Practice MCQs for JEE Chemistry Some Basic Concepts Of Chemistry
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Multiple Choice Questions
(a) 8
(b) 16
(c) 24
(d) 32
Show Answer & Explanation
Answer: (b) 16
Explanation:
1. Molar mass = 2 × 16 = 32.
2. A ratio of specific heats of 1.4 shows a diatomic gas, so atomic weight = 32/2 = 16.
Teacher's Note:
1. The ratio 1.67 means monatomic and 1.4 means diatomic.
2. Divide the molar mass by the atomicity.
(a) Molecular weight
(b) Atomic weight
(c) Equivalent weight
(d) All
Show Answer & Explanation
Answer: (a) Molecular weight
Explanation:
1. 22.4 L of vapour at NTP is one mole, and its mass is the molecular weight in grams.
Teacher's Note:
1. This is the principle of Victor Meyer's method.
2. The volume of vapour equals the volume of air displaced.
(a) 39
(b) 18.5
(c) 78
(d) 112
Show Answer & Explanation
Answer: (c) 78
Explanation:
1. Molar mass = 0.39 × 22400/112 = 78.
Teacher's Note:
1. Mass of 22400 mL gives the molar mass.
2. This is benzene, with molar mass 78.
(a) 40
(b) 60
(c) 80
(d) 120
Show Answer & Explanation
Answer: (c) 80
Explanation:
1. Molar mass = 0.2 × 22400/56 = 80.
Teacher's Note:
1. The air displaced equals the vapour volume at STP.
2. Scale to 22400 mL.
(a) 130
(b) 17
(c) 1700
(d) 170
Show Answer & Explanation
Answer: (d) 170
Explanation:
1. Mass = 0.510 g.
2. Molar mass = 0.510 × 22400/67.2 = 170.
Teacher's Note:
1. Convert mg to g first.
2. The result is 170 g/mol.
(a) 1.25
(b) 14
(c) 28
(d) 56
Show Answer & Explanation
Answer: (c) 28
Explanation:
1. Molar mass = 6.25 × 22.4/5 = 28 g/mol.
Teacher's Note:
1. Mass of 22.4 L is the gram molecular weight.
2. This is the molar mass of N2 or CO.
(a) N2O
(b) NO
(c) N2O4
(d) NO2
Show Answer & Explanation
Answer: (a) N2O
Explanation:
1. Molar mass = 0.44 × 22400/224 = 44 g/mol.
2. N2O has molar mass 44 and is colourless; NO2 is brown.
Teacher's Note:
1. Compute the molar mass and match the oxide.
2. N2O is laughing gas.
(a) C2H2
(b) CO
(c) O2
(d) NH3
Show Answer & Explanation
Answer: (a) C2H2
Explanation:
1. Molar mass = 1.16 × 22.4 = 26 g/mol.
2. C2H2 has molar mass 26.
Teacher's Note:
1. Density × 22.4 gives molar mass.
2. CO is 28, O2 is 32 and NH3 is 17.
(a) 68.2
(b) 103.7
(c) 136.4
(d) 166.3
Show Answer & Explanation
Answer: (c) 136.4
Explanation:
1. Atomic weight = 2 × 32.7 = 65.4.
2. MCl2 = 65.4 + 71 = 136.4.
Teacher's Note:
1. Valency is 2, so the chloride is MCl2.
2. Add 2 × 35.5 = 71.
(a) 27
(b) 75
(c) 102
(d) 18
Show Answer & Explanation
Answer: (c) 102
Explanation:
1. Valency = 3, so atomic mass of M = 9 × 3 = 27.
2. Molar mass of M2O3 = 2 × 27 + 48 = 102.
Teacher's Note:
1. Valency in M2O3 is 3.
2. Add the mass of three oxygen atoms.
(a) Lavoisier
(b) Dalton
(c) Proust
(d) Gay-Lussac
Show Answer & Explanation
Answer: (b) Dalton
Explanation:
1. John Dalton proposed the law of multiple proportions in 1803.
Teacher's Note:
1. Lavoisier: conservation of mass. Proust: definite proportions.
2. Gay-Lussac: combining volumes.
(a) H2O, Na2O
(b) MgO, Na2O
(c) Na2O, BaO
(d) SnCl2, SnCl4
Show Answer & Explanation
Answer: (d) SnCl2, SnCl4
Explanation:
1. The law applies to two compounds made of the same two elements.
2. SnCl2 and SnCl4 contain Sn and Cl, with Cl masses in the ratio 1 : 2 for a fixed mass of Sn.
Teacher's Note:
1. Look for the same pair of elements forming two compounds.
2. The ratio of the second element's masses is a simple whole number.
(a) Definite proportion
(b) Multiple proportion
(c) Conservation of mass
(d) Gaseous volumes
Show Answer & Explanation
Answer: (d) Gaseous volumes
Explanation:
1. Gases combine in simple whole number volume ratios at the same T and P.
2. This is Gay-Lussac's law of gaseous volumes.
Teacher's Note:
1. Volume ratio of gases means Gay-Lussac's law.
2. The ratio is the same as the mole ratio.
(a) Equivalent proportion
(b) Multiple proportion
(c) Constant proportion
(d) Conservation of matter
Show Answer & Explanation
Answer: (b) Multiple proportion
Explanation:
1. Nitrogen and oxygen form several oxides with oxygen masses in simple whole number ratios for fixed nitrogen mass.
2. This is the law of multiple proportions.
Teacher's Note:
1. Same two elements, different compounds: multiple proportions.
2. N2O, NO, N2O3, NO2 and N2O5 are examples.
(a) Law of conservation of mass
(b) Law of multiple proportions
(c) Law of gaseous volume
(d) None of these
Show Answer & Explanation
Answer: (d) None of these
Explanation:
1. The two samples have different masses of carbon per mole, so they are not two different compounds of the same elements in a simple ratio.
