# CBSE Class 12 Chemistry Chemical Kinetics Worksheet Set D

Read and download free pdf of CBSE Class 12 Chemistry Chemical Kinetics Worksheet Set D. Students and teachers of Class 12 Chemistry can get free printable Worksheets for Class 12 Chemistry in PDF format prepared as per the latest syllabus and examination pattern in your schools. Standard 12 students should practice questions and answers given here for Chemistry in Grade 12 which will help them to improve your knowledge of all important chapters and its topics. Students should also download free pdf of Class 12 Chemistry Worksheets prepared by school teachers as per the latest NCERT, CBSE, KVS books and syllabus issued this academic year and solve important problems provided here with solutions on daily basis to get more score in school exams and tests

1. For a chemical reaction represented by R→ P the rate of reaction is denoted by –d [R]/dt or +d[P]/dt . State the significance of plus and minus sign.

2. Express the rate of reaction in terms of disappearance of hydrogen and appearance of ammonia in the given reaction.

N2(g) + 3 H2 (g) → 2NH3 (g)

3. Why rate of reaction does not remain constant throughout?

4. Write the unit of first order rate constant of a gaseous reaction if the partial pressure of gaseous reactant is given in bar.

5. What will be the order of reaction, if the rate of reaction does not depend on the concentration of any of the reactant.

6. For the elementary step of a chemical reaction :

H2 + I2 →2HI

rate of reaction →[H2] [I2]

What is the (i) molecularity and (ii) order of the reaction.

7.For a chemical reaction A→ B. The rate of the reaction is given as Rate = k [A]n the rate of the above reaction quadruples when the concentration of A is doubled. What is the value of n?

8.Mention one example of zero order reaction.

9. What is the value of the order of reaction of radioactive decay?

10. Express the relation between the half life period of a reactant and initial concentration for a reaction of nth order.

Important Questions for NCERT Class 12 Chemistry Chemical Kinetics

Question. In a zero-order reaction, for every 10 °C rise of temperature, the rate is doubled. If the temperature is increased from 10 °C to 100 °C, the rate of the reaction will become
(a) 256 times
(b) 512 times
(c) 64 times
(d) 128 times.

Question. The rate of the reaction,
2NO + Cl2 → 2NOCl is given by the rate equation, rate = k[NO]2[Cl2]. The value of the rate constant can be increased by
(a) increasing the temperature
(b) increasing the concentration of NO
(c) increasing the concentration of the Cl2
(d) doing all of these.

Question. The activation energy for a simple chemical reaction A ⇌ B is Ea in forward direction. The activation energy for reverse reaction
(a) is negative of Ea
(b) is always less than Ea
(c) can be less than or more than Ea
(d) is always double of Ea.

Question. When a biochemical reaction is carried out in laboratory, outside the human body in absence of enzyme, then rate of reaction obtained is 10–6 times, the activation energy of reaction in the presence of enzyme is
(a) 6/RT
(b) P is required
(c) different from Ea obtained in laboratory
(d) can’t say anything.

Question. How enzymes increases the rate of reactions?
(a) By lowering activation energy
(b) By increasing activation energy
(c) By changing equilibrium constant
(d) By forming enzyme substrate complex

Question. Activation energy of a chemical reaction can be determined by
(a) evaluating rate constants at two different temperatures
(b) evaluating velocities of reaction at two different temperatures
(c) evaluating rate constant at standard temperature
(d) changing concentration of reactants.

Question. By the action of enzymes, the rate of biochemical reaction
(a) does not change
(b) increases
(c) decreases
(d) either (a) or (c).

Question. An increase in the concentration of the reactants of a reaction leads to change in
(a) activation energy
(b) heat of reaction
(c) threshold energy
(d) collision frequency.

Question. The rate constant of first order reaction is 3 × 10–6 per second. The initial concentration is 0.10 M.
The initial rate is:
(a) 3 × 10–7 mol/litre/sec
(b) 3 × 10–8 mol/litre/sec
(c) 3 × 10–5 mol/litre/sec
(d) 3 × 10–8 mol/litre/sec

Question. Which of the following statement is true for the reaction, H2 + Br2 →2HBr . The rate law is [ H2 ][ Br2 ]1/ 2 dx/dt=k
(a) order of reaction is 1.5
(b) molecularity of the reaction is 2
(c) by increasing the concentration of Br2 four times the rate of reaction is doubled
(d) all the above are correct.

Question. For the reaction :
H2 Cl2 →sunlight 2HCl the order of reaction is
(a) 0
(b) 2
(c) 1
(d) 3

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