Molar mass = density at STP x 22.4.
(a) 46 g/mol
(b) 55 g/mol
(c) 50 g/mol
(d) 44 g/mol
Show Answer & Explanation
Answer: (c) 50 g/mol
Explanation:
1. Molar masses: 44, 46, 76.
2. Average = (3 x 44 + 2 x 46 + 1 x 76)/6 = (132 + 92 + 76)/6 = 50 g/mol.
Teacher's Note:
1. Average molar mass is the mole-fraction-weighted mean.
(a) 20%
(b) 40%
(c) 50%
(d) 25%
Show Answer & Explanation
Answer: (b) 40%
Explanation:
1. Total moles = 2 + 1 + 2 = 5.
2. Mole percentage of \( \ce{CO2} \) = 2/5 x 100 = 40%.
Teacher's Note:
1. Mole percent = moles of one component / total moles x 100.
(a) 56 g/mol
(b) 258 g/mol
(c) 1217 g/mol
(d) 12170 g/mol
Show Answer & Explanation
Answer: (c) 1217 g/mol
Explanation:
1. One mole of the compound contains 56 g of Fe, which is 4.6% of the molar mass.
2. Molar mass = 56/0.046 = 1217 g/mol.
Teacher's Note:
1. Minimum molar mass = atomic mass of the element divided by its mass fraction.
(a) 2.16 g
(b) 1.08 g
(c) 2.76 g
(d) 4.32 g
Show Answer & Explanation
Answer: (a) 2.16 g
Explanation:
1. Molar mass of \( \ce{Ag2CO3} \) = 276 g/mol, so 2.76 g = 0.01 mol.
2. Ag = 2 x 0.01 = 0.02 mol = 2.16 g (the only solid residue).
Teacher's Note:
1. Only silver is left behind. The carbon dioxide and oxygen escape as gases.
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