2. None of the given laws is illustrated.
Teacher's Note:
1. Isotopes have different masses but identical chemistry.
2. The laws of chemical combination apply to natural samples.
(a) All chemical reactions
(b) Nuclear reactions
(c) Endothermic reactions
(d) Exothermic reactions
Show Answer & Explanation
Answer: (b) Nuclear reactions
Explanation:
1. In nuclear reactions, a small part of mass is converted into energy.
2. Mass is conserved in all chemical reactions, including endothermic and exothermic ones.
Teacher's Note:
1. Einstein's mass-energy relation explains nuclear mass defect.
2. Chemical energy changes are too small to measure as a mass change.
(a) In the order CO2 < O2 < NH3
(b) In the order NH3 < O2 < CO2
(c) The same
(d) NH3 = CO2 < O2
Show Answer & Explanation
Answer: (c) The same
Explanation:
1. Equal volumes of gases at the same T and P contain equal numbers of molecules (Avogadro's law).
Teacher's Note:
1. The identity of the gas does not matter.
2. This holds for ideal gases at the same T and P.
(a) C2H4
(b) C3H6
(c) C6H12
(d) C4H8
Show Answer & Explanation
Answer: (a) C2H4
Explanation:
1. Equal volumes of gases at the same T and P have the same number of molecules, so equal mass means equal molar mass: 28.
2. Mass of CH2 = 14, so n = 28/14 = 2 and the formula is C2H4.
Teacher's Note:
1. Same volume and same mass means same molar mass.
2. Molecular formula = n × empirical formula.
(a) 1 : 1 : 1 : 1
(b) 1 : 2 : 2 : 3
(c) 2 : 1 : 2 : 3
(d) 2 : 1 : 3 : 2
Show Answer & Explanation
Answer: (c) 2 : 1 : 2 : 3
Explanation:
1. Equal volumes have equal numbers of molecules, say N.
2. Atoms: H2 = 2N, He = N, O2 = 2N, O3 = 3N.
3. Ratio = 2 : 1 : 2 : 3.
Teacher's Note:
1. Multiply the common molecule count by atomicity.
2. Helium is monatomic.
(a) 22
(b) 44
(c) 66
(d) 88
Show Answer & Explanation
Answer: (b) 44
Explanation:
1. Same volume means the same number of moles.
2. 0.28/28 = 0.01 mol, so the molar mass of the unknown gas = 0.44/0.01 = 44.
Teacher's Note:
1. Equal moles in the same volume at the same T and P.
2. Use the ratio of masses times 28.
(a) 75
(b) 150
(c) 37.5
(d) 45
Show Answer & Explanation
Answer: (a) 75
Explanation:
1. 15 g of ethane (30 g/mol) = 0.5 mol.
2. The same moles of X2 weigh 75 g, so molar mass = 150 and vapour density = 75.
Teacher's Note:
1. Same vessel, T and P means the same number of moles.
2. V.D. = molar mass ÷ 2.
(a) \( \frac{n}{2} \) g
(b) 100 g
(c) \( \frac{100}{n} \) g
(d) 100n g
Show Answer & Explanation
Answer: (b) 100 g
Explanation:
1. Polymerisation only joins molecules, so no mass is lost or gained.
2. Mass of polymer = 100 g.
Teacher's Note:
1. The law of conservation of mass applies.
2. No by-product is formed in addition polymerisation.
(a) 11.65 g
(b) 23.3 g
(c) 25.5 g
(d) 30.6 g
Show Answer & Explanation
Answer: (b) 23.3 g
Explanation:
1. Total mass of reactants = 20.8 + 9.8 = 30.6 g.
2. Mass of BaSO4 = 30.6 − 7.3 = 23.3 g.
Teacher's Note:
1. Total mass of reactants equals total mass of products.
2. Check: 0.1 mol BaSO4 = 23.3 g.
(a) Multiple proportion
(b) Constant composition
(c) Gaseous volume
(d) Conservation of mass
Show Answer & Explanation
Answer: (d) Conservation of mass
Explanation:
1. Balancing makes the number of atoms of each element equal on both sides, which follows the law of conservation of mass.
Teacher's Note:
1. Balanced equation means mass is conserved.
2. Other laws deal with ratios of combining masses or volumes.
(a) A
(b) B
(c) Both have the same moles
(d) None
Show Answer & Explanation
Answer: (c) Both have the same moles
Explanation:
1. Equal volumes at the same T and P have equal moles (Avogadro's law).
Teacher's Note:
1. The nature of the gas is irrelevant.
2. Same capacity, T and P means same moles.
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Practice MCQs for JEE Chemistry Some Basic Concepts Of Chemistry
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